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This section includes 11242 Mcqs, each offering curated multiple-choice questions to sharpen your Joint Entrance Exam - Main (JEE Main) knowledge and support exam preparation. Choose a topic below to get started.
| 4201. |
The percentage of copper and oxygen in samples of \[CuO\] obtained by different methods were found to be the same. This illustrates the law of [AMU 1982, 92] |
| A. | Constant proportions |
| B. | Conservation of mass |
| C. | Multiple proportions |
| D. | Reciprocal proportions |
| Answer» B. Conservation of mass | |
| 4202. |
Among the following pairs of compounds, the one that illustrates the law of multiple proportions is |
| A. | \[N{{H}_{3}}\text{ and }NC{{l}_{3}}\] |
| B. | \[{{H}_{2}}S\text{ and }S{{O}_{2}}\] |
| C. | \[CuO\text{ and C}{{\text{u}}_{\text{2}}}O\] |
| D. | \[C{{S}_{2}}\text{ and }FeS{{O}_{4}}\] |
| Answer» D. \[C{{S}_{2}}\text{ and }FeS{{O}_{4}}\] | |
| 4203. |
The law of definite proportions is not applicable to nitrogen oxide because [EAMCET 1981] |
| A. | Nitrogen atomic weight is not constant |
| B. | Nitrogen molecular weight is variable |
| C. | Nitrogen equivalent weight is variable |
| D. | Oxygen atomic weight is variable |
| Answer» D. Oxygen atomic weight is variable | |
| 4204. |
Which one of the following pairs of compounds illustrates the law of multiple proportion [EAMCET 1989] |
| A. | \[{{H}_{2}}O,\,N{{a}_{2}}O\] |
| B. | MgO,\[N{{a}_{2}}O\] |
| C. | \[N{{a}_{2}}O,BaO\] |
| D. | \[SnC{{l}_{2}},\,SnC{{l}_{4}}\] |
| Answer» E. | |
| 4205. |
A sample of pure carbon dioxide, irrespective of its source contains 27.27% carbon and 72.73% oxygen. The data support [AIIMS 1992] |
| A. | Law of constant composition |
| B. | Law of conservation of mass |
| C. | Law of reciprocal proportions |
| D. | Law of multiple proportions |
| Answer» B. Law of conservation of mass | |
| 4206. |
After a chemical reaction, the total mass of reactants and products [MP PMT 1989] |
| A. | Is always increased |
| B. | Is always decreased |
| C. | Is not changed |
| D. | Is always less or more |
| Answer» D. Is always less or more | |
| 4207. |
1.0 g of an oxide of A contained 0.5 g of A. 4.0 g of another oxide of A contained 1.6 g of A. The data indicate the law of |
| A. | Reciprocal proportions |
| B. | Constant proportions |
| C. | Conservation of energy |
| D. | Multiple proportions |
| Answer» E. | |
| 4208. |
2 g of hydrogen combine with 16 g of oxygen to form water and with 6 g of carbon to form methane. In carbon dioxide 12 g of carbon are combined with 32 g of oxygen. These figures illustrate the law of |
| A. | Multiple proportions |
| B. | Constant proportions |
| C. | Reciprocal proportions |
| D. | Conservation of mass |
| Answer» D. Conservation of mass | |
| 4209. |
An element forms two oxides containing respectively 53.33 and 36.36 percent of oxygen. These figures illustrate the law of |
| A. | Conservation of mass |
| B. | Constant proportions |
| C. | Reciprocal proportions |
| D. | Multiple proportions |
| Answer» E. | |
| 4210. |
Hydrogen combines with oxygen to form \[{{H}_{2}}O\] in which 16 g of oxygen combine with 2 g of hydrogen. Hydrogen also combines with carbon to form \[C{{H}_{4}}\] in which 2 g of hydrogen combine with 6 g of carbon. If carbon and oxygen combine together then they will do show in the ratio of |
| A. | 6 : 16 or 12 : 32 |
| B. | 6 : 18 |
| C. | 1 : 2 |
| D. | 12 : 24 |
| Answer» B. 6 : 18 | |
| 4211. |
In compound A, 1.00 g nitrogen unites with 0.57 g oxygen. In compound B, 2.00 g nitrogen combines with 2.24 g oxygen. In compound C, 3.00 g nitrogen combines with 5.11 g oxygen. These results obey the following law [CPMT 1971] |
| A. | Law of constant proportion |
| B. | Law of multiple proportion |
| C. | Law of reciprocal proportion |
| D. | Dalton's law of partial pressure |
| Answer» C. Law of reciprocal proportion | |
| 4212. |
The law of multiple proportions is illustrated by the two compounds [NCERT 1972] |
| A. | Sodium chloride and sodium bromide |
| B. | Ordinary water and heavy water |
| C. | Caustic soda and caustic potash |
| D. | Sulphur dioxide and sulphur trioxide |
| Answer» E. | |
| 4213. |
Which of the following is the best example of law of conservation of mass [NCERT 1975] |
| A. | 12 g of carbon combines with 32 g of oxygen to form 44 g of \[C{{O}_{2}}\] |
| B. | When 12 g of carbon is heated in a vacuum there is no change in mass |
| C. | A sample of air increases in volume when heated at constant pressure but its mass remains unaltered |
| D. | The weight of a piece of platinum is the same before and after heating in air |
| Answer» B. When 12 g of carbon is heated in a vacuum there is no change in mass | |
| 4214. |
n g of substance X reacts with m g of substance Y to form p g of substance R and q g of substance S. This reaction can be represented as, \[X+Y=R+S\]. The relation which can be established in the amounts of the reactants and the products will be |
| A. | \[n-m=p-q\] |
| B. | \[n+m=p+q\] |
| C. | \[n=m\] |
| D. | \[p=q\] |
| Answer» C. \[n=m\] | |
| 4215. |
A sample of calcium carbonate \[(CaC{{O}_{3}})\] has the following percentage composition : Ca = 40%; C = 12%; O = 48% If the law of constant proportions is true, then the weight of calcium in 4 g of a sample of calcium carbonate obtained from another source will be |
| A. | 0.016 g |
| B. | 0.16 g |
| C. | 1.6 g |
| D. | 16 g |
| Answer» D. 16 g | |
| 4216. |
Carbon and oxygen combine to form two oxides, carbon monoxide and carbon dioxide in which the ratio of the weights of carbon and oxygen is respectively 12 : 16 and 12 : 32. These figures illustrate the |
| A. | Law of multiple proportions |
| B. | Law of reciprocal proportions |
| C. | Law of conservation of mass |
| D. | Law of constant proportions |
| Answer» B. Law of reciprocal proportions | |
| 4217. |
Which of the following pairs of substances illustrate the law of multiple proportions [CPMT 1972, 78] |
| A. | CO and CO2 |
| B. | \[{{H}_{2}}O\text{ and }{{D}_{2}}O\] |
| C. | \[NaCl\text{ and }NaBr\] |
| D. | \[MgO\text{ and }Mg{{(OH)}_{2}}\] |
| Answer» B. \[{{H}_{2}}O\text{ and }{{D}_{2}}O\] | |
| 4218. |
Chemical equations convey quantitative information on the [Orissa JEE 2002] |
| A. | Type of atoms/molecules taking part in the reaction |
| B. | Number of atoms/molecules of the reactants and products involved in the reaction |
| C. | Relative number of moles of reactants and products involved in the reaction |
| D. | Quantity of reactant consumed and quantity of product formed |
| Answer» D. Quantity of reactant consumed and quantity of product formed | |
| 4219. |
The rate at which substances react depends on their [MP PMT 1997] |
| A. | Atomic weight |
| B. | Molecular weight |
| C. | Equivalent weight |
| D. | Active mass |
| Answer» E. | |
| 4220. |
Theory of ?active mass? indicates that the rate of chemical reaction is directly proportional to the [MP PET 1990] |
| A. | Equilibrium constant |
| B. | Properties of reactants |
| C. | Volume of apparatus |
| D. | Concentration of reactants |
| Answer» E. | |
| 4221. |
The law of mass action was enunciated by [MP PMT 1995] |
| A. | Guldberg and Waage |
| B. | Bodenstein |
| C. | Birthelot |
| D. | Graham |
| Answer» B. Bodenstein | |
| 4222. |
Under a given set of experimental conditions, with increase in the concentration of the reactants, the rate of a chemical reaction [BHU 1979] |
| A. | Decreases |
| B. | Increases |
| C. | Remains unaltered |
| D. | First decreases and then increases |
| Answer» C. Remains unaltered | |
| 4223. |
In a reaction the rate of reaction is proportional to its active mass, this statement is known as [IIT 1979] |
| A. | Law of mass action |
| B. | Le-chatelier principle |
| C. | Faraday law of electrolysis |
| D. | Law of constant proportion |
| Answer» B. Le-chatelier principle | |
| 4224. |
For the system \[A(g)+2B(g)\]⇌\[C(g)\], the equilibrium concentrations are 0.06 mole/litre 0.12 mole/litre 0.216 mole/litre. The \[{{K}_{eq}}\] for the reaction is [CPMT 1983] |
| A. | 250 |
| B. | 416 |
| C. | \[4\times {{10}^{-3}}\] |
| D. | 125 |
| Answer» B. 416 | |
| 4225. |
According to law of mass action rate of a chemical reaction is proportional to [AFMC 2005] |
| A. | Concentration of reactants |
| B. | Molar concentration of reactants |
| C. | Concentration of products |
| D. | Molar concentration of products |
| Answer» C. Concentration of products | |
| 4226. |
Pure ammonia is placed in a vessel at temperature where its dissociation constant (\[\alpha \]) is appreciable. At equilibrium [IIT 1984; Kurukshetra CEE 1998] |
| A. | \[{{K}_{p}}\] does not change significantly with pressure |
| B. | \[\alpha \] does not change with pressure |
| C. | Concentration of \[N{{H}_{3}}\] does not change with pressure |
| D. | Concentration of \[{{H}_{2}}\] is less than that of \[{{N}_{2}}\] |
| Answer» B. \[\alpha \] does not change with pressure | |
| 4227. |
5 moles of SO2 and 5 moles of O2 are allowed to react to form SO3 in a closed vessel. At the equilibrium stage 60% of SO2 is used up. The total number of moles of SO2, O2 and SO3 in the vessel now is [KCET 2001] |
| A. | 10.0 |
| B. | 8.5 |
| C. | 10.5 |
| D. | 3.9 |
| Answer» C. 10.5 | |
| 4228. |
0.6 mole of NH3 in a reaction vessel of 2dm3 capacity was brought to equilibrium. The vessel was then found to contain 0.15 mole of H2 formed by the reaction \[2N{{H}_{3(g)}}={{N}_{2(g)}}+3{{H}_{2(g)}}\] Which of the following statements is true [KCET 1999] |
| A. | 0.15 mole of the original NH3 had dissociated at equilibrium |
| B. | 0.55 mole of ammonia is left in the vessel |
| C. | At equilibrium the vessel contained 0.45 mole of \[{{N}_{2}}\] |
| D. | The concentration of NH3 at equilibrium is 0.25 mole per dm3 |
| Answer» E. | |
| 4229. |
For the reaction : \[{{H}_{2(g)}}+C{{O}_{2(g)}}\] ⇌\[C{{O}_{(g)}}+{{H}_{2}}{{O}_{(g)}}\], if the initial concentration of \[[{{H}_{2}}]=[C{{O}_{2}}]\] and \[x\] moles/litre of hydrogen is consumed at equilibrium, the correct expression of \[{{K}_{p}}\] is [Orissa JEE 2005] |
| A. | \[\frac{{{x}^{2}}}{{{(1-x)}^{2}}}\] |
| B. | \[\frac{{{(1+x)}^{2}}}{{{(1-x)}^{2}}}\] |
| C. | \[\frac{{{x}^{2}}}{{{(2+x)}^{2}}}\] |
| D. | \[\frac{{{x}^{2}}}{1-{{x}^{2}}}\] |
| Answer» B. \[\frac{{{(1+x)}^{2}}}{{{(1-x)}^{2}}}\] | |
| 4230. |
When \[NaN{{O}_{3}}\] is heated in a closed vessel, \[{{O}_{2}}\] is liberated and \[NaN{{O}_{2}}\] is left behind. At equilibrium [IIT 1986; Roorkee 1995] |
| A. | Addition of \[NaN{{O}_{3}}\] favours forward reaction |
| B. | Addition of \[NaN{{O}_{2}}\] favours reverse reaction |
| C. | Increasing pressure favours reverse reaction |
| D. | Increasing temperature favours forward reaction |
| Answer» B. Addition of \[NaN{{O}_{2}}\] favours reverse reaction | |
| 4231. |
What is the effect of halving the pressure by doubling the volume on the following system at 500°C \[{{H}_{2(g)}}+{{I}_{2(g)}}\]⇌ \[2H{{I}_{(g)}}\] [UPSEAT 2004] |
| A. | Shift to product side |
| B. | Shift to product formation |
| C. | Liquefaction of HI |
| D. | No effect |
| Answer» E. | |
| 4232. |
The equilibrium constant in a reversible reaction at a given temperature [AIIMS 1982] |
| A. | Depends on the initial concentration of the reactants |
| B. | Depends on the concentration of the products at equilibrium |
| C. | Does not depend on the initial concentrations |
| D. | It is not characteristic of the reaction |
| Answer» D. It is not characteristic of the reaction | |
| 4233. |
For a reaction \[{{H}_{2}}+{{I}_{2}}\]⇌\[2HI\]at 721K, the value of equilibrium constant is 50. If 0.5 mols each of \[{{H}_{2}}\]and \[{{I}_{2}}\]is added to the system the value of equilibrium constant will be [DCE 2004] |
| A. | 40 |
| B. | 60 |
| C. | 50 |
| D. | 30 |
| Answer» D. 30 | |
| 4234. |
2 mol of \[{{N}_{2}}\] is mixed with 6 mol of \[{{H}_{2}}\]in a closed vessel of one litre capacity. If 50% of \[{{N}_{2}}\]is converted into \[N{{H}_{3}}\]at equilibrium, the value of \[{{K}_{c}}\]for the reaction \[{{N}_{2(g)}}+3{{H}_{2(g)}}\] ⇌\[2N{{H}_{3(g)}}\]is [Kerala PMT 2004] |
| A. | \[4/27\] |
| B. | \[27/4\] |
| C. | \[1/27\] |
| D. | 24 |
| E. | 9 |
| Answer» B. \[27/4\] | |
| 4235. |
Ammonia carbonate when heated to 200°C gives a mixture of \[N{{H}_{3}}\] and \[C{{O}_{2}}\]vapour with a density of 13.0. What is the degree of dissociation of ammonium carbonate [Kerala PMT 2004] |
| A. | \[3/2\] |
| B. | \[1/2\] |
| C. | 2 |
| D. | 1 |
| E. | \[5/2\] |
| Answer» E. \[5/2\] | |
| 4236. |
In the reaction, \[{{H}_{2}}+{{I}_{2}}\]⇌\[2HI\]. In a 2 litre flask 0.4 moles of each \[{{H}_{2}}\] and \[{{I}_{2}}\] are taken. At equilibrium 0.5 moles of \[HI\] are formed. What will be the value of equilibrium constant, \[{{K}_{c}}\] [CPMT 2004] |
| A. | 20.2 |
| B. | 25.4 |
| C. | 0.284 |
| D. | 11.1 |
| Answer» E. | |
| 4237. |
What is the equilibrium expression for the reaction \[{{P}_{4(s)}}+5{{O}_{2(g)}}\]⇌ \[{{P}_{4}}{{O}_{10(s)}}\] [AIEEE 2004] |
| A. | \[{{K}_{c}}={{[{{O}_{2}}]}^{5}}\] |
| B. | \[{{K}_{c}}=[{{P}_{4}}{{O}_{10}}]/5[{{P}_{4}}][{{O}_{2}}]\] |
| C. | \[{{K}_{c}}=[{{P}_{4}}{{O}_{10}}]/[{{P}_{4}}]{{[{{O}_{2}}]}^{5}}\] |
| D. | \[{{K}_{c}}=1/{{[{{O}_{2}}]}^{5}}\] |
| Answer» E. | |
| 4238. |
The equilibrium constant for the reaction \[{{N}_{2(g)}}+{{O}_{2(g)}}\]⇌ \[2N{{O}_{(g)}}\] at temperature T is \[4\times {{10}^{-4}}\]. The value of \[{{K}_{c}}\]for the reaction \[N{{O}_{(g)}}\]⇌\[\frac{1}{2}{{N}_{2(g)}}+\frac{1}{2}{{O}_{2(g)}}\] at the same temperature is [AIEEE 2004] |
| A. | \[4\times {{10}^{-4}}\] |
| B. | \[50\] |
| C. | \[2.5\times {{10}^{2}}\] |
| D. | 0.02 |
| Answer» C. \[2.5\times {{10}^{2}}\] | |
| 4239. |
Calculate the partial pressure of carbon monoxide from the following \[CaC{{O}_{3(s)}}\xrightarrow{\Delta }Ca{{O}_{(s)}}+C{{O}_{2}}\uparrow \]; \[{{K}_{p}}=8\times {{10}^{-2}}\] \[C{{O}_{2(g)}}+{{C}_{(s)}}\to 2C{{O}_{(g)}}\] ; \[{{K}_{p}}=2\]\[\] [Orissa JEE 2004] |
| A. | 0.2 |
| B. | 0.4 |
| C. | 1.6 |
| D. | 4 |
| Answer» C. 1.6 | |
| 4240. |
The compound A and B are mixed in equimolar proportion to form the products, \[A+B\] ⇌ \[C+D\]. At equilibrium, one third of A and B are consumed. The equilibrium constant for the reaction is [KCET 2004] |
| A. | 0.5 |
| B. | 4.0 |
| C. | 2.5 |
| D. | 0.25 |
| Answer» E. | |
| 4241. |
The reaction, \[2S{{O}_{2(g)}}+{{O}_{2(g)}}\]⇌ \[2S{{O}_{3(g)}}\] is carried out in a 1\[d{{m}^{3}}\]vessel and \[2\ d{{m}^{3}}\]vessel separately. The ratio of the reaction velocities will be [KCET 2004] |
| A. | \[1:8\] |
| B. | \[1:4\] |
| C. | \[4:1\] |
| D. | \[8:1\] |
| Answer» E. | |
| 4242. |
56 g of nitrogen and 8 g hydrogen gas are heated in a closed vessel. At equilibrium 34 g of ammonia are present. The equilibrium number of moles of nitrogen, hydrogen and ammonia are respectively [KCET 2004] |
| A. | 1,2,2 |
| B. | 2,2,1 |
| C. | 1,1,2 |
| D. | 2,1,2 |
| Answer» D. 2,1,2 | |
| 4243. |
A reversible chemical reaction having two reactants in equilibrium. If the concentrations of the reactants are doubled, then the equilibrium constant will [CPMT 1982, 90; MP PMT 1990,2004; MNR 1992; UPSEAT 2002; KCET 1999; Pb. CET 2004] |
| A. | Also be doubled |
| B. | Be halved |
| C. | Become one-fourth |
| D. | Remain the same |
| Answer» E. | |
| 4244. |
3.2 moles of hydrogen iodide were heated in a sealed bulb at \[{{444}^{o}}C\] till the equilibrium state was reached. Its degree of dissociation at this temperature was found to be 22%. The number of moles of hydrogen iodide present at equilibrium are [BHU 1982] |
| A. | 2.496 |
| B. | 1.87 |
| C. | 2 |
| D. | 4 |
| Answer» B. 1.87 | |
| 4245. |
For the reaction equilibrium \[{{N}_{2}}{{O}_{4}}\]⇌\[2N{{O}_{2(g)}}\], the concentrations of \[{{N}_{2}}{{O}_{4}}\] and \[N{{O}_{2}}\] at equilibrium are \[4.8\times {{10}^{-2}}\]and \[1.2\times {{10}^{-2}}\,mol\,litr{{e}^{-1}}\] respectively. The value of \[{{K}_{c}}\] for the reaction is [AIEEE 2003] |
| A. | \[3.3\times {{10}^{2}}\]\[mol\,\,litr{{e}^{-1}}\] |
| B. | \[3\times {{10}^{-1}}\]\[mol\,\,litr{{e}^{-1}}\] |
| C. | \[3\times {{10}^{-3}}\]\[mol\,\,litr{{e}^{-1}}\] |
| D. | \[3\times {{10}^{3}}\]\[mol\,\,litr{{e}^{-1}}\] |
| Answer» D. \[3\times {{10}^{3}}\]\[mol\,\,litr{{e}^{-1}}\] | |
| 4246. |
In the reaction \[PC{{l}_{5(g)}}\]⇌ \[PC{{l}_{3(g)}}\]\[+C{{l}_{2(g)}}.\] The equilibrium concentrations of \[PC{{l}_{5}}\] and \[PC{{l}_{3}}\] are 0.4 and 0.2 mole/litre respectively. If the value of \[{{K}_{c}}\]is 0.5 what is the concentration of \[C{{l}_{2}}\] in moles/litre [EAMCET 2003] |
| A. | 2.0 |
| B. | 1.5 |
| C. | 1.0 |
| D. | 0.5 |
| Answer» D. 0.5 | |
| 4247. |
In a reaction, reactant ?A? decomposes 10% in 1 hour, 20% on 2 hour and 30% in 3 hour. The unit of rate constant of this reaction is [MP PET 2003] |
| A. | \[se{{c}^{-1}}\] |
| B. | \[mol\,\,litr{{e}^{-1}}\,se{{c}^{-1}}\] |
| C. | \[litre\,\,mo{{l}^{-1}}\,se{{c}^{-1}}\] |
| D. | \[litr{{e}^{2}}\,mo{{l}^{-2}}\,se{{c}^{-1}}\] |
| Answer» C. \[litre\,\,mo{{l}^{-1}}\,se{{c}^{-1}}\] | |
| 4248. |
Two moles of \[N{{H}_{3}}\] when put into a previously evacuated vessel (one litre), partially dissociate into \[{{N}_{2}}\] and \[{{H}_{2}}\]. If at equilibrium one mole of NH3 is present, the equilibrium constant is [MP PET 2003] |
| A. | 3/4 \[mo{{l}^{2}}\,litr{{e}^{-2}}\] |
| B. | 27/64 \[mo{{l}^{2}}\,litr{{e}^{-2}}\] |
| C. | 27/32 \[mo{{l}^{2}}\,litr{{e}^{-2}}\] |
| D. | 27/1 \[mo{{l}^{2}}\,litr{{e}^{-2}}\] |
| Answer» E. | |
| 4249. |
9.2 grams of \[{{N}_{2}}{{O}_{4(g)}}\] is taken in a closed one litre vessel and heated till the following equilibrium is reached \[{{N}_{2}}{{O}_{4(g)}}\]⇌ \[2N{{O}_{2(g)}}\]. At equilibrium, 50% \[{{N}_{2}}{{O}_{4(g)}}\] is dissociated. What is the equilibrium constant (in mol litre?1) (Molecular weight of \[{{N}_{2}}{{O}_{4}}=92)\] [MP PET 2003] |
| A. | 0.1 |
| B. | 0.4 |
| C. | 0.2 |
| D. | 2 |
| Answer» D. 2 | |
| 4250. |
Write the equilibrium constant K for \[C{{H}_{3}}COOH+{{H}_{2}}O={{H}_{3}}{{O}^{+}}+C{{H}_{3}}CO{{O}^{-}}\] [Kerala (Med.) 2002] |
| A. | \[K=\frac{[{{H}_{3}}{{O}^{+}}][{{H}_{2}}O]}{[C{{H}_{3}}CO{{O}^{-}}][C{{H}_{3}}COOH]}\] |
| B. | \[K=\frac{[{{H}_{3}}{{O}^{+}}][C{{H}_{3}}CO{{O}^{-}}]}{[{{H}_{2}}O][C{{H}_{3}}COOH]}\] |
| C. | \[K=\frac{[{{H}_{3}}{{O}^{+}}][{{H}_{2}}O]}{[C{{H}_{3}}COOH][C{{H}_{3}}CO{{O}^{-}}]}\] |
| D. | \[K=\frac{[{{H}_{2}}O][C{{H}_{3}}CO{{O}^{-}}]}{[{{H}_{2}}O][C{{H}_{3}}COOH]}\] |
| Answer» C. \[K=\frac{[{{H}_{3}}{{O}^{+}}][{{H}_{2}}O]}{[C{{H}_{3}}COOH][C{{H}_{3}}CO{{O}^{-}}]}\] | |