Explore topic-wise MCQs in Joint Entrance Exam - Main (JEE Main).

This section includes 11242 Mcqs, each offering curated multiple-choice questions to sharpen your Joint Entrance Exam - Main (JEE Main) knowledge and support exam preparation. Choose a topic below to get started.

651.

The molecular mass of acetic acid dissolved in water is 60 and when dissolved in benzene it is 120.This difference in behaviour of \[C{{H}_{3}}COOH\] is because       [AMU 2000]

A. Water prevents association of acetic acid
B. Acetic acid does not fully dissolve in water
C. Acetic acid fully dissolves in benzene
D. Acetic acid does not ionize in benzene
Answer» C. Acetic acid fully dissolves in benzene
652.

Which of the following molecules has one lone pair of electrons on the central atom [EAMCET 1980; AMU 1982; MNR 1989]

A. \[{{H}_{2}}O\]
B. \[N{{H}_{3}}\]
C. \[C{{H}_{4}}\]
D. \[PC{{l}_{5}}\]
Answer» C. \[C{{H}_{4}}\]
653.

Ge(II)compounds are powerful reducing agents whereas Pb(IV)compounds are strong oxidants. It is because

A. Pb is more electropositive than Ge
B. ionization potential of lead is less than that of Ge
C. ionic radii of \[P{{b}^{2+}}\]and \[P{{b}^{4+}}\] are larger than those of \[G{{e}^{2+}}\] and \[G{{e}^{4+}}\]
D. of more pronounced inert pair effect in lead than in Ge
Answer» E.
654.

Which of the following set of quantum numbers is possible

A. \[n=3;\,\,l=2;\,\,m=2\] and \[s=+\frac{1}{2}\]
B. \[n=3;\,\,l=4;\,\,m=0\] and \[s=-\frac{1}{2}\]
C. \[n=4;\,l=0;\,\,m=2\] and \[s=+\frac{1}{2}\]
D. \[n=4;\,\,l=4;\,\,m=3\] and \[s=+\frac{1}{2}\]
Answer» B. \[n=3;\,\,l=4;\,\,m=0\] and \[s=-\frac{1}{2}\]
655.

Which of the following sets of quantum numbers is correct for an electron in \[4f\] orbital

A. \[n=4,\,l=3,\,m=+1,\,s=+\frac{1}{2}\]
B. \[n=4,\,l=4,\,m=-4,\,s=-\frac{1}{2}\]
C. \[n=4,\,l=3,\,m=+4,\,s=+\frac{1}{2}\]
D. \[n=3,\,l=2,\,m=-2,\,s=+\frac{1}{2}\]
Answer» B. \[n=4,\,l=4,\,m=-4,\,s=-\frac{1}{2}\]
656.

To what extent must a given solution of concentration of 40 mg silver nitrate per ml be diluted to yield a solution of concentration of 16 mg \[AgN{{O}_{3}}\] per ml [NCERT 1977]

A. Each ml must be diluted to 2.5 ml
B. To each ml of solution 2.5 ml of water should be added
C. To 2.5 ml of solution 2 ml of water should be added
D. To 1.5 ml of solution 1.5 ml of water should be added
Answer» B. To each ml of solution 2.5 ml of water should be added
657.

Washing soap can be prepared by saponification with alkali of the oil      [CPMT 1986]

A. Rose oil
B. Paraffin oil
C. Groundnut oil
D. Kerosene
Answer» D. Kerosene
658.

The volume of a gas decreases from \[500\,cc\] to \[300\,cc\] when a sample of gas is compressed by an average pressure of 0.6 atm. During this process 10 J of heat is liberated. The change in internal energy is              [Pb. PMT 2000]

A. ? 2.16 J
B. 12.156 J
C. 2.16 J
D. 101.3 J
Answer» D. 101.3 J
659.

The energy of a photon is calculated by                 [Pb. PMT 2000]

A. \[E=h\nu \]
B. \[h=E\nu \]
C. \[h=\frac{E}{\nu }\]
D. \[E=\frac{h}{\nu }\]
Answer» B. \[h=E\nu \]
660.

When acetic acid and \[{{K}_{4}}Fe{{\left( CN \right)}_{6}}\] is added to a copper salt, a chocolate precipitate is obtained of the compound

A. Copper cyanide
B. Copper ferrocyanide
C. Basic copper sulphate
D. Basic copper cyanide
Answer» C. Basic copper sulphate
661.

10 mL, of a strong acid solution of \[pH=2.000\] are mixed with 990 mL of another strong acid solution of \[pH=4.000\]. The pH of the resulting solution will be:

A. 4.002
B. 4.000
C. 4.200
D. 3.7
Answer» E.
662.

Conjugate base of \[NH_{4}^{+}\] is

A. \[N{{H}_{3}}\]
B. \[NH_{2}^{-}\]
C. \[N{{H}_{4}}OH\]
D. \[C{{l}^{-}}\]
Answer» B. \[NH_{2}^{-}\]
663.

The correct order of acidic strength is:

A. \[C{{l}_{2}}{{O}_{7}}>S{{O}_{2}}>{{P}_{4}}{{O}_{10}}\]
B. \[C{{O}_{2}}>{{N}_{2}}{{O}_{5}}>S{{O}_{3}}\]
C. \[N{{a}_{2}}O>MgO>A{{l}_{2}}{{O}_{3}}\]
D. \[{{K}_{2}}O>CaO>MgO\]
Answer» B. \[C{{O}_{2}}>{{N}_{2}}{{O}_{5}}>S{{O}_{3}}\]
664.

Which of the following contains asymmetric centre [CPMT 1996]

A. 2-butene
B. 2, 2-dimethylpropane
C. 2-hexyne
D. Lactic acid
Answer» E.
665.

Number of isomers of molecular formula \[{{C}_{2}}{{H}_{2}}B{{r}_{2}}\] are [CPMT 1987]

A. 1
B. 2
C. 3
D. 0
Answer» D. 0
666.

Which of the following compounds may not exist as enantiomers [CPMT 1987]

A. \[C{{H}_{3}}CH(OH)C{{O}_{2}}H\]
B. \[C{{H}_{3}}C{{H}_{2}}CH(C{{H}_{3}})C{{H}_{2}}OH\]
C. \[{{C}_{6}}{{H}_{5}}C{{H}_{2}}C{{H}_{3}}\]
D. \[{{C}_{6}}{{H}_{5}}CHClC{{H}_{3}}\]
Answer» D. \[{{C}_{6}}{{H}_{5}}CHClC{{H}_{3}}\]
667.

An electron, a proton and an alpha particle have kinetic energies of 16E, 4E and E respectively. What is the qualitative order of their de-Broglie wavelengths?

A. \[{{\lambda }_{e}}>{{\lambda }_{p}}={{\lambda }_{\alpha }}\]
B. \[{{\lambda }_{p}}={{\lambda }_{\alpha }}={{\lambda }_{e}}\]
C. \[{{\lambda }_{p}}>{{\lambda }_{e}}>{{\lambda }_{\alpha }}\]
D. \[{{\lambda }_{\alpha }}<{{\lambda }_{e}}>{{\lambda }_{p}}\]
Answer» B. \[{{\lambda }_{p}}={{\lambda }_{\alpha }}={{\lambda }_{e}}\]
668.

On moving down the group gradually increase

A. Oxidising property
B. Electronegativity
C. Acidic property
D. Metallic property
Answer» E.
669.

An ion which has 18 electrons in the outermost shell is

A. \[{{K}^{+}}\]
B. \[C{{a}^{2+}}\]
C. \[N{{a}^{+}}\]
D. \[C{{u}^{+}}\]
Answer» E.
670.

Which of the following electronic configurations in the outermost shell is characteristic of alkali metals [Bihar CEE 1992]

A. \[(n-1)\,{{s}^{2}}{{p}^{6}},\,n{{s}^{2}}{{p}^{1}}\]
B. \[(n-1)\,{{s}^{2}}{{p}^{6}}{{d}^{10}},\,n{{s}^{1}}\]
C. \[(n-1)\,{{s}^{2}}{{p}^{6}},\,n{{s}^{1}}\]
D. \[n{{s}^{2}}{{p}^{6}}{{d}^{1}}\]
Answer» D. \[n{{s}^{2}}{{p}^{6}}{{d}^{1}}\]
671.

Lactic acid shows which type of isomerism [CPMT 1987; MP PMT 1987; BHU 2003]

A. Geometrical isomerism
B. Tautomerism
C. Optical isomerism
D. Metamerism
Answer» D. Metamerism
672.

The orbital angular momentum for an electron revolving in an orbit is given by \[\sqrt{l(l+1)}\frac{h}{2\pi }\]. This momentum for \[{{d}^{5}},\,{{d}^{6}},\,{{p}^{3}}\] electron will be respectively

A. \[\sqrt{6}\,\frac{h}{2\pi },\,\sqrt{7}\,\frac{h}{2\pi },\,\sqrt{2}\,\frac{h}{2\pi }\]
B. \[0\,\frac{\sqrt{6}h}{2\pi },\,\frac{\sqrt{2}h}{2\pi }\]
C. \[\sqrt{6}\,\frac{h}{2\pi },\,\sqrt{6}\frac{6}{2\pi },\,\sqrt{2}\frac{h}{2\pi }\]
D. \[\sqrt{6}\,\frac{h}{2\pi },\,\sqrt{6}\frac{h}{2\pi },\,\sqrt{3}\frac{h}{2\pi }\]
Answer» D. \[\sqrt{6}\,\frac{h}{2\pi },\,\sqrt{6}\frac{h}{2\pi },\,\sqrt{3}\frac{h}{2\pi }\]
673.

The correct order of thermal stability of hydroxides is:

A. \[Ba{{(OH)}_{2}}<Ca{{(OH)}_{2}}<Sr{{(OH)}_{2}}<Mg{{(OH)}_{2}}\]
B. \[Mg{{(OH)}_{2}}<Sr{{(OH)}_{2}}<Ca{{(OH)}_{2}}<Ba{{(OH)}_{2}}\]
C. \[Mg{{(OH)}_{2}}<Ca{{(OH)}_{2}}<Sr{{(OH)}_{2}}<Ba{{(OH)}_{2}}\]
D. \[Ba{{(OH)}_{2}}<Sr{{(OH)}_{2}}<Ca{{(OH)}_{2}}<Mg{{(OH)}_{2}}\]
Answer» E.
674.

Which of the following about wave function \[\psi \] is not correct?

A. \[\psi \] may be a real valued wave function
B. \[\psi \] may be in some cases be a complex function
C. \[\psi \] has a mathematical significance only
D. \[\psi \] is proportional to the probability of finding an electron
Answer» E.
675.

Calculate \[\Delta {{H}^{o}}\] for evaporation of \[{{H}_{2}}O(l)\] \[{{H}_{2}}+\frac{1}{2}{{O}_{2}}\xrightarrow{\,}\,{{H}_{2}}O(l);\Delta H=285.77\,\,kJ\] ?(i) \[{{H}_{2}}+\frac{1}{2}{{O}_{2}}\xrightarrow{\,}\,{{H}_{2}}O(g);\,\Delta H=241.84\,\,kJ\]?(ii)

A. + 43.93 kJ
B. - 43.93 kJ
C. 527.61 kJ
D. - 527.61 kJ
Answer» C. 527.61 kJ
676.

The heat of neutralization of four acids A, B, C, D are -13.7, -9.4, - 11.2 and - 12.4 kcal, respectively, when they are neutralized by a common base. The acidic character obeys the order:

A. A > B > C < D
B. A > D > C> B
C. D > C > B > A
D. D > B > C > A
Answer» C. D > C > B > A
677.

The enthalpies of formation of \[A{{l}_{2}}{{O}_{3}}\] and \[C{{r}_{2}}{{O}_{3}}\] 1596 kJ and - 1134 kJ respectively. \[\Delta H\] for the reaction \[2Al+C{{r}_{2}}{{O}_{3}}\to 2Cr+A{{l}_{2}}{{O}_{3}}\]

A. - 2730 kJ
B. - 462 kJ
C. - 1365 kJ
D. + 2730 kJ
Answer» C. - 1365 kJ
678.

How many molecules are present in one gram of hydrogen [AIIMS 1982]

A. \[6.02\times {{10}^{23}}\]
B. \[3.01\times {{10}^{23}}\]
C. \[2.5\times {{10}^{23}}\]
D. \[1.5\times {{10}^{23}}\]
Answer» C. \[2.5\times {{10}^{23}}\]
679.

Three dimensional molecules with cross links are formed in the case of a              [KCET 2005]

A. Thermoplastic
B. Thermosetting plastic
C. Both
D. None
Answer» C. Both
680.

Bond length of ethane (I), ethene (II), acetylene (III), and benzene (IV) follows the order:

A. \[I>II>III>IV\]
B. \[I>II>IV>III\]
C. \[I>IV>II>III\]
D. \[III>IV>II>I\]
Answer» D. \[III>IV>II>I\]
681.

Amongst the following, the total number of species which does/do not exist is : \[S{{F}_{6}},B{{F}_{6}}^{3-},S{{F}_{4}},O{{F}_{4}},Al{{F}_{6}}^{3-},P{{H}_{5}},PC{{l}_{5}},NC{{l}_{5}},SC{{l}_{6}}\]

A. 9
B. 5
C. 6
D. 8
Answer» C. 6
682.

Most favorable condition for ionic bonding are:

A. low charge on ions, large cations, small anions
B. low charge on ions, large cations, large anions
C. high charge on ions, small cations, large anions
D. high charge on ions, large cations, small anions
Answer» B. low charge on ions, large cations, large anions
683.

Racemic mixture is formed by mixing two [AIEEE 2002]

A. Isomeric compounds
B. Chiral compounds
C. Meso compounds
D. Optical isomers
Answer» C. Meso compounds
684.

\[\underset{H}{\overset{{{H}_{3}}C}{\mathop{{}}}}\,>C=CC=C< & {}  \\    \,\,\,\,H & {} & C{{H}_{3}}  \\ \end{matrix}\]exhibit which isomerism [MP PET 2002]

A. Position isomerism
B. Geometrical isomerism
C. Optical isomerism
D. Functional  isomerism
Answer» C. Optical isomerism
685.

\[BC{{l}_{3}}\] is a planar molecule whereas \[NC{{l}_{3}}\] is pyramidal because

A. \[BC{{l}_{3}}\] has no lone pair of electrons but \[NC{{l}_{3}}\] has a lone pair of electrons.
B. \[B-Cl\] bond is more polar than \[N-Cl\] bond.
C. nitrogen atom is smaller than boron atom.
D. \[N-Cl\] bond is more covalent than \[B-Cl\] bond.
Answer» B. \[B-Cl\] bond is more polar than \[N-Cl\] bond.
686.

To a piece of charcoal, sulphuric acid is added. Then:

A. there is no reaction
B. water gas is formed
C. \[S{{O}_{2}}\] and \[C{{O}_{2}}\] are evolved
D. CO and \[S{{O}_{2}}\] are evolved
Answer» D. CO and \[S{{O}_{2}}\] are evolved
687.

The solubility product of \[BaS{{O}_{4}}\] is \[1.3\times {{10}^{-9}}\]. The solubility of this salt in pure water will be          [MP PET 2002]

A. \[1.69\times {{10}^{-9}}mol\,litr{{e}^{-1}}\]
B. \[1.69\times {{10}^{-18}}mol\,litr{{e}^{-1}}\]
C. \[3.6\times {{10}^{-18}}mol\,litr{{e}^{-1}}\]
D. \[3.6\times {{10}^{-5}}mol\,litr{{e}^{-1}}\]
Answer» E.
688.

In the following metals which one has lowest probable interatomic forces                                            [MP PMT 1990]

A. Copper
B. Silver
C. Zinc
D. Mercury
Answer» E.
689.

Which one of the following removes temporary hardness of water

A. Slaked lime
B. Plaster of Paris
C. Cuprous
D. Hydrolith
Answer» B. Plaster of Paris
690.

Quartz is a crystalline variety of                 [Pb. PMT 2000]

A. Silica
B. Sodium silicate
C. Silicon carbide
D. Silicon
Answer» B. Sodium silicate
691.

The radius of the nucleus is related to the mass number \[A\]  by                             [EAMCET 1998]

A. \[R={{R}_{o}}{{A}^{1/2}}\]
B. \[R={{R}_{o}}A\]
C. \[R={{R}_{o}}{{A}^{2}}\]
D. \[R={{R}_{o}}{{A}^{1/3}}\]
Answer» E.
692.

Which of the following species would be least likely to act as Lewis base?

A. \[PC{{l}_{3}}\]
B. \[C{{N}^{-}}\]
C. \[SC{{l}_{2}}\]
D. \[{{I}^{+}}\]
Answer» E.
693.

Which of the following cannot have a conjugate base?

A. \[{{H}_{2}}PO_{2}^{-}\]
B. \[HCO_{3}^{-}\]
C. \[{{H}_{2}}{{O}_{2}}\]
D. \[HSO_{4}^{-}\]
Answer» B. \[HCO_{3}^{-}\]
694.

If acetic acid is 1.0% ionised in its decinormal solution, then pH of its seminormal solution will be

A. 3.4
B. 4.8
C. 1.6
D. 2.6
Answer» E.
695.

The least number of oxyacids are formed by:

A. Chlorine
B. Nitrogen
C. Fluorine
D. Sulphur
Answer» D. Sulphur
696.

Which of the following halogen acids is least acidic   [RPET 2003]

A. HI
B. HCl
C. HF
D. HBr
Answer» D. HBr
697.

\[{{N}_{0}}/2\] atoms of X(g) are converted into \[{{X}^{+}}(g)\] by energy E. \[{{N}_{0}}/2\] atoms of X(g) are converted into \[{{X}^{-}}(g)\] by energy \[{{E}_{2}}\]. Hence, ionization potential and electron affinity of X(g) are

A. \[\frac{2{{E}_{1}}}{{{N}_{0}}},\frac{2({{E}_{1}}-{{E}_{2}})}{{{N}_{0}}}\]
B. \[\frac{2{{E}_{1}}}{{{N}_{0}}},\frac{2{{E}_{2}}}{{{N}_{0}}}\]
C. \[\frac{({{E}_{1}}-{{E}_{2}})}{{{N}_{0}}},\frac{2{{E}_{2}}}{{{N}_{0}}}\]
D. None is correct
Answer» C. \[\frac{({{E}_{1}}-{{E}_{2}})}{{{N}_{0}}},\frac{2{{E}_{2}}}{{{N}_{0}}}\]
698.

The number of molecules in 8.96 litre of a gas at  \[0{}^\circ C\] and 1 atm. pressure is approximately

A. \[6.023\times {{10}^{23}}\]
B. \[12.04\times {{10}^{23}}\]
C. \[18.06\times {{10}^{23}}\]
D. \[24.08\times {{10}^{22}}\]
Answer» E.
699.

What is the reagent used for testing fluoride ion in water [EAMCET 2003]

A. Alizarin - S
B. Quinalizarin
C. Phenolphthalein
D. Benzene
Answer» B. Quinalizarin
700.

The mobility of metal ions in aqueous medium \[(L{{i}^{+}},N{{a}^{+}},{{K}^{+}},R{{b}^{+}})\] in the electric field, follows the order

A. \[L{{i}^{+}}>N{{a}^{+}}>{{K}^{+}}>R{{b}^{+}}\]
B. \[R{{b}^{+}}>N{{a}^{+}}={{K}^{+}}>L{{i}^{+}}\]
C. \[L{{i}^{+}}<N{{a}^{+}}<{{K}^{+}}<R{{b}^{+}}\]
D. \[N{{a}^{+}}={{K}^{+}}>R{{b}^{+}}>L{{i}^{+}}\]
Answer» D. \[N{{a}^{+}}={{K}^{+}}>R{{b}^{+}}>L{{i}^{+}}\]