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This section includes 456 Mcqs, each offering curated multiple-choice questions to sharpen your Chemical Engineering knowledge and support exam preparation. Choose a topic below to get started.
301. |
For an isothermal reversible compression of an ideal gas_______________? |
A. | Only ΔE = 0 |
B. | Only ΔH =0 |
C. | ΔE = ΔH = 0 |
D. | dQ = dE |
Answer» D. dQ = dE | |
302. |
For an irreversible process involving only pressure-volume work____________________? |
A. | (dF)T, p <0 |
B. | (dF)T, p = 0 |
C. | (dF)T, p > 0 |
D. | (dA)T, v >0 |
Answer» B. (dF)T, p = 0 | |
303. |
For an isothermal process, the internal energy of a gas____________________? |
A. | Increases |
B. | Decreases |
C. | Remains unchanged |
D. | Data insufficient, can’t be predicted |
Answer» D. Data insufficient, can’t be predicted | |
304. |
For an incompressible fluid, the _______________ is a function of both pressure as well as temperature? |
A. | Internal energy |
B. | Enthalpy |
C. | Entropy |
D. | All (A), B. & (C) |
Answer» C. Entropy | |
305. |
For an ideal solution, the value of activity co-efficient is______________________? |
A. | 0 |
B. | 1 |
C. | < 1 |
D. | > 1 |
Answer» C. < 1 | |
306. |
For an ideal gas, the enthalpy__________________? |
A. | Increases with rise in pressure |
B. | Decreases with rise in pressure |
C. | Is independent of pressure |
D. | Is a path function |
Answer» D. Is a path function | |
307. |
For an ideal gas, the internal energy depends upon its ____________ only? |
A. | Molecular size |
B. | Temperature |
C. | Volume |
D. | Pressure |
Answer» C. Volume | |
308. |
For an ideal gas, the chemical potential is given by______________? |
A. | RT d ln P |
B. | R d ln P |
C. | R d ln f |
D. | None of these |
Answer» B. R d ln P | |
309. |
For an ideal gas, the activity co-efficient is_________________? |
A. | Directly proportional to pressure |
B. | Inversely proportional to pressure |
C. | Unity at all pressures |
D. | None of these |
Answer» D. None of these | |
310. |
For an exothermic reaction ____________________? |
A. | Only enthalpy change (ΔH) is negative |
B. | Only internal energy change (ΔE) is negative |
C. | Both ΔH and ΔE are negative |
D. | Enthalpy change is zero |
Answer» D. Enthalpy change is zero | |
311. |
For a thermodynamic system containing ‘x’ chemical species, the maximum number of phases that can co-exist at equilibrium is_________________? |
A. | x |
B. | x + 1 |
C. | x + 2 |
D. | x + 3 |
Answer» D. x + 3 | |
312. |
For a stable phase at constant pressure and temperature, the fugacity of each component in a binary system _____________ as its mole fraction increases? |
A. | Decreases |
B. | Increases |
C. | Remain same |
D. | Decreases linearly |
Answer» C. Remain same | |
313. |
For a spontaneous process, free energy__________________? |
A. | Is zero |
B. | Increases |
C. | Decreases whereas the entropy increases |
D. | And entropy both decrease |
Answer» D. And entropy both decrease | |
314. |
For a single component two phase mixture, the number of independent variable properties are_________________? |
A. | Two |
B. | One |
C. | Zero |
D. | Three |
Answer» C. Zero | |
315. |
For a reversible process involving only pressure-volume work____________________? |
A. | (dF)T, p 0 |
B. | (dF)T, p = 0 |
C. | (dA)T, v < 0 |
D. | None of these |
Answer» C. (dA)T, v < 0 | |
316. |
For a real gas, the chemical potential is given by_____________________? |
A. | RT d ln P |
B. | RT d ln f |
C. | R d ln f |
D. | None of these |
Answer» C. R d ln f | |
317. |
For a multi-component system, the term chemical potential is equivalent to the ___________________? |
A. | Molal concentration difference |
B. | Molar free energy |
C. | Partial molar free energy |
D. | Molar free energy change |
Answer» D. Molar free energy change | |
318. |
For a given substance at a specified temperature, activity is ______________ to fugacity? |
A. | Directly proportional |
B. | Inversely proportional |
C. | Equal |
D. | None of these |
Answer» B. Inversely proportional | |
319. |
For a cyclic process, a fixed ratio between heat and work___________________? |
A. | Always exists |
B. | May exist |
C. | Never exists |
D. | Is difficult to predict |
Answer» B. May exist | |
320. |
For a constant volume process_________________? |
A. | dE = CpdT |
B. | dE = CvdT |
C. | dQ = dE + pdV |
D. | dW = pdV |
Answer» C. dQ = dE + pdV | |
321. |
For a constant volume process _____________ by the system is used only to increase the internal energy? |
A. | Heat absorbed |
B. | Work done |
C. | Both A. & B |
D. | Neither A. nor B |
Answer» B. Work done | |
322. |
For a constant pressure reversible process, the enthalpy change (ΔH) of the system is___________________? |
A. | Cv.dT |
B. | Cp.dT |
C. | ∫ Cp.dT |
D. | ∫ Cv.dT |
Answer» D. ∫ Cv.dT | |
323. |
First law of thermodynamics deals with the ___________________? |
A. | Direction of energy transfer |
B. | Reversible processes only |
C. | Irreversible processes only |
D. | None of these |
Answer» B. Reversible processes only | |
324. |
Filling of gas from a high pressure cylinder into small bottles is an example of a/an ______________ process? |
A. | Equilibrium |
B. | Adiabatic |
C. | Steady |
D. | Unsteady |
Answer» E. | |
325. |
Extensive properties of a thermodynamic system depend upon the _____________ of the system? |
A. | Specific volume |
B. | Temperature |
C. | Mass |
D. | Pressure |
Answer» D. Pressure | |
326. |
____________ explains the equilibrium constant for any chemical reaction? |
A. | Henry’s law |
B. | Law of mass action |
C. | Hess’s law |
D. | None of these |
Answer» C. Hess’s law | |
327. |
(∂E/∂T)V is the mathematical expression for____________________? |
A. | CV |
B. | Enthalpy change |
C. | Free energy change |
D. | None of these |
Answer» E. | |
328. |
Equilibrium constant of a reaction varies with the____________________? |
A. | Initial concentration of the reactant |
B. | Pressure |
C. | Temperature |
D. | None of these |
Answer» D. None of these | |
329. |
Equilibrium constant decreases as the temperature___________________? |
A. | Increases, for an exothermic reaction |
B. | Decreases, for an exothermic reaction |
C. | Increases, for an endothermic reaction |
D. | None of these |
Answer» B. Decreases, for an exothermic reaction | |
330. |
Equation which relates pressure, volume and temperature of a gas is called the__________________? |
A. | Equation of state |
B. | Gibbs Duhem equation |
C. | Ideal gas equation |
D. | None of these |
Answer» B. Gibbs Duhem equation | |
331. |
______________ Equation predicts the activity co-efficient from experimental data ? |
A. | Lewis-Randall |
B. | Margules |
C. | Van Laar |
D. | Both B. & C. |
Answer» E. | |
332. |
Entropy, which is a measure of the disorder of a system, is__________________? |
A. | Independent of pressure |
B. | Independent of temperature |
C. | Zero at absolute zero temperature for a perfect crystalline substance |
D. | All A, B. & C |
Answer» D. All A, B. & C | |
333. |
Entropy of the system decreases, when_______________? |
A. | Snow melts into water |
B. | A gas expands spontaneously from high pressure to low pressure |
C. | Water is converted into ice |
D. | Both B. & C |
Answer» E. | |
334. |
Entropy of an ideal gas depends upon its__________________? |
A. | Pressure |
B. | Temperature |
C. | Both A. & B |
D. | Neither A. nor B |
Answer» D. Neither A. nor B | |
335. |
Entropy of a substance remains constant during a/an ____________ change? |
A. | Reversible isothermal |
B. | Irreversible isothermal |
C. | Reversible adiabatic |
D. | None of these |
Answer» D. None of these | |
336. |
Entropy is a/an___________________? |
A. | State function |
B. | Macroscopic property |
C. | Extensive property |
D. | None of these |
Answer» E. | |
337. |
Entropy is a measure of the _____________ of a system? |
A. | Disorder |
B. | Orderly behaviour |
C. | Temperature changes only |
D. | None of these |
Answer» B. Orderly behaviour | |
338. |
Entropy change of the reaction, H2O (liquid) → H2O (gas), is termed as the enthalpy of___________________? |
A. | Solution |
B. | Vaporisation |
C. | Formation |
D. | Sublimation |
Answer» C. Formation | |
339. |
Entropy change of mixing two liquid substances depends upon the_________________? |
A. | Molar concentration |
B. | Quantity (i.e. number of moles) |
C. | Both A. and B |
D. | Neither A. nor B |
Answer» D. Neither A. nor B | |
340. |
Entropy change in case of reversible adiabatic process is________________? |
A. | Minimum |
B. | Zero |
C. | Maximum |
D. | Indeterminate |
Answer» C. Maximum | |
341. |
Entropy change for an irreversible process taking system and surrounding together is___________________? |
A. | 0 |
B. | > 0 |
C. | < 0 |
D. | None of these |
Answer» C. < 0 | |
342. |
Entropy change for an irreversible isolated system is__________________? |
A. | ∞ |
B. | 0 |
C. | < 0 |
D. | > 0 |
Answer» E. | |
343. |
Enthalpy of a gas depends upon its___________________? |
A. | Temperature |
B. | Mass |
C. | Volume |
D. | Pressure |
Answer» B. Mass | |
344. |
Enthalpy ‘H’ is defined as___________________? |
A. | H = E – PV |
B. | H = F – TS |
C. | H – E = PV |
D. | None of these |
Answer» D. None of these | |
345. |
Enthalpy changes over a constant pressure path are always zero for ______________ gas? |
A. | Any |
B. | A perfect |
C. | An easily liquefiable |
D. | A real |
Answer» C. An easily liquefiable | |
346. |
Efficiency of a heat engine working on Carnot cycle between two temperature levels depends upon the__________________? |
A. | Two temperatures only |
B. | Pressure of working fluid |
C. | Mass of the working fluid |
D. | Mass and pressure both of the working fluid |
Answer» B. Pressure of working fluid | |
347. |
Efficiency of a Carnot engine working between temperatures T1 and T2 (T1 < T) is ________________? |
A. | (T2 – T1)/T2 |
B. | (T2 – T1)/T1 |
C. | (T1 – T2)/T2 |
D. | (T1 – T2)/T1 |
Answer» B. (T2 – T1)/T1 | |
348. |
dW and dq are not the exact differential, because q and W are__________________? |
A. | State functions |
B. | Path functions |
C. | Intensive properties |
D. | Extensive properties |
Answer» C. Intensive properties | |
349. |
During the phase transition, _______________ changes? |
A. | Pressure |
B. | Volume |
C. | Temperature |
D. | All A , B. and C |
Answer» C. Temperature | |
350. |
During Joule-Thomson expansion of gases_________________? |
A. | Enthalpy remains constant |
B. | Entropy remains constant |
C. | Temperature remains constant |
D. | None of these |
Answer» B. Entropy remains constant | |