Explore topic-wise MCQs in Chemical Engineering.

This section includes 456 Mcqs, each offering curated multiple-choice questions to sharpen your Chemical Engineering knowledge and support exam preparation. Choose a topic below to get started.

151.

PVγ = Constant (where, γ = Cp/Cv) is valid for a/an ______________ process?

A. Isothermal
B. Isentropic
C. Isobaric
D. Adiabatic
Answer» E.
152.

Pressure-enthalpy chart is useful in refrigeration. The change in internal energy of an ideal fluid used in ideal refrigeration cycle is_____________________?

A. Positive
B. Negative
C. Zero
D. Infinity
Answer» D. Infinity
153.

Pick out the wrong statement_________________?

A. Phase rule variables are intensive properties
B. Heat and work are both state function
C. The work done by expansion of a gas in vacuum is zero
D. CP and CV are state function
Answer» C. The work done by expansion of a gas in vacuum is zero
154.

Pick out the wrong statement pertaining to the decomposition of PCl5 represented by, PCl5 ⇌ PCl3 + Cl2.Degree of dissociation of PCl5 will_________________?

A. Decrease on addition of Cl2
B. Increase on addition of an inert gas at constant pressure
C. Decrease on increasing the pressure of the system
D. None of these
Answer» E.
155.

Pick out the wrong statement. A. The conversion for a gas phase reaction increases with decrease in pressure, if there is an increase in volume accompanying the reaction________________?

A. With increase in temperature, the equilibrium constant increases for an exothermic reaction
B. The equilibrium constant of a reaction depends upon temperature only
C. The conversion for a gas phase reaction increases with increase in pressure, if there is a decrease in volume accompanying the reaction
Answer» B. The equilibrium constant of a reaction depends upon temperature only
156.

Pick out the undesirable property for a good refrigerant ?

A. High thermal conductivity
B. Low freezing point
C. Large latent heat of vaporisation
D. High viscosity
Answer» E.
157.

Pick out the correct equation relating ‘F’ and ‘A’___________________?

A. F = A + PV
B. F = E + A
C. F = A – TS
D. F = A + TS
Answer» B. F = E + A
158.

Pick out the Clausius-Clapeyron equation from the following?

A. dP/dT = ΔH/TΔV
B. ln P = – (ΔH/RT) + constant
C. ΔF = ΔH + T [∂(ΔF)/∂T]P
D. None of these
Answer» C. ΔF = ΔH + T [∂(ΔF)/∂T]P
159.

Partial molar free energy of an element A in solution is same as its__________________?

A. Chemical potential
B. Activity
C. Fugacity
D. Activity co-efficient
Answer» B. Activity
160.

Out of the following refrigeration cycles, which one has the minimum COP (Co-efficient of performance) ?

A. Air cycle
B. Carnot cycle
C. Ordinary vapour compression cycle
D. Vapour compression with a reversible expansion engine
Answer» B. Carnot cycle
161.

One ton of refrigeration is defined as the heat rate corresponding to melting of one ton of ice in one ________________?

A. Hour
B. Day
C. Minute
D. Second
Answer» C. Minute
162.

One ton of refrigeration capacity is equivalent to the heat removal rate of____________________?

A. 50 kcal/hr
B. 200 BTU/hr
C. 200 BTU/minute
D. 200 BTU/day
Answer» D. 200 BTU/day
163.

One mole of nitrogen at 8 bar and 600 K is contained in a piston-cylinder arrangement. It is brought to 1 bar isothermally against a resisting pressure of 1 bar. The work done (in Joules) by the gas is_________________?

A. 30554
B. 10373
C. 4988.4
D. 4364.9
Answer» C. 4988.4
164.

On opening the door of an operating refrigerator kept in a closed room, the temperature of the room will____________________?

A. Increase
B. Decrease
C. Remain same
D. Increase in summer and will decrease in winter
Answer» B. Decrease
165.

On a P-V diagram of an ideal gas, suppose a reversible adiabatic line intersects a reversible isothermal line at point A. Then at a point A, the slope of the reversible adiabatic line (∂P/∂V)s and the slope of the reversible isothermal line (∂P/∂V)T are related as (where, y = Cp/Cv) ?

A. (∂P/∂V)S = (∂P/∂V)T
B. (∂P/∂V)S = [(∂P/∂V)T]Y
C. (∂P/∂V)S = y(∂P/∂V)T
D. (∂P/∂V)S = 1/y(∂P/∂V)T
Answer» D. (∂P/∂V)S = 1/y(∂P/∂V)T
166.

Number of phases in a colloidal system is_____________________?

A. 1
B. 2
C. 3
D. 4
Answer» C. 3
167.

Number of degrees of freedom for a three phase system in equilibrium comprising of three non-reacting chemical species is__________________?

A. 2
B. 0
C. 1
D. 3
Answer» B. 0
168.

Number of components (C), phase (P) and degrees of freedom (F) are related by Gibbs phase rule as________________?

A. P + F – C = 2
B. C = P – F + 2
C. F = C – P – 2
D. P = F – C – 2
Answer» B. C = P – F + 2
169.

Normal temperature and pressure (N.T.P.) corresponds to ___________________?

A. 0°C and 760 mm Hg
B. 15°C and 760 mm Hg
C. 20°C and 760 mm Hg
D. 0°C and 1 kgf/cm2
Answer» D. 0°C and 1 kgf/cm2
170.

No work is done by the system, when a reaction occurs at constant__________________?

A. Volume
B. Temperature
C. Pressure
D. None of these
Answer» B. Temperature
171.

Near their critical temperatures, all gases occupy volumes _____________ that of the ideal gas?

A. Less than
B. Same as
C. More than
D. Half
Answer» B. Same as
172.

Mollier diagram is a plot of___________________?

A. Temperature vs. enthalpy
B. Temperature vs. enthalpy
C. Entropy vs. enthalpy
D. Temperature vs. internal energy
Answer» D. Temperature vs. internal energy
173.

Mollier chart is a _____________ plot?

A. Pressure vs. enthalpy
B. Pressure vs. volume
C. Enthalpy vs. entropy
D. Temperature vs. entropy
Answer» D. Temperature vs. entropy
174.

Molar heat capacity of water in equilibrium with ice at constant pressure is __________ Kcal/kg mole. °K___________________?

A. 0
B.
C. 50
D. 100
Answer» C. 50
175.

Minimum number of phases that exists in a system is 1. Number of chemical species in a colloidal system is__________________?

A. 1
B. 2
C. 3
D. 4
Answer» C. 3
176.

Melting of wax is accompanied with ______________ in entropy?

A. Increase
B. Decrease
C. No change
D. None of these
Answer» B. Decrease
177.

Melting of ice is an example of an _____________ process?

A. Adiabatic
B. Isothermal
C. Isometric
D. None of these
Answer» C. Isometric
178.

Melting of ice exemplifies a/an______________________?

A. Adiabatic process
B. Endothermic reaction
C. Exothermic reaction
D. Process involving a chemical reaction
Answer» C. Exothermic reaction
179.

Measurement of thermodynamic property of temperature is facilitated by ____________ law of thermodynamics?

A. 1st
B. Zeroth
C. 3rd
D. None of these
Answer» C. 3rd
180.

Maxwell’s relation corresponding to the identity, dH = dS = Vdp + Σμi dni is_____________________?

A. (∂T/∂V)S, ni = -(∂P/∂S)V, ni
B. (∂S/∂P)T, ni = (∂V/∂T)P, ni
C. (∂S/∂V)T, ni = (∂P/∂T)V, ni
D. (∂T/∂P)S, ni = (∂V/∂S)P, ni
Answer» E.
181.

Maximum work that could be secured by expanding the gas over a given pressure range is the _____________ work?

A. Isothermal
B. Adiabatic
C. Isentropic
D. None of these
Answer» B. Adiabatic
182.

Lowering of condenser temperature (keeping the evaporator temperature constant) in case of vapour compression refrigeration system results in__________________?

A. Increased COP
B. Same COP
C. Decreased COP
D. Increased or decreased COP; depending upon the type of refrigerant
Answer» B. Same COP
183.

Linde gas liquefaction process employs cooling ____________________?

A. By throttling
B. By expansion in an engine
C. At constant pressure
D. None of these
Answer» B. By expansion in an engine
184.

Lenz’s law results from the law of conservation of___________________?

A. Mass
B. Momentum
C. Energy
D. None of these
Answer» D. None of these
185.

_____________ law of thermodynamics ascertains the direction of a particular spontaneous process?

A. Zeroth
B. First
C. Second
D. Third
Answer» D. Third
186.

“Law of corresponding states” says that___________________?

A. Two different gases behave similarly, if their reduced properties (i.e. P, V and T) are same
B. The surface of separation (i. e. the meniscus) between liquid and vapour phase disappears at the critical temperature
C. No gas can be liquefied above the critical temperature, howsoever high the pressure may be.
D. The molar heat of energy of gas at constant volume should be nearly constant (about 3 calories)
Answer» B. The surface of separation (i. e. the meniscus) between liquid and vapour phase disappears at the critical temperature
187.

Kopp’s rule is used to calculate the heat capacity of___________________?

A. Solids
B. Liquids
C. Gases
D. All (A), B. & (C)
Answer» B. Liquids
188.

Joule-Thomson experiment is__________________?

A. Isobaric
B. Adiabatic
C. Isenthalpic
D. Both B. & C.
Answer» E.
189.

Joule-Thomson co-efficient which is defined as, η = (∂T/∂P)H = 1/Cp (∂H/∂T)P, changes sign at a temperature known as inversion temperature. The value of Joule-Thomson co-efficient at inversion temperature is ___________________?

A. 0
B.
C. +ve
D. -ve
Answer» B. ∞
190.

Joule-Thomson effect i.e., a throttling process is a constant _____________ process?

A. Entropy
B. Temperature
C. Internal energy
D. Enthalpy
Answer» E.
191.

Joule-Thomson co-efficient is defined as__________________?

A. μ = (∂P/∂T)H
B. μ = (∂T/∂P)H
C. μ = (∂E/∂T)H
D. μ = (∂E/∂P)H
Answer» C. μ = (∂E/∂T)H
192.

Joule-Thomson co-efficient for a perfect gas is_____________________?

A. Zero
B. Positive
C. Negative
D. None of these
Answer» B. Positive
193.

Joule-Thomson co-efficient depends on the_____________________?

A. Pressure
B. Temperature
C. Both A. & B
D. Neither A. nor B
Answer» D. Neither A. nor B
194.

Joule-Thomson Co-efficient at any point on the inversion curve is___________________?

A.
B. +ve
C. 0
D. -ve
Answer» D. -ve
195.

Isotherm on an enthalpy-concentration diagram, for an ideal solution will be a __________________?

A. Straight line
B. Sine curve
C. Parabola
D. Hyperbola
Answer» B. Sine curve
196.

Isobaric process means a constant process ?

A. Temperature
B. Pressure
C. Volume
D. Entropy
Answer» C. Volume
197.

Isentropic process means a constant _____________________ process ?

A. Enthalpy
B. Pressure
C. Entropy
D. None of these
Answer» D. None of these
198.

is desired to bring about a certain change in the state of a system by performing work on the system under adiabatic conditions ?

A. The amount of work needed is path dependent
B. Work alone cannot bring out such a change of state
C. The amount of work needed is independent of path
D. More information is needed to conclude anything about the path dependence or otherwise of the work needed
Answer» B. Work alone cannot bring out such a change of state
199.

Internal energy of an element at 1 atm and 25° C is ____________ kcal/kg.mole?

A. 0
B. 273
C. 273
D. None of these
Answer» B. 273
200.

Internal energy of an ideal gas___________________?

A. Increases with increase in pressure
B. Decreases with increase in temperature
C. Is independent of temperature
D. None of these
Answer» E.