Explore topic-wise MCQs in Chemical Engineering.

This section includes 103 Mcqs, each offering curated multiple-choice questions to sharpen your Chemical Engineering knowledge and support exam preparation. Choose a topic below to get started.

1.

The vapor pressure of liquids of similar chemical nature at any particular temperature __________ with increase in the molecular weight.

A. decreases
B. increases
C. either ( or (; depends on the liquid
D. remains unchanged
Answer» B. increases
2.

A \'limiting reactant\' is the one, which decides the __________ in the chemical reacation.

A. conversion
B. equilibrium constant
C. none of these
D. rate constant
Answer» B. equilibrium constant
3.

__________ is an intensive property.

A. Refractive index
B. Temperature
C. none of these
D. Volume
Answer» D. Volume
4.

The heat change for the reaction, C(s) 2S(s) → CS2(l), is 104.2 kJ. It represents the heat of

A. solution
B. formation
C. fusion
D. combustion
Answer» C. fusion
5.

Under conditions of equal reduced pressure and equal reduced temperature, substances are said to be in the \'corresponding states\'. At equal reduced conditions i.e., at the corresponding state, the __________ of different gases are nearly

A. molecular weight
B. compressibility
C. none of these
D. humidity
Answer» C. none of these
6.

Assuming that CO2 obeys perfect gas law, calculate the density of CO2 (in kg/m3) at 263°C and 2 atm.

A. 2
B. 1
C. 4
D. 3
Answer» B. 1
7.

Heat capacity of air can be approximately expressed as, Cp = 26.693 7.365 x10-3 T, where, Cp is in J/mole.K and T is in K. The heat given off by 1 mole of air when cooled at atmospheric pressure from 500°C to - 100°C is

A. 16.15 kJ
B. 10.73 kJ
C. 18.33 kJ
D. 18.11 kJ
Answer» E.
8.

In the reaction, Ca 2H2O = Ca(OH)2 H2 ; what volume (c.c.) of hydrogen at STP would be liberated, when 8 gm of calcium reacts with excess water ? (atomic weight of calcium = 40)

A. 2240
B. 4480
C. 0.4
D. 1120
Answer» C. 0.4
9.

A gas at 0°C is cooled at constant pressure until its volume becomes half the original volume. The temperature of the gas at this state will be

A. -136.5°C
B. - 136.5°K
C. -273°C
D. 0°K
Answer» B. - 136.5°K
10.

An equation for calculating vapour pressure is given by, log 10 P = A - B(t + c). This is called the

A. Kistyakowsky equation
B. Antonic equation
C. Kopp's rule
D. Trouton's rule
Answer» C. Kopp's rule
11.

1 kg/m 2 is equal to __________ mm water column.

A. 1
B. 10
C. 100
D. 1000
Answer» B. 10
12.

For a neutral solution (pH = 7), the value of[H + ] [OH - ] is equal to

A. 0
B. 1
C. < 1
D. > 1
Answer» C. < 1
13.

Giga' stands for

A. 10 9
B. 10 -12
C. 10 12
D. 10 15
Answer» B. 10 -12
14.

One kg of saturated steam at 100°C and 1.01325 bar is contained in a rigid walled vessel. It lias a volume of 1.673 m 3 . It cools to 98°C ; the saturation pressure is 0.943 bar ; one kg of water vapour under these conditions has a volume of 1.789 m 3 . The latent heat of condensation (kJ/kg -1 ) under these conditions is

A. 40732
B. 2676
C. 2263
D. 540
Answer» D. 540
15.

For a given mass of a gas at constant temperature, if the volume ' V ' becomes three times, then the pressure ' P ' will become

A. P /3
B. 3 P
C. 9 P 2
D. 9 P
Answer» B. 3 P
16.

1 kg/cm 2 is equal to

A. 760 torr
B. 1KPa
C. 10 metres of water column
D. 1 metre of water column
Answer» D. 1 metre of water column
17.

What is the total pressure exerted by a mixture of 0.45 kg mole of benzene, 0.44 kg mole of toluene and 0.23 kg mole of o-xylene at 100°C, if their vapor pressures at 100°C are 1340, 560 and 210 mmHg respectively ?

A. 756.2
B. 780.5
C. 801.5
D. 880.5
Answer» D. 880.5
18.

C p is expressed in S.I. unit as

A. J/kg.°K
B. 0°K
C. W/m 2 . °C
D. W/m. °K
Answer» B. 0°K
19.

1 BTU/ft 3 is approximately equal to __________ kcal/m 3 .

A. 1
B. 9
C. 4
D. 252
Answer» C. 4
20.

At 100°C, water and methylcyclohexane both have vapour pressures of 1 atm. Also at 100°C, the latent heats of vaporisation of these compounds are 40.63 kJ/mole for water and 31.55 kJ/mole for methylcyclohexane. The vapour pressure of water at 150°C is 4.69 atm. At 150°C, the vapour pressure of methylcyclohexane would be expected to be

A. significantly less than 4.69 atm.
B. nearly equal to 4.69 atm.
C. significantly more than 4.69 atm.
D. indeterminate due to lack of data
Answer» D. indeterminate due to lack of data
21.

Enthalpy of formation of NH 3 is - 46 kJ/kg mole. The enthalpy change for the gaseous reaction, 2NH 3 ? N 2 + 3H 2 , is equal to __________ kJ/kg. mole.

A. 46
B. 92
C. -23
D. -92
Answer» C. -23
22.

__________ kg of CaC0 3 on heating will give 56 kg of CaO.

A. 56 .
B. 100
C. 144
D. 1000
Answer» C. 144
23.

The temperature of a gas in a closed container is 27° C. If the temperature of the gas is incresed to 300° C, then the pressure exerted is

A. doubled.
B. halved.
C. trebled.
D. unpredictable.
Answer» E.
24.

1 gm mole of methane (CH 4 ) contains

A. 6.02 x 10 23 atoms of hydrogen.
B. 4 gm atoms of hydrogen.
C. 3.01 x 10 23 molecules of methane.
D. 3 gms of carbon.
Answer» C. 3.01 x 10 23 molecules of methane.
25.

The value of gas constant ' R ' is __________ kcal/kg.mole.°C.

A. 2.79
B. 1.987
C. 3.99
D. none of these
Answer» E.
26.

Assume that benzene is insoluble in water. The normal boiling points of benzene and water are 80.1 and 100°C respectively. At a pressure of 1 atm, the boiling point of a mixture of benzene and water is

A. 80.1°C.
B. less than 80.1°C.
C. 100°C.
D. greater than 80.1°C but less than 100°C.
Answer» E.
27.

Which of the following holds good for a solution obeying Raoult's law (i.e., an ideal solution) (where, ? H = heat of mixing, and ? V = volume change on mixing ) ?

A. ? H = 1 (+ ve )and ? V = - ve
B. ? H = 0
C. ? V = 0
D. both (b) and (c)
Answer» E.
28.

One kg of saturated steam at 100°C and 1.01325 bar is contained in a rigid walled vessel. It lias a volume of 1.673 m 3 . It cools to 98°C ; the saturation pressure is 0.943 bar ; one kg of water vapour under these conditions has a volume of 1.789 m 3 . The amount of water vapour condensed (in kg) is

A. 0.0
B. 0.065
C. 0.1
D. 1.0
Answer» C. 0.1
29.

°API gravity of water at N.T.P. is about

A. 0
B. 1
C. 10
D. 100
Answer» D. 100
30.

Two solutions A 1 and A 2 have pH value of 2 and 6 respectively. It implies that the solution

A. A 2 is more alkaline than solution A 2
B. A 1 is highly acidic.
C. A 1 is very slightly acidic.
D. both (a) &(c).
Answer» E.
31.

The unit of specific heat at constant pressure, C p , in SI unit is

A. W/m 2 °C
B. J/kg°K
C. W/m°K
D. J/m 3 °K
Answer» C. W/m°K
32.

C p / C v for monoatomic gases is

A. 1.44
B. 1.66
C. 1.99
D. 1
Answer» C. 1.99
33.

The density of a liquid is 1500 kg/m 3 . Its value in gin/litre will be equal to

A. 1.5
B. 15
C. 150
D. 1500
Answer» E.
34.

The OH - concentration in a solution having pH value 3 is

A. 10 -3
B. 10 -10
C. 10 -11
D. 10 -13
Answer» D. 10 -13
35.

Cox' chart which is useful in the design of a distillation column (particularly suitable for petroleum hydrocarbons) is a plot of the

A. temperature vs. log (vapor pressure).
B. vapor pressure vs. log (temperature).
C. log (temperature) vs. log (vapor pressure).
D. vapor pressure vs. temperature.
Answer» B. vapor pressure vs. log (temperature).
36.

A gas occupies a volume of 283 c.c at 10°C. If it is heated to 20°C at constant pressure, the new volume of the gas will be __________ c.c.

A. 283
B. 566
C. 293
D. 141.5
Answer» D. 141.5
37.

If 1.5 moles of oxygen combines with aluminium to form Al 2 O 3 , then the weight of aluminium (atomic weight = 27 ) used in this reaction is __________ gm.

A. 27
B. 54
C. 5.4
D. 2.7
Answer» C. 5.4
38.

Pure aniline is evaporating through a stagnant air film of 1 mm thickness at 300 K and a total pressure of 100 KPa. The vapor pressure of aniline at 300 K is 0.1 KPa. The total molar concentration under these conditions is 40.1 mole/m 3 . The diffusivity of aniline in air is 0.74xl0 -5 m 2 /s.The numerical value of mass transfer co-efficient is 7.4 x 10 -3 . Its units are

A. m/s
B. cm/s
C. mole/m 2 .s.Pa
D. kmole/m 2 .s.Pa
Answer» D. kmole/m 2 .s.Pa
39.

The heats of vaporisation of CS 2 , C 2 H 5 OH &H 2 O are 26.8, 38.6 & 40.6 KJ/kg mole respectively. The order of decreasing inter-molecular forces in these liquids is

A. H 2 O > C 2 H 5 OH > CS 2
B. CS 2 > C 2 H 5 OH > H 2 O
C. H 2 O > CS 2 > C 2 H 5 OH
D. CS 2 > H 2 O > C 2 H 5 OH
Answer» B. CS 2 > C 2 H 5 OH > H 2 O
40.

The total number of atoms in 8.5 gm of NH 3 is __________ x 10 23 .

A. 9.03
B. 3.01
C. 1.204
D. 6.02
Answer» B. 3.01
41.

Osmotic pressure exerted by a solution prepared by dissolving one gram mole of a solute in 22.4 litres of a solvent at 0°C will be __________ atmosphere.

A. 0.5
B. 1
C. 1.5
D. 2
Answer» C. 1.5
42.

The equilibrium data of component A in the two phases B and C are given below. The estimate of Y for X = 4 by fitting a quadratic expression of a form Y = m X 2 for the above data is

A. 15.5
B. 16
C. 16.5
D. 17
Answer» D. 17
43.

Saturated solution of benzene in water is in equilibrium with a mixture of air and vapours of benzene and water at room temperature and pressure. Mole fraction of benzene in liquid is x B and the vapour pressures of benzene and water at these conditions are p v B and p v w respectively. The partial pressure of benzene in air-vapour mixture is

A. P v B
B. x B . P v B
C. ( P atm - P v w ) x B
D. x B . P atm
Answer» C. ( P atm - P v w ) x B
44.

One mole of methane undergoes complete combustion in a stoichiometric amount of air. The reaction proceeds as CH 4 + 2O 2 ? CO 2 + 2H 2 O. Both the reactants and products are in gas phase. ?H° 298 = - 730 kJ/mole of methane. If the average specific heat of all the gases/vapour is 40 J/mole.K, the maximum temperature rise of the exhaust gases in °C would be approximately equal to

A. 1225
B. 1335
C. 1525
D. 1735
Answer» E.
45.

Air at a temperature of 20°C and 750 mm Hg pressure has a relative humidity of 80%. What is its percentage humidity ? Vapour pressure of water at 20°C is 17.5 mm Hg.

A. 80.38
B. 80
C. 79.62
D. 78.51
Answer» D. 78.51
46.

On mixing 56 gm of CaO with 63 gm of HNO 3 , the amount of Ca(NO 3 ) 2 formed is __________ gm.

A. 82
B. 164
C. 41
D. 8.2
Answer» B. 164
47.

What fraction of the total pressure is exerted by oxygen, if equal weights of oxygen and methane are mixed in an empty vessel at 25°C ?

A. 2/3
B. 1/3
C. 1/2
D. l/3 x
Answer» C. 1/2
48.

Na 2 SO 4 . 10H 2 O crystals are formed by cooling 100 Kg of 30% by weight aqueous solution of Na 2 SO 4 . The final concentration of the solute in the solution is 10%. The weight of crystals is

A. 20
B. 32.2
C. 45.35
D. 58.65
Answer» E.
49.

If 1 Nm 3 of O 2 contains 'N' number of molecules, then number of molecules in 2Nm 3 of SO 2 will be

A. N
B. N/2
C. 2N
D. 4N
Answer» D. 4N
50.

At a temperature of 0°K, the molecules of a gas have only __________ energy.

A. rotational
B. vibrational
C. translational
D. none of these
Answer» D. none of these