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This section includes 21 Mcqs, each offering curated multiple-choice questions to sharpen your Engineering Chemistry knowledge and support exam preparation. Choose a topic below to get started.
1. |
The formula of enantiomeric excess is ____________ |
A. | [(d+l)/(d-l)]*100 |
B. | [(d)/(d+l)]*100 |
C. | [(d-l)/(d)]*100 |
D. | /(d+l)]*100c) [(d-l)/(d)]*100d) [(d-l)/(d+l)]*100 |
Answer» D. /(d+l)]*100c) [(d-l)/(d)]*100d) [(d-l)/(d+l)]*100 | |
2. |
Optical purity is defined as the ____________ |
A. | Ratio of rotation of pure enantiomer to rotation of mixture |
B. | Ratio of rotation of mixture to rotation of pure enantiomer |
C. | Product of rotation of mixture and rotation of pure enantiomer |
D. | Sum of rotation of mixture and rotation of pure enantiomer |
Answer» C. Product of rotation of mixture and rotation of pure enantiomer | |
3. |
Under SN2 conditions, on reaction with NaOH, (S)-2-bromo octane gives (R)-2-octanol. This is an example of ____________ |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» E. | |
4. |
Under SN2 conditions, on reaction with NaOH, (R)-2-bromo octane gives ____________ |
A. | (S)-2-octanol |
B. | (R)-2-octanol |
C. | Trans-2-butene |
D. | Cis-2-butene |
Answer» B. (R)-2-octanol | |
5. |
R – C = C – R reacts in the presence of lindlar catalyst to give a syn product. This is an example of ____________ |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» C. Regioselective | |
6. |
Reaction of (±) 2,3- dibromobutane is slower than meso in which the two methyl groups are ____________ |
A. | Skew |
B. | Anti |
C. | Gauche |
D. | Partially eclipsed |
Answer» E. | |
7. |
The reaction in which stereochemically different molecules react differently is called ____________ |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» E. | |
8. |
The reaction that yields predominantly one enantiomer of a possible pair is called ____________ |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» C. Regioselective | |
9. |
The reaction which gives exclusively one of several possible isomeric products is called ____________ |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» D. Stereospecific | |
10. |
UNDER_SN2_CONDITIONS,_ON_REACTION_WITH_NAOH,_(R)-2-BROMO_OCTANE_GIVES?$ |
A. | (S)-2-octanol |
B. | (R)-2-octanol |
C. | Trans-2-butene |
D. | Cis-2-butene |
Answer» B. (R)-2-octanol | |
11. |
Optical purity is defined as the$ |
A. | Ratio of rotation of pure enantiomer to rotation of mixture |
B. | Ratio of rotation of mixture to rotation of pure enantiomer |
C. | Product of rotation of mixture and rotation of pure enantiomer |
D. | Sum of rotation of mixture and rotation of pure enantiomer |
Answer» C. Product of rotation of mixture and rotation of pure enantiomer | |
12. |
Under_SN2_conditions,_on_reaction_with_NaOH,_(S)-2-bromo_octane_gives_(R)-2-octanol._This_is_an_example_of |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» E. | |
13. |
The_formula_of_enantiomeric_excess_is |
A. | [(d+l)/(d-l)]*100 |
B. | [(d)/(d+l)]*100 |
C. | [(d-l)/(d)]*100 |
D. | [(d-l)/(d+l)]*100 |
Answer» D. [(d-l)/(d+l)]*100 | |
14. |
R – C = C – R reacts in the presence of lindlar catalyst to give syn product. This is an example o?# |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» C. Regioselective | |
15. |
Dynamic stereochemistry helps in correlating conformation and reactivity and in stereoselective synthesis. |
A. | True |
B. | False |
Answer» B. False | |
16. |
Reaction of (±) 2,3- dibromobutane is slower than meso in which the two methyl groups are$ |
A. | Skew |
B. | Anti |
C. | Gauche |
D. | Partially eclipsed |
Answer» E. | |
17. |
Which of the following is an example of regioselective reaction? |
A. | Debromination of 2,3- dibromobutane |
B. | 2-bromo octane with sodium hydroxide |
C. | Addition of HI to propylene |
D. | Debromination of meso dibromobutane |
Answer» D. Debromination of meso dibromobutane | |
18. |
The reaction in which stereochemically different molecules react differently is called |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» E. | |
19. |
Stereoselectivity can be exhibited in various degrees. |
A. | True |
B. | False |
Answer» B. False | |
20. |
The reaction that yields predominantly one enantiomer of a possible pair is called |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» C. Regioselective | |
21. |
The reaction which gives exclusively one of several possible isomeric products is called |
A. | Dynamicselective |
B. | Stereoselective |
C. | Regioselective |
D. | Stereospecific |
Answer» D. Stereospecific | |