Explore topic-wise MCQs in Joint Entrance Exam - Main (JEE Main).

This section includes 11242 Mcqs, each offering curated multiple-choice questions to sharpen your Joint Entrance Exam - Main (JEE Main) knowledge and support exam preparation. Choose a topic below to get started.

3651.

Which of the following is a biodegradable polymer?

A. Cellulose           
B. Polythene
C. Polyvinyl chloride
D. Nylon-6
Answer» B. Polythene
3652.

Among cellulose, poly (vinyl chloride), nylon and natural rubber, the polymer in which the intermolecular force of attraction is weakest is

A. nylon   
B. poly (vinyl chloride)
C. cellulose
D. natural rubber.
Answer» E.
3653.

The compound required for the formation of a thermosetting polymer with methanal is

A. benzene
B. phenyl amine
C. benzaldehyde
D. phenol
Answer» E.
3654.

Arrange the following monomers in order of decreasing ability to undergo cationic polymerisation.(I) \[C{{H}_{2}}=CH-{{C}_{6}}{{H}_{4}}(N{{O}_{2}})\](II) \[C{{H}_{2}}=CH-{{C}_{6}}{{H}_{4}}(C{{H}_{3}})\](III) \[C{{H}_{2}}=CH-{{C}_{6}}{{H}_{4}}(OC{{H}_{3}})\] 

A. I > II > III
B. II > I > III
C. III > II > I        
D. I > III > II
Answer» D. I > III > II
3655.

Match the following (i) Biodegradable polymer (p) 3-Hydroxybutanoic acid (ii) Bakelite (q) phenol (iii) Neoprene (r) 2-chlorobuta-1, 3-diene (iv) Glyptal (s) phthalic acid

A. i\[\to \]p; ii\[\to \]q; iii\[\to \]r; iv\[\to \]s
B. i\[\to \]q; ii\[\to \]p; iii\[\to \]r; iv\[\to \]s
C. i\[\to \]p; ii\[\to \]q; iii\[\to \]s; iv\[\to \]r
D. i\[\to \]s; ii\[\to \]r; iii\[\to \]p; iv\[\to \]q
Answer» B. i\[\to \]q; ii\[\to \]p; iii\[\to \]r; iv\[\to \]s
3656.

Isotactic polypropylene polymer is one in which

A. the methyl groups present alternate regularly from one side to the other
B. all methyl groups are on one side of the extended chain. It is a highly crystalline, has high melting point and forms strong fibres
C. the methyl groups are distributed at random. It is a soft, elastic and rubbery material
D. None of the above
Answer» C. the methyl groups are distributed at random. It is a soft, elastic and rubbery material
3657.

The number average molecular mass and mass average molecular mass of a polymer are respectively 30,000 and 40,000. The polydispersity index of the polymer is

A. <1                   
B. >1
C. 1         
D. 0
Answer» C. 1         
3658.

Gutta-percha is

A. trans-polyisoprene
B. non-elastic and softens to a plastic ?like material on heating
C. used in underwater cables and golf balls
D. All of the above
Answer» D. All of the above
3659.

What is not true regarding free radical polymerisation of propene?

A. Without proper control, atactic polypropylene is produced
B. During polymerization, a secondary free radical is produced in every step
C. Use of Ziegler-Natta catalyst results in isotactic polypropylene
D. During polymerization, a linear, unbranched, crystalline polymer is usually obtained
Answer» E.
3660.

A reaction of ethy1amine and acetic anhydride leads to the formation of

A. \[C{{H}_{3}}NHCOC{{H}_{3}}\]
B. \[{{C}_{2}}{{H}_{5}}CONHC{{H}_{3}}\]
C. \[C{{H}_{3}}CONH{{C}_{2}}{{H}_{5}}\]
D. \[C{{H}_{3}}-CH=N-O{{C}_{2}}{{H}_{5}}\]
Answer» D. \[C{{H}_{3}}-CH=N-O{{C}_{2}}{{H}_{5}}\]
3661.

Ethyl methylamine cannot be resolved under normal conditions because

A. The nitrogen atom rapidly inverts its configuration leading to a racemic mixture
B. it isomerizes rapidly with the achiral isomer trimethylamine
C. the favoured configuration is not chiral
D. the C-N bond is not stable under conditions used for resolution
Answer» B. it isomerizes rapidly with the achiral isomer trimethylamine
3662.

Which of the following is a set of enamine?

A. I and II 
B. II, III and IV
C. II, IV and V      
D. Only II
Answer» E.
3663.

N-Ethyl pthalimide on hydrolysis gives

A. Methyl alcohol
B. Ethyl amine
C. Dimethyl amine
D. Diethyl amine
Answer» C. Dimethyl amine
3664.

An organic compound 'A' \[({{C}_{3}}{{H}_{9}}N)\] reacts with benzene sulphonyl chloride to give a solid insoluble in alkali. The structure of 'A' is

A. \[C{{H}_{3}}\,NH\,{{C}_{2}}{{H}_{5}}\]
B. \[{{(C{{H}_{3}})}_{3}}N\]
C. \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}N{{H}_{2}}\]
D. insufficient data to predict
Answer» B. \[{{(C{{H}_{3}})}_{3}}N\]
3665.

Which of the following compounds will be obtained in the end of the following reaction? Ethyl amine\[\xrightarrow{HN{{O}_{2}}}A\xrightarrow{PC{{l}_{5}}}B\xrightarrow{N{{H}_{3}}}C\]

A. Ethyl cyanide    
B. Acetamide
C. Methyl amine    
D. Ethyl amine
Answer» E.
3666.

A compound with molecular mass 180 is acylated with \[C{{H}_{3}}COCl\] to get a compound with molecular mass 390 The number of amino groups present per molecule of the former compound is

A. 6                     
B. 2
C. 5         
D. 4
Answer» D. 4
3667.

Toluene is nitrated and the resulting product is reduced with tin and hydrochloric acid. The product so obtained is diazotized and then heated with cuprous bromide. The reaction mixture so formed contains

A. Mixture of \[{{o}^{-}}\]and p-bromotoluense
B. Mixture of \[{{o}^{-}}\]and p-dibrombenzenes
C. Mixture of \[{{o}^{-}}\]and p-bromoanilines
D. Mixture of \[{{o}^{-}}\]and m-bromoanilnes
Answer» B. Mixture of \[{{o}^{-}}\]and p-dibrombenzenes
3668.

What sequence of reactions would best accomplish the following reaction?

A. (i) \[LiAl{{H}_{4}}\] in ether: (ii) \[{{P}_{2}}{{O}_{5}}\]and heat
B. (i) \[LiAl{{H}_{4}}\] in ether; (ii) \[3C{{H}_{3}}I\] followed by heating with \[AgOH\]
C. (i) 20%\[{{H}_{2}}S{{O}_{4}}\]and heat; (ii) \[{{P}_{2}}{{O}_{5}}\] and heat
D. \[{{H}_{2}}\] and Lindlar catalyst
Answer» C. (i) 20%\[{{H}_{2}}S{{O}_{4}}\]and heat; (ii) \[{{P}_{2}}{{O}_{5}}\] and heat
3669.

The order of increasing boiling points among the three compounds is \[{{C}_{2}}{{H}_{5}}ONO(I)\] \[{{C}_{2}}{{H}_{5}}N{{O}_{2}}(II)\] \[{{C}_{2}}{{H}_{6}}(III)\]

A. III<II<I
B. I<II<III
C. III<I<II            
D. III<I\[\approx \]II
Answer» D. III<I\[\approx \]II
3670.

In the diazotization of aniline with sodium nitrite and hydrochloric acid, an excess of hydrochloric acid is used primarily to:

A. suppress the concentration of free aniline available for coupling
B. suppress hydrolysis of phenol
C. insure a stoichiometric amount of nitrous acid
D. neutralize the base liberated
Answer» B. suppress hydrolysis of phenol
3671.

p-Chloro aniline and anilinium hydrogen chloride can be distinguished by

A. Sandmeyer reaction
B. Carbylamine reaction
C. Hinsberg?s reaction
D. \[AgN{{O}_{3}}\]
Answer» E.
3672.

  Arrange the following compounds in decreasing order of coupling with benzenediazonium chloride.

A. IV>I>II>III      
B. II>I>IV>III
C. II>IV>I>III      
D. II>III>IV>I
Answer» D. II>III>IV>I
3673.

The decreasing order of basic character at a, b, and c m the following compound is

A. b > a > c         
B. c > b> a
C. a > b > c         
D. c > a > b
Answer» D. c > a > b
3674.

When (1R, 2R)-1,2-Dibromo-1,2-diphenyl ethane is treated with alcoholic solution of KOH, the most probable product would be:

A. trans-1, 2-diphenyl ethane
B. A mixture of cis, trans alkenyl bromide
C. cis-alkenyl bromide
D. trans-alkenyl bromide
Answer» E.
3675.

The decreasing order of rate of \[{{S}_{N}}2\] reaction is:

A. IV > III > II > I
B. II > III > I > IV
C. II > I > IV > III
D. None of these
Answer» D. None of these
3676.

Reaction intermediate of E1cB reaction is:

A. Carbocation      
B. Carbanion
C. Benzyne           
D. Free radical
Answer» C. Benzyne           
3677.

The stability order of following carbocation is

A. i> ii> iv> iii    
B. iii> i> ii> iv
C. iv> ii> iii> i    
D. ii> iv> iii> i
Answer» E.
3678.

The decreasing order of electron density on the ring is:

A.  (II)> (III)> (IV)> (I)
B.  (IV)> (I)> (II)> (III)
C.  (IV)> (I)> (III)> (II)
D.  (I)> (III)> (IV)> (II)
Answer» E.
3679.

The correct order of +m effect of 'N' containing functional group on benzene ring, amongst the given compounds is

A.  I>II>IV>III     
B. II>I>III>IV
C. I>II>III>IV     
D. IV>III>II>I
Answer» D. IV>III>II>I
3680.

Assign number 1 for least to 4 for most to indicate the relative base strength of the following:(I) \[{{C}_{6}}{{H}_{5}}N{{H}_{2}}\]         (II) \[p-N{{O}_{2}}{{C}_{6}}{{H}_{4}}N{{H}_{2}}\](III) \[m-N{{O}_{2}}{{C}_{6}}{{H}_{4}}N{{H}_{2}}\](IV) \[p-C{{H}_{3}}O{{C}_{6}}{{H}_{4}}N{{H}_{2}}\] 

A. I - 3     II - 1     III - 2    IV - 4
B.  I - 1     II - 2     III - 3    IV - 4
C.  I - 2     II - 3     III - 4    IV - 1
D.  I - 4     II - 1     III - 3    IV - 2
Answer» B.  I - 1     II - 2     III - 3    IV - 4
3681.

64 g of an organic compound contains 24 g of carbon, 8 g of hydrogen and the rest oxygen. The empirical formula of the compound is

A. \[C{{H}_{2}}O\]                     
B. \[{{C}_{2}}{{H}_{4}}O\]
C. \[C{{H}_{4}}O\]         
D. \[{{C}_{2}}{{H}_{8}}{{O}_{2}}\]
Answer» D. \[{{C}_{2}}{{H}_{8}}{{O}_{2}}\]
3682.

What is the systematic IUPAC name of the following compound?

A.  1-Methy1 bicyclo [3, 2, 1] octane
B.  6-Methy1 bicyclo [3, 2, 1] octane
C.  8-Methy1 bicyclo [3, 2, 1] octane
D.  8-Methy1 tricyclo [3, 2, 1] octane
Answer» D.  8-Methy1 tricyclo [3, 2, 1] octane
3683.

For the detection of phosphorus, the organic compound after fusion with \[N{{a}_{2}}{{O}_{2}}\]is extracted with water, boiled with \[Na{{O}_{3}}\]and then ammonium molybdate is added to it, A yellow ppt. is obtained which is due to the formation of

A.  ammonium phosphate
B.  ammonium phosphomolybdate
C.  ferric phosphate
D.  disodium ammonium phosphate
Answer» C.  ferric phosphate
3684.

What is the correct IUPAC name of the compound Shown below?

A.  5-Bromo-2-chloro-1-cyclobuty1-6cyclohexy1-1, 6-dimethy1-3-hexyne
B.  5-Bromo-2chloro-1-cyclobuty1-6-cyclohexy1-1-methy1-3-heptyne
C.  3-Bromo-6-chloro-7-cyclobuty1-2-cyclohexy1-4-octyne
D.  6-Bromo-3-chloro-2-cyclobuty1?7-cyclohexy1-4-oct-compound?
Answer» E.
3685.

According to IUPAC convention, the systematic name of the compound given below is

A.  4-(4-Bromocyclohexy1)-1-(3-chlorocy clohexy1)-2-flouorocyclohexane
B.  5-(4-Bromocyclohexy1)-2-(3-Chlorocy clohexy1)-1-flouorocyclohexane
C.  1-(3-chlorocyclohexy1)-4-(4-bromocy clohexy1)-2-flouorocyclohexane
D.  1-(4-Bromocyclohexy1)-4-(3-chlorocy clohexy1)-3-fluorocyclohexane
Answer» B.  5-(4-Bromocyclohexy1)-2-(3-Chlorocy clohexy1)-1-flouorocyclohexane
3686.

The correct IUPAC name of the compound

A.  6-Ethy1-1-methy1-4-oxohept-6-ene-1-suplphonic acid
B.  7-Ethy1-5-oxooct-7-ene-2-sulphonic acid
C.  2-Ethy1-7-sulphooct-1-ene-4-one
D.  7-Methylene-5-oxononane-2-sulphonic acid
Answer» C.  2-Ethy1-7-sulphooct-1-ene-4-one
3687.

A hydrocarbon with molecular formula \[{{C}_{6}}{{H}_{8}}\]is chiral but upon catalytic hydrogenation gives achiral hydrocarbon of molar mass 86. Which of the following could be the starting compound?

A.  3-methy1-1-pentene-4-yne
B.  1, 4-dimethylcyclobutadiene
C.  1-etheny1-3-methylcyclopropene
D.  5-methy1-1, 3-cyclopentadiene
Answer» B.  1, 4-dimethylcyclobutadiene
3688.

How many total structural isomers are obtained when three hydrogen atoms are replaced by chlorine atom from molecular formula \[{{C}_{3}}{{H}_{8}}\]

A. 5        
B. 4
C. 6                    
D. 3
Answer» B. 4
3689.

The order of reactivity of the following alcohols towards conc. HCl is:

A. I> II> III>IV               
B. I> III> II,> IV
C. IV> III> II>I   
D. IV> III> I> II
Answer» D. IV> III> I> II
3690.

pH for the solution of salt undergoing anionic hydrolysis (say \[C{{H}_{3}}COONa\]) is given by:

A.  \[pH=1/2\left[ p{{K}_{w}}+p{{K}_{a}}+\log C \right]\]
B.  \[pH=1/2\left[ p{{K}_{w}}+p{{K}_{a}}-\log C \right]\]
C.  \[pH=1/2\left[ p{{K}_{w}}+p{{K}_{b}}-\log C \right]\]
D.  None of these
Answer» B.  \[pH=1/2\left[ p{{K}_{w}}+p{{K}_{a}}-\log C \right]\]
3691.

The pH of a 0.01 M solution of a monobasic acid is four. Which one of the following statements about the acid is invorrect?

A. When a little NaOH is added, it will form a buffer solution
B.  It is a weak acid
C.  Its sodium salt will be acidic
D.  Its sodium salt will be basic
Answer» D.  Its sodium salt will be basic
3692.

Equal volumes of three acid solutions of pH 3, 4 and 5 are mixed in a vessel. What will be the \[{{H}^{+}}\] ion concentration

A. \[3.7\times {{10}^{-3}}M\]
B. \[1.11\times {{10}^{-3}}M\]
C. \[1.11\times {{10}^{-4}}M\]
D. \[3.7\times {{10}^{-4}}M\]
Answer» E.
3693.

The pH of Ba \[{{(OH)}_{2}}\]solution is 13. The number millimoles of Ba\[{{(OH)}_{2}}\] present in 10 ml of solution would be

A. 1.00                 
B. 0.5
C. 10.00  
D. 15
Answer» C. 10.00  
3694.

Four species are listed below:(i) \[HC{{O}^{-}}_{3}\]                      (ii) \[{{H}_{3}}{{O}^{+}}\](iii) \[HS{{O}^{-}}_{4}\]                     (iv) \[HS{{O}_{3}}F\]Which one of the following is the correct sequence of their acid strength?

A. iv <ii <iii <i    
B. ii <iii <i <iv
C. i <iii <ii <iv    
D. iii <i <iv <ii
Answer» D. iii <i <iv <ii
3695.

The degree of dissociation of water at \[25{}^\circ C\] is \[1.9\times {{10}^{-7}}\] % and density is 1.0 g \[c{{m}^{-3}}\]. The ionic constant for water is

A. \[1.0\times {{10}^{-10}}\]       
B. \[1.0\times {{10}^{-14}}\]
C. \[1.0\times {{10}^{-16}}\]       
D. \[1.0\times {{10}^{-8}}\]
Answer» C. \[1.0\times {{10}^{-16}}\]       
3696.

Calculate pH of 0.002 N \[N{{H}_{4}}\]OH having 2% dissociation.

A. 7.6                   
B. 8.6
C. 9.6                  
D. 10.6
Answer» D. 10.6
3697.

When equal volumes of the following solutions are mixed, precipitation of AgCl (\[{{K}_{sp}}\] = \[1.8\times {{10}^{-10}}\]) will occur only with

A.  \[{{10}^{-4}}M(A{{g}^{+}})\,and\,{{10}^{-4}}M(C{{l}^{-}})\]
B.  \[{{10}^{-5}}M(A{{g}^{+}})\,and\,{{10}^{-5}}M(C{{l}^{-}})\]
C.  \[{{10}^{-16}}M(A{{g}^{+}})\,and\,{{10}^{-6}}M(C{{l}^{-}})\]
D. \[{{10}^{-10}}M(A{{g}^{+}})\,and\,{{10}^{-10}}M(C{{l}^{-}})\]
Answer» B.  \[{{10}^{-5}}M(A{{g}^{+}})\,and\,{{10}^{-5}}M(C{{l}^{-}})\]
3698.

The best indicator for detection of end point in titration of a Weak acid and a strong base is

A. Methy1 orange (3 to 4)
B.  Methy1 red (5 to 6)
C.  Bromothymol blue (6 to 7.5)
D.  Phenolphthalein (8 to 9.6)
Answer» E.
3699.

The first and second dissociation constant of an acid \[{{H}_{2}}A\] are\[1.0\times {{10}^{-5}}\] and \[5.0\times {{10}^{-10}}\] respectively. The overall dissociation constant of the acid will be:

A. \[5.0\times {{10}^{-5}}\]        
B. \[5.0\times {{10}^{15}}\]
C. \[5.0\times {{10}^{-15}}\]       
D. \[0.2\times {{10}^{5}}\]
Answer» D. \[0.2\times {{10}^{5}}\]
3700.

In a saturated solution of the sparingly soluble strong electrolyte \[AgI{{O}_{3}}\] (molecular mass = 283) the equilibrium which sets in is \[AgI{{O}_{3}}(s)\rightleftharpoons A{{g}^{+}}(aq)+I{{O}^{-}}_{3}(aq)\] If the solubility product constant \[{{K}_{sp}}\]of\[AgI{{O}_{3}}\], at a given temperature is\[1.0\times {{10}^{-8}}\], what is the mass of, \[AgI{{O}_{3}}\] contained in 100 mL of its saturated solution?

A. \[28.3\times {{10}^{-2}}g\]     
B. \[28.3\times {{10}^{-3}}g\]
C. \[1.0\times {{10}^{-7}}g\]       
D. \[1.0\times {{10}^{-4}}g\]
Answer» B. \[28.3\times {{10}^{-3}}g\]