Based on solute-solvent interactions, arrange the following in order of increasing solubility in n*octane and explain. Cyclohexane, KCl, CH3OH, CH3CN.
n-octane is a non-polar solvent. Therefore, the solubility of a non-polar solute is more than that of a polar solute in the n-octane.
The order of increasing polarity is:
Cyclohexane < CH3CN < CH3OH < KCl Therefore, the order of increasing solubility is: KCl < CH3OH < CH3CN < Cyclohexane
(i) Cyclohexane and n-octane both are non-polar. Hence they mix completely in all proportions.
(ii) KCl is an ionic compound while n-octane is nonpolar. Hence, KCl will not dissolve at all in n-octane.
(iii) CH3OH and CH3CN both are polar but CH3CN is less polar than CH3OH. As the solvent is non-polar, CH3CN will dissolve more than CH3OH is n-octane.
Thus the order of solubility will be KCl< CH3OH < CH3CN < Cyclohexane.