1.

Indicate which nitrogen compound amongst the following would undergo Hofmann's reaction (i.e. reaction with \[B{{r}_{2}}\] and strong KOH) to furnish the primary amine (\[R-N{{H}_{2}}\]) [CBSE PMT 1989]

A. \[R-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-NH.C{{H}_{3}}\]
B. \[R-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-O.N{{H}_{4}}\]
C. \[R-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-N{{H}_{2}}\]
D. \[R-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-NHOH\]
Answer» D. \[R-\overset{O}{\mathop{\overset{||}{\mathop{C}}\,}}\,-NHOH\]


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