1.

In the process of extraction of gold, Roasted gold ore\[+C{{N}^{-}}+{{H}_{2}}O\xrightarrow{{{O}_{2}}}[X]+O{{H}^{-}}\] \[[X]+Zn\to [Y]+Au\] Identify the complexes [X] and [Y] [IIT-JEE 2003]

A. \[X={{[Au{{(CN)}_{2}}]}^{-}},\,Y={{[Zn{{(CN)}_{4}}]}^{2-}}\]
B. \[X={{[Au{{(CN)}_{4}}]}^{3-}},\,Y={{[Zn{{(CN)}_{4}}]}^{2-}}\]
C. \[X={{[Au{{(CN)}_{2}}]}^{-}},\,Y=Zn{{(CN)}_{6}}{{]}^{4-}}\]
D. \[X={{[Au{{(CN)}_{4}}]}^{-}},\,Y={{[Zn{{(CN)}_{4}}]}^{2-}}\]
Answer» B. \[X={{[Au{{(CN)}_{4}}]}^{3-}},\,Y={{[Zn{{(CN)}_{4}}]}^{2-}}\]


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