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This section includes 15 Mcqs, each offering curated multiple-choice questions to sharpen your Organic Chemistry knowledge and support exam preparation. Choose a topic below to get started.
1. |
Which type of catalytic reaction, does Dienone phenol rearrangement reaction belong? |
A. | Acid catalysed |
B. | Base catalysed |
C. | Acidic |
D. | Neutral |
Answer» B. Base catalysed | |
2. |
Which medium is used in benzylic acid rearrangement reaction? |
A. | Neutral |
B. | Strong basic |
C. | Mild acidic |
D. | Strong acidic |
Answer» C. Mild acidic | |
3. |
The benzylic acid rearrangement reaction of a cyclic diketone leads to _______ |
A. | Ring expansion |
B. | Ring contraction |
C. | Ring fusion |
D. | Isomers |
Answer» C. Ring fusion | |
4. |
Which Intermediate is formed in Wolff’s reaction? |
A. | Carbene |
B. | Ketene |
C. | Carbocation |
D. | Carbanion |
Answer» C. Carbocation | |
5. |
With accompanying 1, 2-rearrangement in wolff rearrangement, an α-diazocarbonyl compound is converted into a ketene by loss of which of the following compound? |
A. | Dioxygen |
B. | Dinitrogen |
C. | Disulphur |
D. | Ammonia |
Answer» C. Disulphur | |
6. |
WHICH_MEDIUM_IS_USED_IN_BENZYLIC_ACID_REARRANGEMENT_REACTION??$ |
A. | Neutral |
B. | Strong basic |
C. | Mild acidic |
D. | Strong acidic |
Answer» C. Mild acidic | |
7. |
Which type of catalytic reaction, does Dienone phenol rearrangement reaction belong?$ |
A. | Acid catalysed |
B. | Base catalysed |
C. | Acidic |
D. | Neutral |
Answer» B. Base catalysed | |
8. |
The benzylic acid rearrangement reaction of a cyclic diketone leads to ______? |
A. | Ring expansion |
B. | Ring contraction |
C. | Ring fusion |
D. | Isomers |
Answer» C. Ring fusion | |
9. |
In which medium Favorskii rearrangement occurs? |
A. | Acidic |
B. | Basic |
C. | Neutral |
D. | Alkaline |
Answer» C. Neutral | |
10. |
Which intermediate carbocation is more stable in pinacole -pinacolone rearrangement? |
A. | 1<sup>o</sup> |
B. | 2<sup>o</sup> |
C. | 3<sup>o</sup> |
D. | 4<sup>o</sup> |
Answer» D. 4<sup>o</sup> | |
11. |
Which was the first molecular rearrangement identified as such by early chemists? |
A. | Wolff’s rearrangement |
B. | Pinacole rearrangement |
C. | Favorskii rearrangement |
D. | Hofmann rearrangement |
Answer» B. Pinacole rearrangement | |
12. |
Which Intermediate is formed in Wolff’s reaction?$ |
A. | Carbene |
B. | Ketene |
C. | Carbocation |
D. | Carbanion |
Answer» B. Ketene | |
13. |
With accompanying 1, 2-rearrangement in wolff rearrangement, an α-diazocarbonyl compound is converted into a ketene by loss of which of the following compound?$ |
A. | Dioxygen |
B. | Dinitrogen |
C. | Disulphur |
D. | Ammonia |
Answer» C. Disulphur | |
14. |
What is the main difference between Hofmann and Curtius rearrangement? |
A. | Products are different |
B. | Intermediate formed is different |
C. | Reactants are different |
D. | Isomers |
Answer» B. Intermediate formed is different | |
15. |
Which types of isomers are formed in rearrangement reactions? |
A. | structural isomers |
B. | Geometrical isomers |
C. | Optical isomer |
D. | Conformational isomers |
Answer» B. Geometrical isomers | |