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This section includes 13 Mcqs, each offering curated multiple-choice questions to sharpen your Chemistry knowledge and support exam preparation. Choose a topic below to get started.
1. |
Which of the following would not be a good choice for reducing an aryl nitro compound to an amine? |
A. | H<sub>2</sub>/Pt |
B. | LiAlH<sub>4</sub>-ether |
C. | Fe and HCl |
D. | Sn and HCl |
Answer» C. Fe and HCl | |
2. |
Only primary amine is formed as the main product when ammonolysis of an alkyl halide takes place with large excess of ammonia. |
A. | True |
B. | False |
Answer» B. False | |
3. |
Ammonolysis is a reaction between an alkyl halide and most preferably an ______ solution of NH3. |
A. | alkaline |
B. | acidic |
C. | alcoholic |
D. | aqueous |
Answer» D. aqueous | |
4. |
What is the correct order of reactivity of the following alkyl halides towards ammonolysis reaction? |
A. | CH<sub>3</sub>I > CH<sub>3</sub>Br > CH<sub>3</sub>Cl |
B. | CH<sub>3</sub>I > CH<sub>3</sub>Cl > CH<sub>3</sub>Br |
C. | CH<sub>3</sub>Cl > CH<sub>3</sub>Br > CH<sub>3</sub>I |
D. | CH<sub>3</sub>Br > CH<sub>3</sub>Cl > CH<sub>3</sub>I |
Answer» B. CH<sub>3</sub>I > CH<sub>3</sub>Cl > CH<sub>3</sub>Br | |
5. |
The main product formed when the ammonolysis is carried out using excess of iodoethane is _______ |
A. | 1 amine |
B. | 2 amine |
C. | 3 amine |
D. | quaternary ammonium salt |
Answer» E. | |
6. |
Aniline can be formed from the ammonolysis of chlorobenzene. |
A. | True |
B. | False |
Answer» C. | |
7. |
What is the most suitable condition for the ammonolysis of an alkyl halide? |
A. | 273K, open tube |
B. | 273K, sealed tube |
C. | 373K, open tube |
D. | 373K, sealed tube |
Answer» E. | |
8. |
What is the type of amine obtained from the ammonolysis of alkyl halides? |
A. | Primary |
B. | Primary and secondary |
C. | Secondary and tertiary |
D. | Primary, secondary and tertiary |
Answer» D. Primary, secondary and tertiary | |
9. |
Ammonolysis is a type of _________ reaction. |
A. | electrophilic addition |
B. | electrophilic substitution |
C. | nucleophilic addition |
D. | nucleophilic substitution |
Answer» E. | |
10. |
How many water molecules are formed as the by product of reduction of one molecule of nitropropane to one molecule of propanamine, with hydrogen gas in Pt catalyst? |
A. | 1 |
B. | 2 |
C. | 3 |
D. | 4 |
Answer» C. 3 | |
11. |
What compound is formed when hydrogen gas is passed through nitrobenzene in the presence of finely divided nickel? |
A. | Aniline |
B. | 2-Nitroaniline |
C. | 3-Nitroaniline |
D. | 4-Nitroaniline |
Answer» B. 2-Nitroaniline | |
12. |
Which of the following reagents cannot be used to convert nitrobenzene to aniline? |
A. | LiAlH<sub>4</sub>-dry ether |
B. | SnCl<sub>2</sub>/HCl |
C. | H<sub>2</sub>/Pd-ethanol |
D. | Zn in HCl |
Answer» B. SnCl<sub>2</sub>/HCl | |
13. |
Which of the following is the most preferred reagent for reducing nitroethane to ethylamine? |
A. | H<sub>2</sub>/Pt |
B. | Sn/HCl |
C. | Fe/HCl |
D. | Zn/HCl |
Answer» D. Zn/HCl | |