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This section includes 18 Mcqs, each offering curated multiple-choice questions to sharpen your Engineering Chemistry knowledge and support exam preparation. Choose a topic below to get started.
1. |
Ethene is devoid of any alpha hydrogen so hyperconjugation is not possible. |
A. | True |
B. | False |
Answer» B. False | |
2. |
The compound that can be most readily sulphonated is __________ |
A. | Benzene |
B. | Toluene |
C. | Nitrobenzene |
D. | Chlorobenzene |
Answer» C. Nitrobenzene | |
3. |
When the contributing structure contains the same number of two-electron bonds as the normal lewis formula, it will be __________ |
A. | Heterovalent hyperconjugation |
B. | Sacrificial hyperconjugation |
C. | Isovalent hyperconjugation |
D. | All of the mentioned |
Answer» D. All of the mentioned | |
4. |
On increasing the number of α-hydrogens, the number of hyperconjugation structures will __________ |
A. | Decrease |
B. | Increase |
C. | Remains same |
D. | None of the mentioned |
Answer» C. Remains same | |
5. |
Larger the number of hyperconjugation structures, the stability of free radicals will __________ |
A. | Increase |
B. | Decrease |
C. | Remains same |
D. | None of the mentioned |
Answer» B. Decrease | |
6. |
The resonance energy (kCal/mol) of tertiary butyl is __________ |
A. | 9 |
B. | 10 |
C. | 11 |
D. | 12 |
Answer» E. | |
7. |
Number of hyperconjugation structures in isopropyl radical is __________ |
A. | 3 |
B. | 6 |
C. | 9 |
D. | 12 |
Answer» C. 9 | |
8. |
Hyperconjugation involves the delocalisation of __________ |
A. | σ bond orbital |
B. | π bond orbital |
C. | Both σ and π bond orbital |
D. | None of the mentioned |
Answer» B. π bond orbital | |
9. |
THE_COMPOUND_THAT_CAN_BE_MOST_READILY_SULPHONATED_IS?$ |
A. | Benzene |
B. | Toluene |
C. | Nitrobenzene |
D. | Chlorobenzene |
Answer» C. Nitrobenzene | |
10. |
Ethene is devoid of any alpha hydrogen so hyperconjugation is not possible.$ |
A. | True |
B. | False |
Answer» B. False | |
11. |
When the contributing structure contains the same number of two-electron bonds as the normal lewis formula, it will b? |
A. | Heterovalent hyperconjugation |
B. | Sacrificial hyperconjugation |
C. | Isovalent hyperconjugation |
D. | All of the mentioned |
Answer» D. All of the mentioned | |
12. |
On increasing the number of α-hydrogens, the number of hyperconjugation structures will$ |
A. | Decrease |
B. | Increase |
C. | Remains same |
D. | None of the mentioned |
Answer» C. Remains same | |
13. |
Which of the following is a consequence of Baker-Nathan effect? |
A. | It is helpful in explaining the directive influence of alkyl groups in aromatic alkyl benzene |
B. | It is helpful in explaining the relative stability of alkenes |
C. | It is helpful in explaining the relative stabilities of alkyl carbocations |
D. | All of the mentioned |
Answer» E. | |
14. |
Larger the number of hyperconjugation structures, the stability of free radicals will |
A. | Increase |
B. | Decrease |
C. | Remains same |
D. | None of the mentioned |
Answer» B. Decrease | |
15. |
The resonance energy (kCal/mol) of tertiary butyl is |
A. | 9 |
B. | 10 |
C. | 11 |
D. | 12 |
Answer» E. | |
16. |
Number of hyperconjugation structures in isopropyl radical is |
A. | 3 |
B. | 6 |
C. | 9 |
D. | 12 |
Answer» C. 9 | |
17. |
Hyperconjugation involves the delocalisation of |
A. | σ bond orbital |
B. | π bond orbital |
C. | Both σ and π bond orbital |
D. | None of the mentioned |
Answer» B. ‚âà√¨‚àö√ë bond orbital | |
18. |
Which of the following is known as Baker-Nathan effect? |
A. | Mesomeric effect |
B. | Inductive effect |
C. | Hyperconjugation |
D. | Electromeric effect |
Answer» D. Electromeric effect | |