Explore topic-wise MCQs in Joint Entrance Exam - Main (JEE Main).

This section includes 11242 Mcqs, each offering curated multiple-choice questions to sharpen your Joint Entrance Exam - Main (JEE Main) knowledge and support exam preparation. Choose a topic below to get started.

10201.

If NaCl is doped with mol% \[SrC{{l}_{2}},\] what is the concentration of cation vacancies?

A. \[6.02\times {{10}^{18}}mo{{l}^{-1}}\]
B. \[6.02\times {{10}^{19}}mo{{l}^{-1}}\]
C. \[6.02\times {{10}^{23}}mo{{l}^{-1}}\]
D. \[6.02\times {{10}^{26}}mo{{l}^{-1}}\]
Answer» B. \[6.02\times {{10}^{19}}mo{{l}^{-1}}\]
10202.

A solid AB has NaCl structure. If the radius of action \[{{A}^{+}}\] is 170 pm, calculate the maximum possible radius of the anion \[{{B}^{-}}\]

A. 210.3 pm
B. 397.4 pm
C. 410.6 pm
D. 347.9 pm
Answer» D. 347.9 pm
10203.

In orthorhombic, the value of a, b and c are respectively 4.2\[\overset{\text{o}}{\mathop{\text{A}}}\,\], 8.6\[\overset{\text{o}}{\mathop{\text{A}}}\,\] and 8.3\[\overset{\text{o}}{\mathop{\text{A}}}\,\]. Given the molecular mass off solute is 155 gm \[mo{{l}^{-1}}\] and that of density is 3.3 g/cc, the number of formula units per unit cell is

A. 2
B. 3
C. 4
D. 6
Answer» D. 6
10204.

LiCl has NaCl type structure with edge length 512 pm. Assuming that the \[L{{i}^{+}}\] ion is small enough that the chloride ions are in contact, then radius of \[C{{I}^{-}}\] ion is

A. 223 pm
B. 224 pm
C. 181 pm
D. 362 pm
Answer» E.
10205.

Copper crystallises in a structure of face centered cubic unit cell. The atomic radius of copper is 1.28 \[\overset{\text{o}}{\mathop{\text{A}}}\,\]. What is the axial length on an edge of copper?

A. 2.16\[\overset{\text{o}}{\mathop{\text{A}}}\,\]
B. 3.62\[\overset{\text{o}}{\mathop{\text{A}}}\,\]
C. 3.94\[\overset{\text{o}}{\mathop{\text{A}}}\,\]
D. 4.15\[\overset{\text{o}}{\mathop{\text{A}}}\,\]
Answer» C. 3.94\[\overset{\text{o}}{\mathop{\text{A}}}\,\]
10206.

The basic building unit of all silicates is [UPSEAT 2002]

A. \[Si{{O}_{4}}\] square planar
B. \[{{[Si{{O}_{4}}]}^{4-}}\] tetrahedron
C. \[Si{{O}_{4}}\] octahedron
D. \[Si{{O}_{4}}\] linear
Answer» C. \[Si{{O}_{4}}\] octahedron
10207.

What type of crystal defect is indicated in the diagram below [AIEEE 2004] \[N{{a}^{+}}\,\,C{{l}^{-}}\,\,N{{a}^{+}}\,\,C{{l}^{-}}\,\,\,N{{a}^{+}}\,\,\,C{{l}^{-}}\] \[C{{l}^{-}}\] ¨ \[C{{l}^{-}}\] \[N{{a}^{+}}\] ¨ \[N{{a}^{+}}\] \[N{{a}^{+}}\] \[C{{l}^{-}}\]¨ \[C{{l}^{-}}\] \[N{{a}^{+}}\] \[C{{l}^{-}}\] \[C{{l}^{-}}\] \[N{{a}^{+}}\] \[C{{l}^{-}}\] \[N{{a}^{+}}\] ¨ \[N{{a}^{+}}\]

A. Interstitial defect
B. Schottky defect
C. Frenkel defect
D. Frenkel and Schottky defects
Answer» C. Frenkel defect
10208.

Coordination number for \[Cu\] is [AMU 1982]

A. 1
B. 6
C. 8
D. 12
Answer» E.
10209.

In the calcium fluoride structure the co-ordination number of the cation and anions are respectively [J & K 2005]

A. 6, 6
B. 8, 4
C. 4, 4
D. 4, 8
Answer» C. 4, 4
10210.

The difference of number of water molecules in gypsum and plaster of Paris is

A. \[\frac{5}{1}\]
B. 2
C. \[1/2\]
D. \[1\frac{1}{2}\]
Answer» E.
10211.

Acidified solution of sodium thiosulphate is unstable because in thiosulphate

A. the sulphur atoms are at unstable oxidation state of \[+2\]
B. the two sulphur atoms are at different oxidation states of \[+6\] and \[-2\]
C. the \[S-S\] bond are unstable bonds.
D. sulphur is in zero oxidation state.
Answer» C. the \[S-S\] bond are unstable bonds.
10212.

Sodium carbonate solution in water is alkaline due to

A. hydrolysis of \[N{{a}^{+}}\]
B. hydrolysis of \[CO_{3}^{2-}\]
C. hydrolysis of both \[N{{a}^{+}}\] and \[CO_{3}^{2-}\] ions
D. None of these
Answer» C. hydrolysis of both \[N{{a}^{+}}\] and \[CO_{3}^{2-}\] ions
10213.

Which or me following are found in biological fluids \[N{{a}^{+}},M{{g}^{2+}},C{{a}^{2+}},{{K}^{+}},S{{r}^{2+}},L{{i}^{+}}\] and \[B{{a}^{2+}}\]?

A. \[M{{g}^{2+}},C{{a}^{2+}},\] and \[S{{r}^{2+}}\]
B. \[N{{a}^{2+}}\] and \[{{K}^{+}}\]
C. \[N{{a}^{+}},{{K}^{+}},M{{g}^{2+}}\] and \[C{{a}^{2+}}\]
D. \[S{{r}^{+}},Li\] and \[B{{a}^{2+}}\]
Answer» D. \[S{{r}^{+}},Li\] and \[B{{a}^{2+}}\]
10214.

The main oxides formed on combustion of \[Li,\text{ }Na\] and K in excess of air are, respectively:

A. \[L{{i}_{2}}{{O}_{2}},N{{a}_{2}}{{O}_{2}}\] and \[K{{O}_{2}}\]
B. \[L{{i}_{2}}O,N{{a}_{2}}{{O}_{2}}\]and \[K{{O}_{2}}\]
C. \[L{{i}_{2}}O,N{{a}_{2}}O\] and \[K{{O}_{2}}\]
D. \[Li{{O}_{2}},N{{a}_{2}}{{O}_{2}}\]and \[{{K}_{2}}O\]
Answer» C. \[L{{i}_{2}}O,N{{a}_{2}}O\] and \[K{{O}_{2}}\]
10215.

Melting point of calcium halides decreases in the order

A. \[Ca{{F}_{2}}>CaC{{l}_{2}}>CaB{{r}_{2}}>Ca{{I}_{2}}\]
B. \[Ca{{I}_{2}}>CaB{{r}_{2}}>CaC{{l}_{2}}>Ca{{F}_{2}}\]
C. \[CaB{{r}_{2}}>Ca{{I}_{2}}>Ca{{F}_{2}}>CaC{{l}_{2}}\]
D. \[CaC{{l}_{2}}>CaB{{r}_{2}}>Ca{{I}_{2}}>Ca{{F}_{2}}\]
Answer» B. \[Ca{{I}_{2}}>CaB{{r}_{2}}>CaC{{l}_{2}}>Ca{{F}_{2}}\]
10216.

The reducing power of a metal depends on various factors. Suggest the factor which makes \[Li\] metal the strongest reducing agent in aqueous solution:

A. Sublimation enthalpy
B. Ionisation enthalpy
C. Hydration enthalpy
D. Electron-gain enthalpy
Answer» D. Electron-gain enthalpy
10217.

Sodium is heated n excess of air, free from \[C{{O}_{2}}\]at \[350{}^\circ \]C to from X. X. absorbs \[C{{O}_{2}}\] and forms \[N{{a}_{2}}C{{O}_{3}}\]and Y. 'X' and 'Y' are respectively:

A. \[N{{a}_{2}}{{O}_{{}}}\]and \[{{O}_{2}}\]
B. \[N{{a}_{2}}{{O}_{2}}\]and \[{{O}_{2}}\]
C. \[Na\]\[{{O}_{2}}\] and \[{{O}_{2}}\]
D. \[N{{a}_{2}}{{O}_{2}}\] and \[{{O}_{3}}\]
Answer» C. \[Na\]\[{{O}_{2}}\] and \[{{O}_{2}}\]
10218.

The decreasing order of the second ionization potentials of K, Ca and Ba is

A. K>Ca>Ba
B. Ca>Ba>K
C. Ba>K>Ca
D. K>Ba>Ca
Answer» B. Ca>Ba>K
10219.

Which of the following is a false statement [CPMT 2004]

A. Fluorine is more electronegative than chlorine
B. Nitrogen has greater \[\text{I}{{\text{E}}_{1}}\]than oxygen
C. Lithium is amphoteric
D. Chlorine is an oxidising agent
Answer» D. Chlorine is an oxidising agent
10220.

Alkaline earth metals are denser than alkali metals, because metallic bonding in alkaline earth's metal, is [BHU 2004]

A. Stronger
B. Weaker
C. Volatile
D. Not present
Answer» B. Weaker
10221.

The ratio of \[\frac{{{C}_{p}}}{{{C}_{v}}}\] for inert gases is [DCE 1999]

A. 1.99
B. 2.13
C. 1.66
D. 1.33
Answer» D. 1.33
10222.

Out of (i) \[Xe{{O}_{3}}\] (ii) \[XeO{{F}_{4}}\] and (iii) \[Xe{{F}_{6}}\], the molecules having same number of lone pairs on Xe are

A. (i) and (ii) only
B. (i) and (iii) only
C. (ii) and (iii) only
D. (i), (ii) and (iii)
Answer» E.
10223.

Which one of the following is correct pair with respect to molecular formula of xenon compound and hybridization state of xenon in it?

A. \[Xe{{F}_{4}},s{{p}^{3}}\]
B. \[Xe{{F}_{2}},sp\]
C. \[Xe{{F}_{2}},s{{p}^{3}}d\]
D. \[Xe{{F}_{4}},s{{p}^{2}}\]
Answer» D. \[Xe{{F}_{4}},s{{p}^{2}}\]
10224.

Incorrect statement regarding following reactions is:

A. 'X' is explosive
B. 'Y' is an oxyacid of xenon
C. Both are example of non-redox reaction
D. \[Xe{{F}_{6}}\] can undergo partial hydrolysis.
Answer» C. Both are example of non-redox reaction
10225.

Which of the following xenon-oxo compounds may not be obtained by hydrolysis of xenon fluorides?

A. \[Xe{{O}_{2}}{{F}_{2}}\]
B. \[XeO{{F}_{4}}\]
C. \[Xe{{O}_{3}}\]
D. \[Xe{{O}_{4}}\]
Answer» E.
10226.

Chlorine cannot displace

A. fluorine from NaF
B. iodine from Nal
C. bromine from NaBr
D. None of these
Answer» B. iodine from Nal
10227.

Excess of KI reacts with \[CuS{{O}_{4}}\] solution and then \[N{{a}_{2}}{{S}_{2}}{{O}_{3}}\] solution is added to it. Which of the statements is incorrect for this reaction?

A. \[N{{a}_{2}}{{S}_{2}}{{O}_{3}}\] is oxidized
B. \[Cu{{I}_{2}}\] is formed
C. \[C{{u}_{2}}{{I}_{2}}\] is formed
D. Evolved \[{{I}_{2}}\] is reduced
Answer» C. \[C{{u}_{2}}{{I}_{2}}\] is formed
10228.

Which of the following form of the sulphur shows paramagnetic behaviour?

A. \[{{S}_{8}}\]
B. \[{{S}_{6}}\]
C. \[{{S}_{2}}\]
D. All of these
Answer» D. All of these
10229.

The shape of the molecule \[S{{F}_{3}}C{{l}_{3}}\] is

A. trigonal bipyramidal
B. cubic
C. octahedral
D. tetrahedral
Answer» D. tetrahedral
10230.

\[N{{H}_{4}}Cl{{O}_{4}}+HN{{O}_{3}}\left( dil. \right)\xrightarrow{{}}HCl{{O}_{4}}+\left[ X \right]\] \[[X]\xrightarrow{\Delta }Y(g)\] [X] and [Y] are respectively-

A. \[N{{H}_{4}}N{{O}_{3}}\And {{N}_{2}}O\]
B. \[N{{H}_{4}}N{{O}_{2}}\And {{N}_{2}}\]
C. \[HN{{O}_{4}}\And {{O}_{2}}\]
D. None of these
Answer» B. \[N{{H}_{4}}N{{O}_{2}}\And {{N}_{2}}\]
10231.

Concentrated \[{{H}_{2}}S{{O}_{4}}\] is not used to prepare \[HBr\] from KBr because it

A. oxidizes \[HBr\].
B. reduces \[HBr\].
C. causes disproportionation of \[HBr\].
D. reacts too slowly with KBr.
Answer» B. reduces \[HBr\].
10232.

A white precipitate is obtained on hydrolysis of

A. \[PC{{l}_{5}}\]
B. \[NC{{l}_{3}}\]
C. \[BiC{{l}_{3}}\]
D. \[AsC{{l}_{3}}\]
Answer» D. \[AsC{{l}_{3}}\]
10233.

Which of the following compound has a P-P bond?

A. \[{{H}_{4}}{{P}_{2}}{{O}_{5}}\]
B. \[{{(HP{{O}_{3}})}_{3}}\]
C. \[{{H}_{4}}{{P}_{2}}{{O}_{6}}\]
D. \[{{H}_{4}}{{P}_{2}}{{O}_{7}}\]
Answer» D. \[{{H}_{4}}{{P}_{2}}{{O}_{7}}\]
10234.

A metal X on heating in nitrogen gas gives Y. Y on treatment with \[{{H}_{2}}O\] gives a colourless gas which when passed through \[CuS{{O}_{4}}\] solution gives a blue colour. Y is

A. \[Mg{{(N{{O}_{3}})}_{2}}\]
B. \[M{{g}_{3}}{{N}_{2}}\]
C. \[N{{H}_{3}}\]
D. \[MgO\]
Answer» C. \[N{{H}_{3}}\]
10235.

Which of the following compounds does not exist?

A. \[AsC{{l}_{5}}\]
B. \[SbC{{l}_{3}}\]
C. \[BiC{{l}_{5}}\]
D. \[SbC{{l}_{5}}\]
Answer» D. \[SbC{{l}_{5}}\]
10236.

Which of the following conceivable structures for \[CC{{l}_{4}}\] will have a zero dipole moment?

A. Square planar
B. Square pyramid (carbon at apex)
C. Irregular tetrahedron
D. None of these
Answer» E.
10237.

In which of the following, a salt of the type \[KM{{O}_{2}}\] is obtained?

A. \[{{B}_{2}}{{H}_{6}}+KOH\,(aq)\to \]
B. \[Al+KOH\left( aq \right)\to \]
C. Both
D. None of these
Answer» D. None of these
10238.

Among the following substituted silanes the one which will give rise to cross linked silicone polymer on hydrolysis is

A. \[{{R}_{4}}Si\]
B. \[{{R}_{2}}SiC{{l}_{2}}\]
C. \[RSiC{{l}_{3}}\]
D. \[{{R}_{3}}SiCl\]
Answer» B. \[{{R}_{2}}SiC{{l}_{2}}\]
10239.

\[Pb{{F}_{4}},PbC{{l}_{4}}\] exist but \[PbB{{r}_{4}}\] and \[Pb{{I}_{4}}\] do not exist because of

A. large size of \[B{{r}^{-}}\] and \[{{I}^{-}}\]
B. strong oxidising character of \[P{{b}^{4+}}\]
C. strong reducing character of \[P{{b}^{4+}}\]
D. low electronegativity of \[B{{r}^{-}}\] and \[{{I}^{-}}\].
Answer» C. strong reducing character of \[P{{b}^{4+}}\]
10240.

The correct order of increasing \[C-O\] bond length of \[CO,C{{O}_{2}}\] and \[CO_{3}^{2-}\] is:

A. \[CO_{3}^{2-}~<C{{O}_{2}}<CO\]
B. \[C{{O}_{2}}<CO_{3}^{2-}<CO\]
C. \[CO<CO_{3}^{2-}<C{{O}_{2}}\]
D. \[CO<C{{O}_{2}}<CO_{3}^{2-}\]
Answer» E.
10241.

The correct statement with respect to CO is

A. it combines with \[{{H}_{2}}O\] to give carbonic acid
B. it reacts with haemoglobin in RBC
C. it is powerful oxidising agent
D. it is used to prepare aerated drinks
Answer» C. it is powerful oxidising agent
10242.

An aqueous solution of \[FeS{{O}_{4}},A{{l}_{2}}{{(S{{O}_{4}})}_{3}}\] and chrome alum is heated with excess of \[N{{a}_{2}}{{O}_{2}}\] and filtered. The materials obtained are:

A. a colourless filtrate and a green residue
B. a yellow filtrate and a green residue
C. a yellow filtrate and a brown residue
D. a green filtrate and a brown residue
Answer» D. a green filtrate and a brown residue
10243.

Which of the following group shows the highest boiling point [MP PET 2002]

A. \[{{H}_{2}}O\]
B. \[{{H}_{2}}S\]
C. \[{{H}_{2}}Se\]
D. \[{{H}_{2}}Te\]
Answer» B. \[{{H}_{2}}S\]
10244.

Shape of \[{{O}_{2}}{{F}_{2}}\] is similar to that of [AIIMS 2004]

A. \[{{C}_{2}}{{F}_{2}}\]
B. \[{{H}_{2}}{{O}_{2}}\]
C. \[{{H}_{2}}{{F}_{2}}\]
D. \[{{C}_{2}}{{H}_{2}}\]
Answer» C. \[{{H}_{2}}{{F}_{2}}\]
10245.

Which is not easily soluble in water [CPMT 1994]

A. \[{{H}_{2}}\]
B. \[{{O}_{2}}\]
C. \[S{{O}_{2}}\]
D. \[C{{O}_{2}}\]
Answer» D. \[C{{O}_{2}}\]
10246.

Which of the following products is formed on boiling tin with an alkali solution [Roorkee 2000]

A. \[Sn{{(OH)}_{2}}\]
B. \[Sn{{(OH)}_{4}}\]
C. \[SnO_{3}^{2-}\]
D. \[Sn{{O}_{2}}\]
Answer» D. \[Sn{{O}_{2}}\]
10247.

An example of a neutral oxide is [KCET 2003]

A. \[NO\]
B. \[C{{O}_{2}}\]
C. \[CaO\]
D. \[ZnO\]
Answer» B. \[C{{O}_{2}}\]
10248.

Hypo is used in photography to [CBSE PMT 1988; Pb. CET 1989]

A. Reduce \[AgBr\] grains to metallic silver
B. Convert the metallic silver to silver salt
C. Remove undecomposed silver bromide as a soluble complex
D. Remove reduced silver
Answer» D. Remove reduced silver
10249.

The element which liberates oxygen gas from water is [MP PMT 1993]

A. \[P\]
B. \[Na\]
C. \[F\]
D. \[I\]
Answer» D. \[I\]
10250.

The acid used in lead storage cells is [NCERT 1971; Roorkee 1989]

A. Phosphoric acid
B. Nitric acid
C. Sulphuric acid
D. Hydrochloric acid
Answer» D. Hydrochloric acid