Explore topic-wise MCQs in Joint Entrance Exam - Main (JEE Main).

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3351.

Urea is preferred to ammonium sulphate as a nitrogeneous fertilizer because  [KCET 2003]

A. It is more soluble in water
B. It is cheaper than ammonium sulphate
C. It is quite stable
D. It does not cause acidity in the soil
Answer» E.
3352.

In case of nitrogen, \[NC{{l}_{3}}\] is possible but not \[NC{{l}_{5}}\] while in case of phosphorous, \[PC{{l}_{3}}\] as well as \[PC{{l}_{5}}\]are possible. It is due to [AIEEE 2002]

A. Availability of vacant d-orbital in P but not in N
B. Lower electronegativity of P than N
C. Lower tendency of H bond formation in P than N
D. Occurrence of P in solid while N in gaseous state at room temperature
Answer» B. Lower electronegativity of P than N
3353.

The three important oxidation states of phosphorus are [Kerala (Med.) 2002]

A. \[-3,\,+3\] and \[+5\]
B. \[-3,\,+3\] and \[-5\]
C. \[-3,\,+4\] and \[-4\]
D. \[-3,\,+3\] and \[+4\]
Answer» B. \[-3,\,+3\] and \[-5\]
3354.

The most common minerals of phosphorus are [Kerala (Med.) 2002]

A. Hydroxy apatite and kernite
B. Colemanite and fluoraptite
C. Borax and fluoraptite
D. Hydroxy apatite and colemanite
E.   Hydroxy apatite and fluorapatile
Answer» F.
3355.

Atoms in a \[{{P}_{4}}\] molecule of white phosphorus are arranged regularly in space in which of the following way [Kerala (Engg.) 2002]

A. At the corners of tetrahedron
B. At the corners of a cube
C. At the corners of a four membered ring
D. At the centre and corners of an equilateral triangle
Answer» B. At the corners of a cube
3356.

Solid \[PC{{l}_{5}}\] exits as [JIPMER 2002]

A. \[PC{{l}_{5}}\]
B. \[PCl_{4}^{+}\]
C. \[PCl_{6}^{-}\]
D. \[PCl_{4}^{+}\] and \[PCl_{6}^{-}\]
Answer» E.
3357.

Superphosphate is a mixture of [KCET (Med.) 2001]

A. \[Ca{{({{H}_{2}}P{{O}_{4}})}_{2}}{{H}_{2}}O+CaC{{l}_{2}}\,.\,2{{H}_{2}}O\]
B. \[C{{a}_{3}}{{(P{{O}_{4}})}_{2}}\,.\,{{H}_{2}}O+CaC{{l}_{2}}\,.\,2{{H}_{2}}O\]
C. \[C{{a}_{3}}{{(P{{O}_{4}})}_{2}}\,.\,{{H}_{2}}O+2CaS{{O}_{4}}\,.\,2{{H}_{2}}O\]
D. \[Ca{{({{H}_{2}}P{{O}_{4}})}_{2}}.\,{{H}_{2}}O+2CaS{{O}_{4}}\,.\,2{{H}_{2}}O\]
Answer» E.
3358.

\[HN{{O}_{3}}\] in aqueous solution yields [AMU 2000]

A. \[NO_{3}^{-}\] and \[{{H}^{+}}\]
B. \[NO_{3}^{-}\] and \[{{H}_{3}}{{O}^{+}}\]
C. \[NO_{2}^{-}\] and \[O{{H}^{-}}\]
D. \[{{N}_{2}}{{O}_{5}}\] and \[{{H}_{2}}O\]
Answer» C. \[NO_{2}^{-}\] and \[O{{H}^{-}}\]
3359.

In the following reaction \[{{P}_{4}}+3NaOH+3{{H}_{2}}O\to P{{H}_{3}}+3Na{{H}_{2}}P{{O}_{2}}\] [MP PMT 1994]

A. Phosphorus is oxidised
B. Phosphorus is oxidised and reduced
C. Phosphorus is reduced
D. Sodium is oxidized
Answer» C. Phosphorus is reduced
3360.

Which of the following has highest boiling point [MP PET 1994]

A. \[N{{H}_{3}}\]
B. \[P{{H}_{3}}\]
C. \[As{{H}_{3}}\]
D. \[Sb{{H}_{3}}\]
Answer» E.
3361.

Which of the following exhibits highest solubility in water [MP PET 1994]

A. \[N{{H}_{3}}\]
B. \[P{{H}_{3}}\]
C. \[As{{H}_{3}}\]
D. \[Sb{{H}_{3}}\]
Answer» B. \[P{{H}_{3}}\]
3362.

Sodium hydroxide solution reacts with phosphorus to give phosphine. To bring about this reaction, we need [KCET 1989]

A. White phosphorus and dil. \[NaOH\]
B. White phosphorus and conc. \[NaOH\]
C. Red phosphorus and dil. \[NaOH\]
D. Red phosphorus and conc. \[NaOH\]
Answer» C. Red phosphorus and dil. \[NaOH\]
3363.

Blasting of TNT is done by mixing [AFMC 1993]

A. \[N{{H}_{4}}Cl\]
B. \[N{{H}_{4}}N{{O}_{3}}\]
C. \[N{{H}_{4}}N{{O}_{2}}\]
D. \[{{(N{{H}_{4}})}_{2}}S{{O}_{4}}\]
Answer» C. \[N{{H}_{4}}N{{O}_{2}}\]
3364.

When equal weights of the two fertilizers, urea and ammonium sulphate are taken, urea contains [KCET 1989]

A. Less nitrogen than ammonium sulphate
B. As much nitrogen as ammonium sulphate
C. Twice the amount of nitrogen present in ammonium sulphate
D. More than twice the amount of nitrogen present in ammonium sulphate
Answer» E.
3365.

Among the following nitrates, Lead nitrate, Silver nitrate and Ammonium nitrate; the one that decomposes without leaving any solid residue is [NCERT 1983]

A. Lead nitrate
B. Ammonium nitrate
C. Silver nitrate
D. Sodium nitrate
Answer» C. Silver nitrate
3366.

Thomas slag is [CPMT 1988]

A. \[C{{a}_{3}}{{(P{{O}_{4}})}_{2}}\]
B. \[MnSi{{O}_{3}}\]
C. \[CaSi{{O}_{3}}\]
D. \[FeSi{{O}_{3}}\]
Answer» B. \[MnSi{{O}_{3}}\]
3367.

Which one has the highest percentage of nitrogen [KCET 1991; CBSE PMT 1993; AIIMS 1996, MP PET 2001; RPET 2003]

A. Urea
B. Ammonium sulphate
C. Ammonium nitrate
D. Calcium nitrate
Answer» B. Ammonium sulphate
3368.

At high temperature nitrogen combines with calcium carbide \[(Ca{{C}_{2}})\] to give [DPMT 1981, 85; AFMC 1998;  MP PET 2000]

A. Calcium cyanide
B. Calcium cyanamide
C. Calcium carbonate
D. Calcium nitride
Answer» C. Calcium carbonate
3369.

\[BiC{{l}_{3}}\] on hydrolysis forms a white precipitate of [CPMT 1988]

A. Bismuthio acid
B. Bismuth oxychloride
C. Bismuth pentachloride
D. Bismuth hydroxide
Answer» C. Bismuth pentachloride
3370.

The number of hydroxyl group in pyrophosphoric acid is [KCET 1993]

A. 3
B. 4
C. 5
D. 7
Answer» C. 5
3371.

Cyanamide process is used in the formation of [BHU 1995]

A. \[{{N}_{2}}\]
B. \[HN{{O}_{3}}\]
C. \[N{{H}_{3}}\]
D. \[P{{H}_{3}}\]
Answer» D. \[P{{H}_{3}}\]
3372.

In Birkeland-Eyde process, the raw material used is [CPMT 1982, 86]

A. Air
B. \[N{{H}_{3}}\]
C. \[N{{O}_{2}}\]
D. \[HN{{O}_{3}}\]
Answer» B. \[N{{H}_{3}}\]
3373.

Which is not an acid salt [MNR 1989]

A. \[Na{{H}_{2}}P{{O}_{3}}\]
B. \[Na{{H}_{2}}P{{O}_{2}}\]
C. \[N{{a}_{3}}H{{P}_{2}}{{O}_{6}}\]
D. \[N{{a}_{4}}{{P}_{2}}{{O}_{7}}\]
Answer» E.
3374.

Oxidation state of + 1 for phosphorus is found in [MP PMT 1991; MP PET 2001]

A. \[{{H}_{3}}P{{O}_{3}}\]
B. \[{{H}_{3}}P{{O}_{4}}\]
C. \[{{H}_{3}}P{{O}_{2}}\]
D. \[{{H}_{4}}{{P}_{2}}{{O}_{7}}\]
Answer» D. \[{{H}_{4}}{{P}_{2}}{{O}_{7}}\]
3375.

\[{{H}_{3}}P{{O}_{3}}\] is [CPMT 1977, 79, 94; NCERT 1981; MP PMT 1980]

A. A tribasic acid
B. A dibasic acid
C. Neutral
D. A monobasic acid
Answer» C. Neutral
3376.

\[PC{{l}_{3}}\] reacts with water to form [KCET 1990; CBSE PMT 1991; CPMT 2003]

A. \[P{{H}_{3}}\]
B. \[{{H}_{3}}P{{O}_{3}},\]\[HCl\]
C. \[POC{{l}_{3}}\]
D. \[{{H}_{3}}P{{O}_{4}}\]
Answer» C. \[POC{{l}_{3}}\]
3377.

\[{{P}_{2}}{{O}_{5}}\] is heated with water to give [CBSE PMT 1991; DPMT 2000]

A. Hypophosphorus acid
B. Orthophosphorus acid
C. Hypophosphoric acid
D. Orthophosphoric acid
Answer» E.
3378.

One of the acid listed below is formed from \[{{P}_{2}}{{O}_{3}}\] and the rest are formed from \[{{P}_{2}}{{O}_{5}}\]. The acid formed from phosphorus (III) oxide is [NCERT 1975]

A. \[HP{{O}_{3}}\]
B. \[{{H}_{4}}{{P}_{2}}{{O}_{7}}\]
C. \[{{H}_{3}}P{{O}_{4}}\]
D. \[{{H}_{3}}P{{O}_{3}}\]
Answer» E.
3379.

With reference to protonic acids, which of the following statements is correct [CPMT 1990]

A. \[P{{H}_{3}}\] is more basic than \[N{{H}_{3}}\]
B. \[P{{H}_{3}}\] is less basic than \[N{{H}_{3}}\]
C. \[P{{H}_{3}}\] is equally basic as \[N{{H}_{3}}\]
D. \[P{{H}_{3}}\] is amphoteric while \[N{{H}_{3}}\] is basic
Answer» C. \[P{{H}_{3}}\] is equally basic as \[N{{H}_{3}}\]
3380.

When aluminium phosphide is treated with dil. sulphuric acid [KCET 1989]

A. \[S{{O}_{2}}\] is liberated
B. \[P{{H}_{3}}\] is evolved
C. \[{{H}_{2}}S\] is evolved
D. \[{{H}_{2}}\] is evolved
Answer» C. \[{{H}_{2}}S\] is evolved
3381.

Phosphine is produced by adding water to [KCET 1991]

A. \[Ca{{C}_{2}}\]
B. \[HP{{O}_{3}}\]
C. \[C{{a}_{3}}{{P}_{2}}\]
D. \[{{P}_{4}}{{O}_{10}}\]
Answer» D. \[{{P}_{4}}{{O}_{10}}\]
3382.

Ammonium nitrate decomposes on heating into [NCERT 1974,75; CPMT 1973, 78, 88, 94; AMU 1984]

A. Ammonia and nitric acid
B. Nitrous oxide and water
C. Nitrogen, hydrogen and ozone
D. Nitric oxide, nitrogen dioxide and hydrogen
Answer» C. Nitrogen, hydrogen and ozone
3383.

\[P{{H}_{4}}I+NaOH\] forms [CBSE PMT 1991]

A. \[P{{H}_{3}}\]
B. \[N{{H}_{3}}\]
C. \[{{P}_{4}}{{O}_{6}}\]
D. \[{{P}_{4}}{{O}_{10}}\]
Answer» B. \[N{{H}_{3}}\]
3384.

Phosphine is not obtained by the reaction [MP PMT 1989]

A. White P is heated with \[NaOH\]
B. Red P is heated with \[NaOH\]
C. \[C{{a}_{3}}{{P}_{2}}\] reacts with water
D. Phosphorus trioxide is boiled with water
Answer» C. \[C{{a}_{3}}{{P}_{2}}\] reacts with water
3385.

In modern process phosphorus is manufactured by [CPMT 1974, 78, 81]

A. Heating a mixture of phosphorite mineral with sand and coke in electric furnace
B. Heating calcium phosphate with coke
C. Heating bone ash with coke
D. Heating the phosphate mineral with sand
Answer» B. Heating calcium phosphate with coke
3386.

White phosphorus when boiled with strong solution of caustic soda produces [CPMT 1989,03]

A. Phosphine
B. Phosphoric acid
C. Phosphorus acid
D. No reaction
Answer» B. Phosphoric acid
3387.

Mixture used for the tips of match stick is [DPMT 1984]

A. \[S+K\]
B. \[S{{b}_{2}}{{S}_{3}}\]
C. \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}+S+\]red P
D. \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}+K+S\]
Answer» D. \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}+K+S\]
3388.

Which of the following properties of white phosphorus are shared by red phosphorus [NCERT 1973, 74]

A. It shows phosphorescenes in air
B. It reacts with hot aqueous \[NaOH\] to give phosphine
C. It dissolves in carbon disulphide
D. It burns when heated in air
Answer» E.
3389.

Bones glow in the dark because [EAMCET 1980]

A. They contain shining material
B. They contain red phosphorus
C. White phosphorus undergoes slow combustion in contact with air
D. White phosphorus changes into red form
Answer» D. White phosphorus changes into red form
3390.

Which of the following phosphorus is most stable [AFMC 1992]

A. Red
B. White
C. Black
D. All stable
Answer» B. White
3391.

Red phosphorus can be obtained from white phosphorus by [KCET 1989]

A. Heating it with a catalyst in an inert atmosphere
B. Distilling it in an inert atmosphere
C. Dissolving it in carbon disulphide and crystallizing
D. Melting it and pouring the liquid into water
Answer» B. Distilling it in an inert atmosphere
3392.

Phosphide ion has the electronic structure similar to that of [CPMT 1988]

A. Nitride ion
B. Fluoride ion
C. Sodium ion
D. Chloride ion
Answer» E.
3393.

White phosphorus \[\left( {{P}_{4}} \right)\] has [IIT 1998]

A. Six P - P single bonds
B. Four P - P single bonds
C. Four lone pairs of electrons
D. PPP angle of \[{{60}^{o}}\]
Answer» B. Four P - P single bonds
3394.

\[PC{{l}_{5}}\] exists but \[NC{{l}_{5}}\] does not because [EAMCET 1977, 82]

A. Nitrogen has no vacant orbitals
B. \[NC{{l}_{5}}\] is unstable
C. Nitrogen atom is much smaller
D. Nitrogen is highly inert
Answer» B. \[NC{{l}_{5}}\] is unstable
3395.

A hydride of nitrogen which is acidic is [NCERT 1978, 80; CPMT 1980; BHU 1986]

A. \[N{{H}_{3}}\]
B. \[{{N}_{2}}{{H}_{4}}\]
C. \[{{N}_{2}}{{H}_{2}}\]
D. \[{{N}_{3}}H\]
Answer» E.
3396.

Nitrogen is essential constituent of all [MP PMT 1990]

A. Proteins
B. Fats
C. Proteins and fats
D. None of these
Answer» B. Fats
3397.

Ammonia gas can be collected by the displacement of [NCERT 1989, 90]

A. Conc. \[{{H}_{2}}S{{O}_{4}}\]
B. Brine
C. Water
D. Mercury
Answer» E.
3398.

A mixture of ammonia and air at about \[{{800}^{o}}C\] in the presence of Pt gauze forms [Pb. CET 1989]

A. \[{{N}_{2}}O\]
B. \[NO\]
C. \[N{{H}_{2}}OH\]
D. \[{{N}_{2}}{{O}_{3}}\]
Answer» C. \[N{{H}_{2}}OH\]
3399.

Concentrated nitric acid oxidises cane sugar to [CBSE PMT 1991]

A. \[C{{O}_{2}}\] and \[{{H}_{2}}O\]
B. \[CO\] and \[{{H}_{2}}O\]
C. \[CO,\] \[C{{O}_{2}}\] and \[{{H}_{2}}O\]
D. Oxalic acid and water
Answer» E.
3400.

Nitrogen dioxide [KCET 1989]

A. Dissolves in water forming nitric acid
B. Does not dissolve in water
C. Dissolves in water to form nitrous acid and gives off oxygen
D. Dissolves in water to form a mixture of nitrous and nitric acids
Answer» E.