Explore topic-wise MCQs in Joint Entrance Exam - Main (JEE Main).

This section includes 11242 Mcqs, each offering curated multiple-choice questions to sharpen your Joint Entrance Exam - Main (JEE Main) knowledge and support exam preparation. Choose a topic below to get started.

2901.

Oxidation number of \[Fe\]in \[{{K}_{3}}[Fe{{(CN)}_{6}}]\] is [AMU 1988]

A.                 + 2         
B.                 + 3
C.                 + 1         
D.                 + 4
Answer» C.                 + 1         
2902.

The oxidation number of fluorine in \[{{F}_{2}}O\] is [CPMT 1982; BHU 1982; EAMCET 1986]

A. - 1         
B. 1
C. + 2         
D. -2
Answer» B. 1
2903.

The oxidation number of nickel in \[{{K}_{4}}[Ni{{(CN)}_{4}}]\] is [JIPMER 1999]

A. - 2         
B. -1
C. + 2         
D. 0
Answer» E.
2904.

Identify the element which can have highest oxidation numbers              [AIIMS 1996]

A.                 \[N\]    
B.                 \[O\]
C.                 \[Cl\]
D.                 \[C\]
Answer» D.                 \[C\]
2905.

The oxidation number of C in \[C{{O}_{2}}\]is     [MP PET 2001]

A. -2         
B. 2
C. -4         
D. 4
Answer» E.
2906.

When \[{{K}_{2}}C{{r}_{2}}{{O}_{7}}\] is converted to \[{{K}_{2}}Cr{{O}_{4}},\] the change in the oxidation state of chromium is       [NCERT 1981]

A.                 0             
B.                 6
C.                 4             
D.                 3
Answer» B.                 6
2907.

In the series ethane, ethylene and acetylene, the \[C-H\]  bond energy is                                            [NCERT 1977]

A.                 The same in all the three compounds
B.                 Greatest in ethane
C.                 Greatest in ethylene
D.                 Greatest in acetylene
Answer» E.
2908.

The double bond between the two carbon atoms in ethylene consists of                      [NCERT 1981; EAMCET 1979]

A.                 Two sigma bonds at right angles to each other
B.                 One sigma bond and one pi bond
C.                 Two pi bonds at right angles to each other
D.                 Two pi bonds at an angle of \[{{60}^{o}}\] to each other
Answer» C.                 Two pi bonds at right angles to each other
2909.

\[\pi \]bond is formed                                   [JIPMER 2002]

A.                 By overlapping of atomic orbitals on the axis of nuclei
B.                 By mutual sharing of pi electron
C.                 By sidewise overlapping of half filled p-orbitals
D.                 By overlapping of s-orbitals with p-orbitals
Answer» D.                 By overlapping of s-orbitals with p-orbitals
2910.

Strongest bond is                                             [DPMT 1990]

A.                 \[C-C\] 
B.                 \[C=C\]
C.                 \[C\equiv C\]    
D.                 All are equally strong
Answer» D.                 All are equally strong
2911.

In a double bond connecting two atoms, there is a sharing of [CPMT 1977, 80, 81; NCERT 1975; Bihar MEE 1980; MP PET 1999]

A.                 2 electrons         
B.                 1 electron
C.                 4 electrons         
D.                 All electrons
Answer» D.                 All electrons
2912.

The number and type of bonds between two carbon atoms in calcium carbide are           [AIEEE 2005]

A.                 One sigma, one pi           
B.                 One sigma, two pi
C.                 Two sigma, one pi           
D.                 Two singma, two pi
Answer» C.                 Two sigma, one pi           
2913.

Which type of overlapping results the formation of a \[\pi \]bond [DPMT 1981]

A.                 Axial overlapping of \[s-s\] orbitals
B.                 Lateral overlapping of \[p-p\]orbitals
C.                 Axial overlapping of \[p-p\] orbitals
D.                 Axial overlapping of \[s-p\] orbitals
Answer» C.                 Axial overlapping of \[p-p\] orbitals
2914.

Number of sigma bonds in \[{{P}_{4}}{{O}_{10}}\] is        [AIEEE 2002]

A.                 6             
B.                 7
C.                 17          
D.                 16
Answer» E.
2915.

Number of bonds in \[S{{O}_{2}}\]          [DCE 2001]

A.                 Two s and two p             
B.                 Two s and one p
C.                 Two s, two p and one lone pair
D.                 None of these
Answer» D.                 None of these
2916.

The bond in the formation of fluorine molecule will be [MP PMT 1987]

A.                 Due to \[PC{{l}_{5}}\] overlapping
B.                 Due to \[s-p\] overlapping
C.                 Due to \[{{H}_{2}}{{O}_{2}}>{{O}_{3}}>{{O}_{2}}\] overlapping
D.                 Due to hybridization
Answer» D.                 Due to hybridization
2917.

In which of following there exists a \[p\pi -d\pi \] bonding [AFMC 2001]

A.                 Diamond             
B.                 Graphite
C.                 Dimethyl amine               
D.                 Trisilylamine
Answer» E.
2918.

In \[{{N}_{2}}\]molecule, the atoms are bonded by [MP PET 1996; UPSEAT 2001]

A.                 One s, Two p    
B.                 One s, One p
C.                 Two s, One p    
D.                 Three s bonds
Answer» B.                 One s, One p
2919.

The \[p-p\] orbital overlapping is present in the following molecule                         [MP PET 1994]

A.                 Hydrogen           
B.                 Hydrogen bromide
C.                 Hydrogen chloride          
D.                 Chlorine
Answer» E.
2920.

Which of the following is not correct       [CBSE PMT 1990]

A.                 A sigma bond is weaker than \[\pi \]bond
B.                 A sigma bond is stronger than \[\pi \]bond
C.                 A double bond is stronger than a single bond
D.                 A double bond is shorter than a single bond
Answer» B.                 A sigma bond is stronger than \[\pi \]bond
2921.

The most acidic compound among the following is [MP PET 1993]

A.                 \[C{{H}_{3}}C{{H}_{2}}OH\]        
B.                 \[{{C}_{6}}{{H}_{5}}OH\]
C.                 \[C{{H}_{3}}COOH\]       
D.                 \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}OH\]
Answer» D.                 \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}OH\]
2922.

The number of sigma and pi bonds in 1-butene-3-yne are [IIT 1989]

A.                 5 sigma and 5 pi               
B.                 7 sigma and 3 pi
C.                 8 sigma and 2 pi               
D.                 6 sigma and 4 pi
Answer» C.                 8 sigma and 2 pi               
2923.

Triple bond in ethyne is formed from [MP PMT 1990; NCERT 1979; EAMCET 1978; AMU 1985; CPMT 1988; MADT Bihar 1982; MH CET 2000]

A.                 Three sigma bonds         
B.                 Three pi bonds
C.                 One sigma and two pi bonds
D.                 Two sigma and one pi bond
Answer» D.                 Two sigma and one pi bond
2924.

Semipermeable membrane is that which permits the passage of    [BHU 1979; CPMT 1977, 84, 90; MP PMT 1994]

A.                 Solute molecules only
B.                 Solvent molecules only
C.                 Solute and solvent molecules both
D.                 Neither solute nor solvent molecules
Answer» C.                 Solute and solvent molecules both
2925.

In osmosis                                              [DPMT 1985]

A.                 Solvent molecules move from higher concentration to lower concentration
B.                 Solvent molecules move from lower to higher concentration
C.                 Solute molecules move from higher to lower concentration
D.                 Solute molecules move from lower to higher concentration
Answer» C.                 Solute molecules move from higher to lower concentration
2926.

The relationship between osmotic pressure at \[273\,K\] when \[10g\] glucose \[({{P}_{1}}),\,10g\] urea \[({{P}_{2}})\] and \[10g\] sucrose \[({{P}_{3}})\] are dissolved in \[250ml\] of water is       [CBSE PMT 1996]

A.                 \[{{P}_{1}}>{{P}_{2}}>{{P}_{3}}\]            
B.                 \[{{P}_{3}}>{{P}_{1}}>{{P}_{2}}\]
C.             \[{{P}_{2}}>{{P}_{1}}>{{P}_{3}}\]          
D.                 \[{{P}_{2}}>{{P}_{3}}>{{P}_{1}}\]
Answer» D.                 \[{{P}_{2}}>{{P}_{3}}>{{P}_{1}}\]
2927.

Which of the following aqueous solutions are isotonic \[(R=0.082\] atm \[{{K}^{-1}}mo{{l}^{-1}})\]              [Roorkee Qualifying 1998]

A.                 \[0.01\,M\] glucose
B.                 \[0.01\,M\,NaN{{O}_{3}}\]
C.             \[500\,ml\] solution containing \[0.3\,g\] urea
D.                 \[0.04\,N\,HCl\]
Answer» B.                 \[0.01\,M\,NaN{{O}_{3}}\]
2928.

Which of the following aqueous solutions produce the same osmotic pressure           [Roorkee 1999]

A.                 0.1 M  NaCl  solution
B.                 0.1 M glucose solution
C.             0.6 g urea in 100 ml solution
D.                 1.0 g of a non-electrolyte solute (X) in 50 ml solution (Molar mass of X = 200)
Answer» C.             0.6 g urea in 100 ml solution
2929.

A solution of urea contain 8.6 gm/litre (mol. wt. 60.0). It is isotonic with a 5% solution of a non-volatile solute. The molecular weight of the solute will be     [MP PMT 1986]

A.                 348.9     
B.                 34.89
C.                 3489      
D.                 861.2
Answer» B.                 34.89
2930.

As a result of osmosis the volume of solution [JIPMER 2000]

A.                 Increases               
B.                 Decreases
C.                 Remains constant 
D.                 Increases or decreases
Answer» E.
2931.

In osmosis reaction, the volume of solution

A.                 Decreases slowly  
B.                 Increases slowly
C.                 Suddenly increases              
D.                 No change
Answer» C.                 Suddenly increases              
2932.

If osmotic pressure of a solution is \[2\,atm\] at \[273K\], then at \[546K\], the osmotic pressure is

A.                 0.5 atm  
B.                 1 atm
C.                 2 atm     
D.                 4 atm
Answer» E.
2933.

If solubility of  \[NaCl\]  at \[{{20}^{o}}C\] is 35 \[gm\] per 100 gm of water. Then on adding 50 gm of \[NaCl\] to the same volume at same temperature the salt remains undissolved is

A.                 15 gm    
B.                 20 gm
C.                 50 gm    
D.                 35 gm
Answer» B.                 20 gm
2934.

If molecular weight of compound is increased then sensitivity is decreased in which of the following methods [DCE 2001]

A.                 Elevation in boiling point
B.                 Viscosity
C.                 Osmosis
D.                 Dialysis
Answer» E.
2935.

Solvent molecules pass through the semipermeable membrane is called [CPMT 1983; MP PMT 1987; RPET 2000; DCE 2004]

A.                 Electrolysis            
B.                 Electrophoresis
C.                 Cataphoresis         
D.                 Osmosis
Answer» E.
2936.

The solution containing \[4.0gm\] of a polyvinyl chloride polymer in 1 litre of dioxane was found to have an osmotic pressure  \[6.0\times {{10}^{-4}}\] atmosphere at\[300K\],  the value of R used is 0.082 litre atmosphere\[mol{{e}^{-1}}{{k}^{-1}}\]. The molecular mass of the polymer was found to be     [NCERT 1978]

A.                 \[3.0\times {{10}^{2}}\]   
B.                 \[1.6\times {{10}^{5}}\]
C.                 \[5.6\times {{10}^{4}}\]   
D.                 \[6.4\times {{10}^{2}}\]
Answer» C.                 \[5.6\times {{10}^{4}}\]   
2937.

A solution contains non-volatile solute of molecular mass \[{{M}_{p}}\]. Which of the following can be used to calculate molecular mass of the solute in terms of osmotic pressure (m = Mass of solute, V = Volume of solution and  p = Osmotic pressure)                                      [CBSE PMT 2002]

A.                 \[Mp=\left( \frac{m}{\pi } \right)\,VRT\]\[\]             
B.             \[Mp=\left( \frac{m}{V} \right)\frac{RT}{\pi }\]
C.                 \[Mp=\left( \frac{m}{V} \right)\frac{\pi }{RT}\]
D.                 \[Mp=\left( \frac{m}{V} \right)\,\pi RT\]
Answer» C.                 \[Mp=\left( \frac{m}{V} \right)\frac{\pi }{RT}\]
2938.

At constant temperature, the osmotic pressure of a solution [CPMT 1986]

A.                 Directly proportional to the concentration
B.                 Inversely proportional to the concentration
C.                 Directly proportional to the square of the concentration
D.                 Directly proportional to the square root of the concentration
Answer» B.                 Inversely proportional to the concentration
2939.

If a \[0.1M\] solution of glucose (mol. wt. 180) and \[0.1\,\text{molar}\] solution of urea (mol. wt. 60) are placed on the two sides of a semipermeable membrane to equal heights, then it will be correct to say     [CBSE PMT 1992]

A.                 There will be no net movement across the membrane
B.                 Glucose will flow across the membrane into urea solution
C.                 Urea will flow across the membrane into glucose solution
D.                 Water will flow from urea solution into glucose solution
Answer» B.                 Glucose will flow across the membrane into urea solution
2940.

Osmotic pressure of a urea solution at \[{{10}^{o}}C\] is \[500\,\,mm.\] Osmotic pressure of the solution become 105.3 mm. When it is diluted and temperature raised to \[{{25}^{o}}C.\] The extent of dilution is                                          [MP PET 2004]

A.                 6 Times
B.                 5 Times
C.                 7 Times 
D.                 4 Times
Answer» C.                 7 Times 
2941.

Two solutions of \[KN{{O}_{3}}\] and \[C{{H}_{3}}COOH\] are prepared separately. Molarity of both is \[0.1\,M\] and osmotic pressures are \[{{P}_{1}}\] and \[{{P}_{2}}\] respectively. The correct relationship between the osmotic pressures is                [CPMT 1983, 84; Pb CET 2004]

A.                 \[{{P}_{2}}>{{P}_{1}}\]  
B.                 \[{{P}_{1}}={{P}_{2}}\]
C.             \[{{P}_{1}}>{{P}_{2}}\]                
D.                 \[\frac{{{P}_{1}}}{{{P}_{1}}+{{P}_{2}}}=\frac{{{P}_{2}}}{{{P}_{1}}+{{P}_{2}}}\]
Answer» D.                 \[\frac{{{P}_{1}}}{{{P}_{1}}+{{P}_{2}}}=\frac{{{P}_{2}}}{{{P}_{1}}+{{P}_{2}}}\]
2942.

Which of the following molecules would diffuse through a cell membrane                                   [NCERT 1978]

A.                 Fructose
B.                 Glycogen
C.                 Haemoglobin       
D.                 Catalase
Answer» B.                 Glycogen
2943.

The osmotic pressure in atmospheres of 10% solution of canesugar at \[{{69}^{o}}C\] is      [AFMC 1991]

A.                 724        
B.                 824
C.                 8.21       
D.                 7.21
Answer» D.                 7.21
2944.

The osmotic pressure of a dilute solution is directly proportional to the                                        [MP PMT 1987]

A.                 Diffusion rate of the solute
B.                 Ionic concentration
C.                 Elevation of B.P.
D.                 Flow of solvent from a concentrated to a dilute solution
Answer» C.                 Elevation of B.P.
2945.

The osmotic pressure of a decinormal solution of \[BaC{{l}_{2}}\] in water is

A.                 Inversely proportional to its celsius temperature
B.                 Inversely proportional to its absolute temperature
C.                 Directly proportional to its celsius temperature
D.                 Directly proportional to its absolute temperature
Answer» E.
2946.

At the same temperature, following solution will be isotonic [MP PMT 1985]

A.                 3.24 gm of sucrose per litre of water and 0.18 gm glucose per litre of water
B.                 3.42 gm of sucrose per litre and 0.18 gm glucose in 0.1 litre water
C.                 3.24 gm of sucrose per litre of water and 0.585 gm of sodium chloride per litre of water
D.                 3.42 gm of sucrose per litre of water and 1.17 gm of sodium chloride per litre of water
Answer» C.                 3.24 gm of sucrose per litre of water and 0.585 gm of sodium chloride per litre of water
2947.

Osmotic pressure of a solution containing 0.1 mole of solute per litre at \[273K\] is (in atm)      [CPMT 1988]

A.                 \[\frac{0.1}{1}\times 0.08205\times 273\]       
B.                 \[0.1\times 1\times 0.08205\times 273\]
C.                 \[\frac{1}{0.1}\times 0.08205\times 273\]       
D.                 \[\frac{0.1}{1}\times \frac{273}{0.08205}\]
Answer» B.                 \[0.1\times 1\times 0.08205\times 273\]
2948.

The molecular weight of \[NaCl\] determined by osmotic pressure method will be

A.                 Same as theoritical value
B.                 Higher than theoritical value
C.                 Lower than theoritical value
D.                 None of these
Answer» D.                 None of these
2949.

Which one of the following would lose weight on exposure to atmosphere                                 [NCERT 1975]

A.                 Concentrated \[{{H}_{2}}S{{O}_{4}}\]
B.                 Solid \[NaOH\]
C.                 A saturated solution of \[C{{O}_{2}}\]
D.                 Anhydrous sodium carbonate
Answer» D.                 Anhydrous sodium carbonate
2950.

Solutions having the same osmotic pressure under a given set of conditions are known as [BHU 1979; EAMCET 1979; CPMT 1990; MP PMT 1999; AFMC 1999, 2001]

A.                 Hypertonic            
B.                 Hypotonic
C.                 Normal  
D.                 Isotonic
Answer» E.