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This section includes 11242 Mcqs, each offering curated multiple-choice questions to sharpen your Joint Entrance Exam - Main (JEE Main) knowledge and support exam preparation. Choose a topic below to get started.
| 1701. |
Aromatic aldehydes undergo disproportionation in presence of sodium or potassium hydroxide to give corresponding alcohol and acid. The reaction is known as [MNR 1987] |
| A. | Wurtz's reaction |
| B. | Cannizzaro reaction |
| C. | Friedel-Craft's reaction |
| D. | Claisen reaction |
| Answer» C. Friedel-Craft's reaction | |
| 1702. |
\[3C{{H}_{3}}COC{{H}_{3}}\xrightarrow{HCl}{{(C{{H}_{3}})}_{2}}C=CH-CO-CH=C{{(C{{H}_{3}})}_{2}}\] This polymer is obtained when acetone is saturated with hydrogen chloride gas, B can be [CBSE PMT 1989] |
| A. | Phorone |
| B. | Formose |
| C. | Diacetone alcohol |
| D. | Mesityl oxide |
| Answer» B. Formose | |
| 1703. |
Aldol condensation of acetaldehyde involves the formation of which of the following intermediate [Pb. CET 1986] |
| A. | Acetate ion |
| B. | A carbanion |
| C. | A carbonium ion |
| D. | A free radical |
| Answer» C. A carbonium ion | |
| 1704. |
Treatment of propionaldehyde with dilute NaOH solution gives [MNR 1992] |
| A. | \[C{{H}_{3}}C{{H}_{2}}COOC{{H}_{2}}C{{H}_{2}}C{{H}_{3}}\] |
| B. | \[C{{H}_{3}}C{{H}_{2}}CHOHCH(C{{H}_{3}})CHO\] |
| C. | \[C{{H}_{3}}C{{H}_{2}}CHOHC{{H}_{2}}C{{H}_{2}}CHO\] |
| D. | \[C{{H}_{3}}C{{H}_{2}}COC{{H}_{2}}C{{H}_{2}}CHO\] |
| Answer» D. \[C{{H}_{3}}C{{H}_{2}}COC{{H}_{2}}C{{H}_{2}}CHO\] | |
| 1705. |
Acetaldehyde reacts with \[{{C}_{2}}{{H}_{5}}MgCl\] the final product is [Pb. CET 1985] |
| A. | An aldehyde |
| B. | A ketone |
| C. | A primary alcohol |
| D. | A secondary alcohol |
| Answer» E. | |
| 1706. |
Which of the following reagent reacts differently with \[HCHO,\,C{{H}_{3}}CHO\] and \[C{{H}_{3}}COC{{H}_{3}}\] [MP PET 1999] |
| A. | HCN |
| B. | \[N{{H}_{2}}N{{H}_{2}}\] |
| C. | \[N{{H}_{2}}OH\] |
| D. | \[N{{H}_{3}}\] |
| Answer» E. | |
| 1707. |
If formaldehyde and KOH are heated, then we get [MP PET 1999; KCET 2000] |
| A. | Acetylene |
| B. | Methane |
| C. | Methyl alcohol |
| D. | Ethyl formate |
| Answer» D. Ethyl formate | |
| 1708. |
The light yellow compound produced when acetone reacts with iodine and alkali, is [MP PMT 1992; EAMCET 1993] |
| A. | \[C{{H}_{3}}.CO.C{{H}_{2}}I\] |
| B. | \[C{{H}_{3}}I\] |
| C. | \[CH{{I}_{3}}\] |
| D. | None of these |
| Answer» D. None of these | |
| 1709. |
A and B in the following reactions are \[R-\underset{\underset{O}{\mathop{||}}\,}{\mathop{C}}\,-{R}'\underset{KCN}{\mathop{\xrightarrow{HCN}}}\,A\xrightarrow{B}\begin{matrix} R \\ R \\ \end{matrix}\,>C |
| A. | \[A=RR'C<\begin{matrix} CN \\ OH \\ \end{matrix},B-LiAl{{H}_{4}}\] |
| B. | \[A=RR'C<\begin{array}{*{35}{l}} OH \\ COOH \\ \end{array},\,\,B-N{{H}_{3}}\] |
| C. | \[A=RR'C<\begin{matrix} CN \\ OH \\ \end{matrix}\ ,B={{H}_{3}}{{O}^{\oplus }}\] |
| D. | \[A=RR'C{{H}_{2}}CN,B=NaOH\] |
| Answer» B. \[A=RR'C<\begin{array}{*{35}{l}} OH \\ COOH \\ \end{array},\,\,B-N{{H}_{3}}\] | |
| 1710. |
Haloform test is given by the following substance [EAMCET 1988] |
| A. | HCHO |
| B. | \[{{(C{{H}_{3}})}_{2}}CO\] |
| C. | \[C{{H}_{3}}OC{{H}_{3}}\] |
| D. | \[C{{H}_{3}}C{{H}_{2}}Cl\] |
| Answer» C. \[C{{H}_{3}}OC{{H}_{3}}\] | |
| 1711. |
Which of the following does not give iodoform test [AIIMS 1992; MP PMT 1990, 96; CET Pune 1998 DPMT 1981; CPMT 1976] |
| A. | \[C{{H}_{3}}C{{H}_{2}}OH\] |
| B. | \[C{{H}_{3}}OH\] |
| C. | \[C{{H}_{3}}CHO\] |
| D. | \[PhCOC{{H}_{3}}\] |
| Answer» C. \[C{{H}_{3}}CHO\] | |
| 1712. |
Which of the following will not give the iodoform test [MNR 1994] |
| A. | Acetophenone |
| B. | Ethanal |
| C. | Benzophenone |
| D. | Ethanol |
| Answer» D. Ethanol | |
| 1713. |
Benzyl alcohol and sodium benzoate is obtained by the action of sodium hydroxide on benzaldehyde. This reaction is known as [KCET 2005] |
| A. | Perkin's reaction |
| B. | Cannizzaro's reaction |
| C. | Sandmeyer's reaction |
| D. | Claisen condensation |
| Answer» C. Sandmeyer's reaction | |
| 1714. |
To distinguish between formaldehyde and acetaldehyde, we require [Orissa PMT 1987] |
| A. | Tollen's reagent |
| B. | Fehling's solution |
| C. | Schiff's reagent |
| D. | Caustic soda solution |
| Answer» E. | |
| 1715. |
The following reagent converts \[{{C}_{6}}{{H}_{5}}COCHO\] to \[{{C}_{6}}{{H}_{5}}CHOHCOONa\] [Roorkee Qualifying 1998] |
| A. | Aq. NaOH |
| B. | Acidic \[N{{a}_{2}}{{S}_{2}}{{O}_{3}}\] |
| C. | \[N{{a}_{2}}Cr{{O}_{4}}/{{H}_{2}}S{{O}_{4}}\] |
| D. | \[NaN{{O}_{2}}/HCl\] |
| Answer» B. Acidic \[N{{a}_{2}}{{S}_{2}}{{O}_{3}}\] | |
| 1716. |
Acetaldehyde cannot show [AIIMS 1997] |
| A. | Iodoform test |
| B. | Lucas test |
| C. | Benedict's test |
| D. | Tollen's test |
| Answer» C. Benedict's test | |
| 1717. |
Which of the following oxidation reactions can be carried out with chromic acid in aqueous acetone at \[5-{{10}^{o}}C\] [Roorkee Qualifying 1998] |
| A. | \[C{{H}_{3}}{{(C{{H}_{2}})}_{3}}C\equiv C-\underset{\underset{OH}{\mathop{|}}\,}{\mathop{CH}}\,-C{{H}_{3}}\to \]\[C{{H}_{3}}{{(C{{H}_{2}})}_{3}}C\equiv \overset{\begin{smallmatrix} O \\ |\,\,|\end{smallmatrix}}{\mathop{C}}\,-C-C{{H}_{3}}\] |
| B. | \[C{{H}_{3}}{{(C{{H}_{2}})}_{3}}CH=CH-C{{H}_{2}}OH\to \]\[C{{H}_{3}}{{(C{{H}_{2}})}_{3}}CH=CH-CHO\] |
| C. | \[{{C}_{6}}{{H}_{5}}C{{H}_{3}}\to {{C}_{6}}{{H}_{5}}COOH\] |
| D. | \[C{{H}_{3}}{{(C{{H}_{2}})}_{3}}C{{H}_{2}}OH\to C{{H}_{3}}{{(C{{H}_{2}})}_{3}}CHO\] |
| Answer» B. \[C{{H}_{3}}{{(C{{H}_{2}})}_{3}}CH=CH-C{{H}_{2}}OH\to \]\[C{{H}_{3}}{{(C{{H}_{2}})}_{3}}CH=CH-CHO\] | |
| 1718. |
When m-chlorobenzaldehyde is treated with 50% KOH solution, the product (s) obtained is (are) [CBSE PMT 2003] |
| A. | |
| B. | |
| C. | |
| D. | |
| Answer» D. | |
| 1719. |
\[{{C}_{2}}{{H}_{5}}CHO\] and \[{{(C{{H}_{3}})}_{2}}CO\] can be distinguished by testing with [EAMCET 1998; CPMT 1994, 97; MP PET 1995; MP PMT 1996; RPMT 1997, 99] |
| A. | Phenyl hydrazine |
| B. | Hydroxylamine |
| C. | Fehling solution |
| D. | Sodium bisulphite |
| Answer» D. Sodium bisulphite | |
| 1720. |
Which one does not give cannizzaro's reaction [Kerala CET 2005] |
| A. | Benzaldehyde |
| B. | 2-methyl propanal |
| C. | p-methoxy benzaldehyde |
| D. | 2,2 dimethyl propanal |
| E. | Formaldehyde |
| Answer» C. p-methoxy benzaldehyde | |
| 1721. |
\[C{{H}_{3}}-CHO+HCN\to A\]; Compound \[A\] on hydrolysis gives [Kerala CET 2005] |
| A. | \[C{{H}_{3}}-C{{H}_{2}}-COOH\] |
| B. | \[C{{H}_{3}}-C{{H}_{2}}-C{{H}_{2}}-N{{H}_{2}}\] |
| C. | \[C{{H}_{3}}-CO-COOH\] |
| D. | \[C{{H}_{3}}CO-CH=NOH\] |
| E. | \[C{{H}_{3}}-\underset{OH}{\mathop{\underset{|\,\,\,\,\,\,}{\mathop{CH}}\,}}\,-COOH\] |
| Answer» F. | |
| 1722. |
A compound \[A\to {{C}_{5}}{{H}_{10}}C{{l}_{2}}\] on hydrolysis gives \[{{C}_{5}}{{H}_{10}}O\] which reacts with \[N{{H}_{2}}OH\], forms iodoform but does not give fehling test. \[A\] is [DPMT 2005] |
| A. | \[C{{H}_{3}}\underset{Cl}{\mathop{\underset{|}{\mathop{\overset{Cl}{\mathop{\overset{|}{\mathop{-C-}}\,}}\,}}\,}}\,C{{H}_{2}}-C{{H}_{2}}-C{{H}_{3}}\] |
| B. | \[C{{H}_{3}}C{{H}_{2}}\underset{Cl}{\mathop{\underset{|}{\mathop{\overset{Cl}{\mathop{\overset{|}{\mathop{-C-}}\,}}\,}}\,}}\,C{{H}_{2}}C{{H}_{3}}\] |
| C. | \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}C{{H}_{2}}\underset{Cl\,\,}{\mathop{\underset{|\,\,\,\,\,\,}{\mathop{\overset{Cl\,}{\mathop{\overset{|\,\,\,\,\,}{\mathop{CH}}\,}}\,}}\,}}\,\] |
| D. | \[C{{H}_{3}}\overset{Cl}{\mathop{\overset{|}{\mathop{-CH}}\,}}\,\overset{Cl}{\mathop{\overset{|}{\mathop{-CH}}\,}}\,-C{{H}_{2}}-C{{H}_{3}}\] |
| Answer» B. \[C{{H}_{3}}C{{H}_{2}}\underset{Cl}{\mathop{\underset{|}{\mathop{\overset{Cl}{\mathop{\overset{|}{\mathop{-C-}}\,}}\,}}\,}}\,C{{H}_{2}}C{{H}_{3}}\] | |
| 1723. |
Which of the following will form two isomers with semi carbazide [Orissa JEE 2005] |
| A. | Benzaldehyde |
| B. | Acetone |
| C. | Benzoquinone |
| D. | Benzophenone |
| Answer» B. Acetone | |
| 1724. |
Ketones react with Mg-Hg over water gives [AFMC 2005] |
| A. | Pinacolone |
| B. | Pinacols |
| C. | Alcohols |
| D. | None of these |
| Answer» C. Alcohols | |
| 1725. |
How will you convert butan-2-one to propanoic acid? [IIT 2005] |
| A. | Tollen-s reagent |
| B. | Fehling's solution |
| C. | \[NaOH/{{I}_{2}}/{{H}^{+}}\] |
| D. | \[NaOH/NaI/{{H}^{+}}\] |
| Answer» D. \[NaOH/NaI/{{H}^{+}}\] | |
| 1726. |
Which of the following does not give Fehling solution test? [BCECE 2005] |
| A. | Acetone |
| B. | Propanal |
| C. | Ethanal |
| D. | Butanal |
| Answer» B. Propanal | |
| 1727. |
Methyl ketone group is identified by [BCECE 2005] |
| A. | Iodoform test |
| B. | Fehling solution |
| C. | Tollen?s reagent |
| D. | Shiff?s reagent |
| Answer» B. Fehling solution | |
| 1728. |
Acetaldehyde when treated with dilute NaOH gives [EAMCET 1998] |
| A. | \[C{{H}_{3}}C{{H}_{2}}OH\] |
| B. | \[C{{H}_{3}}COOH\] |
| C. | \[C{{H}_{3}}-\underset{\underset{OH}{\mathop{|}}\,}{\mathop{CH}}\,-C{{H}_{2}}-CHO\] |
| D. | \[C{{H}_{3}}-C{{H}_{3}}\] |
| Answer» D. \[C{{H}_{3}}-C{{H}_{3}}\] | |
| 1729. |
Hexamethylene tetramine is used as [MP PMT 1979, 84] |
| A. | Analgesic |
| B. | Antipyretic |
| C. | Urinary antiseptic |
| D. | All of these |
| Answer» D. All of these | |
| 1730. |
Paraldehyde is used as a [CBSE PMT 1989] |
| A. | Medicine |
| B. | Poison |
| C. | Polymer |
| D. | Dye |
| Answer» B. Poison | |
| 1731. |
Paraldehyde is [CPMT 1985; MP PET 1992, 96; RPMT 2000] |
| A. | A trimer of formaldehyde |
| B. | A trimer of acetaldehyde |
| C. | A hexamer of formaldehyde |
| D. | A hexamer of acetaldehyde |
| Answer» E. | |
| 1732. |
The most appropriate reagent to distinguish between acetaldehyde and formaldehyde is [UPSEAT 2004] |
| A. | Fehling's solution |
| B. | Tollen's reagent |
| C. | Schiff's reagent |
| D. | Iodine in presence of base |
| Answer» E. | |
| 1733. |
The pair of compounds in which both the compounds give positive test with Tollen's reagent is [IIT-JEE (Screening) 2004] |
| A. | Glucose and Sucrose |
| B. | Fructose and Sucrose |
| C. | Acetophenone and Hexanal |
| D. | Glucose and Fructose |
| Answer» E. | |
| 1734. |
Which responds to +ve iodoform test? [Orissa JEE 2004] |
| A. | Butanol |
| B. | Butan-1-al |
| C. | Butanol-2 |
| D. | 3-pentanone |
| Answer» D. 3-pentanone | |
| 1735. |
A compound has a vapour density of 29. On warming an aqueous solution of alkali, it gives a yellow precipitate. The compound is [DPMT 2004] |
| A. | \[C{{H}_{3}}C{{H}_{2}}CHO\] |
| B. | \[C{{H}_{3}}CHOHC{{H}_{3}}\] |
| C. | \[C{{H}_{3}}COC{{H}_{3}}\] |
| D. | \[C{{H}_{3}}C{{H}_{2}}COOH\] |
| Answer» B. \[C{{H}_{3}}CHOHC{{H}_{3}}\] | |
| 1736. |
Wolf kishner reduction, reduces [Pb. CET 2003] |
| A. | \[-COOH\] group |
| B. | \[-C\equiv C-\] group |
| C. | \[-CHO\] group |
| D. | \[-O-\]group |
| Answer» D. \[-O-\]group | |
| 1737. |
Fehling solution is [Pb. CET 2003] |
| A. | \[CuS{{O}_{4}}\]+ lime |
| B. | \[CuS{{O}_{4}}+NaOH(aq)\] |
| C. | \[CuS{{O}_{4}}+N{{a}_{2}}C{{O}_{3}}\] |
| D. | None of these |
| Answer» E. | |
| 1738. |
In Wolf-Kishner reduction, the carbonyl group of aldehydes and ketones is converted into [Pb. CET 2000] |
| A. | \[>C{{H}_{2}}\] group |
| B. | \[-C{{H}_{3}}\] group |
| C. | \[-C{{H}_{2}}OH\]group |
| D. | \[>CHOH\] group |
| Answer» B. \[-C{{H}_{3}}\] group | |
| 1739. |
The order of susceptibility of nucleophilic attack on aldehydes follows the order [DCE 2002] |
| A. | \[1{}^\circ >3{}^\circ >2{}^\circ ~\] |
| B. | \[1{}^\circ >2{}^\circ >3{}^\circ ~\] |
| C. | \[3{}^\circ >2{}^\circ >1{}^\circ ~\] |
| D. | \[2{}^\circ >3{}^\circ >1{}^\circ ~\] |
| Answer» C. \[3{}^\circ >2{}^\circ >1{}^\circ ~\] | |
| 1740. |
Acetaldehyde and Acetone can be distinguished by [DCE 2003] |
| A. | Iododorm test |
| B. | Nitroprusside test |
| C. | Fehling's solution test |
| D. | DNP test |
| Answer» D. DNP test | |
| 1741. |
The aldehyde which react with NaOH to produce an alcohol and sodium salt is [Pb. PMT 2004] |
| A. | HCHO |
| B. | \[C{{H}_{3}}CHO\] |
| C. | \[C{{H}_{3}}C{{H}_{2}}CHO\] |
| D. | \[C{{H}_{3}}C{{H}_{2}}C{{H}_{2}}CHO\] |
| Answer» B. \[C{{H}_{3}}CHO\] | |
| 1742. |
\[A\xrightarrow{{}}{{(C{{H}_{3}})}_{2}}C=CHCOC{{H}_{3}}A\] is [MHCET 2004] |
| A. | Acetone |
| B. | Acetaldehyde |
| C. | Propionaldehyde |
| D. | Formaldehyde |
| Answer» B. Acetaldehyde | |
| 1743. |
Which of the following aldehydes give red precipitate with Fehling solution ? [MHCET 2004] |
| A. | Benzaldehyde |
| B. | Salicylaldehyde |
| C. | Acetaldehyde |
| D. | None of these |
| Answer» D. None of these | |
| 1744. |
Which of the following organic compounds exhibits positive Fehling test as well as iodoform test [MP PET 1994; KCET 2001] |
| A. | Methanal |
| B. | Ethanol |
| C. | Propanone |
| D. | Ethanal |
| Answer» E. | |
| 1745. |
Which of the following is used to detect aldehydes [MHCET 2004] |
| A. | Million's test |
| B. | Tollen's reagent |
| C. | Neutral ferric chloride solution |
| D. | Molisch's test |
| Answer» C. Neutral ferric chloride solution | |
| 1746. |
Cyanohydrin of which of the following forms lactic acid [MHCET 2003] |
| A. | \[C{{H}_{3}}C{{H}_{2}}CHO\] |
| B. | \[C{{H}_{3}}CHO\] |
| C. | \[HCHO\] |
| D. | \[C{{H}_{3}}COC{{H}_{3}}\] |
| Answer» C. \[HCHO\] | |
| 1747. |
Acetone reacts with iodine to form iodoform in the presence of [BHU 2004; CPMT 2004] |
| A. | \[CaC{{O}_{3}}\] |
| B. | \[NaOH\] |
| C. | \[KOH\] |
| D. | \[MgC{{O}_{3}}\] |
| Answer» C. \[KOH\] | |
| 1748. |
Aldehydes and ketones can be reduced to corresponding hydrocarbons by [Kerala PMT 2004] |
| A. | Refluxing with water |
| B. | Refluxing with strong acids |
| C. | Refluxing with soda amalgam and water |
| D. | Refluxing with zinc amalgam and concentrated HCl |
| E. | Passing the vapour under heated \[Pb{{O}_{2}}\] |
| Answer» E. Passing the vapour under heated \[Pb{{O}_{2}}\] | |
| 1749. |
Three molecules of acetone in the presence of dry HCl form [MP PET 2004] |
| A. | Mesitylene |
| B. | Phorone |
| C. | Glyoxal |
| D. | Mesityl oxide |
| Answer» C. Glyoxal | |
| 1750. |
Which one of the following is reduced with zinc and hydrochloric acid to give the corresponding hydrocarbon [AIEEE 2004] |
| A. | Acetamide |
| B. | Acetic acid |
| C. | Ethyl acetate |
| D. | Butan?2?one |
| Answer» E. | |