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This section includes 11242 Mcqs, each offering curated multiple-choice questions to sharpen your Joint Entrance Exam - Main (JEE Main) knowledge and support exam preparation. Choose a topic below to get started.
| 5101. |
The structure of \[{{H}_{2}}{{O}_{2}}\] is [CBSE PMT 1999; AFMC 2003] |
| A. | Planar |
| B. | Non-planar |
| C. | Spherical |
| D. | Linear |
| Answer» C. Spherical | |
| 5102. |
The hybrid orbitals used by central atoms in \[BeC{{l}_{2}},\,\,BC{{l}_{3}}\] and \[CC{{l}_{4}}\] molecules are respectively [MP PMT 1999] |
| A. | \[s{{p}^{2}},\,\,s{{p}^{3}}\] and \[sp\] |
| B. | \[s{{p}^{{}}},\,\,s{{p}^{2}}\] and \[s{{p}^{3}}\] |
| C. | \[s{{p}^{2}},\,\,s{{p}^{3}}\] and \[s{{p}^{2}}\] |
| D. | \[s{{p}^{2}},\,\,sp\] and \[s{{p}^{3}}\] |
| Answer» C. \[s{{p}^{2}},\,\,s{{p}^{3}}\] and \[s{{p}^{2}}\] | |
| 5103. |
\[s{{p}^{3}}\] hybridization leads to which shape of the molecule [MP PET/PMT 1998] |
| A. | Tetrahedron |
| B. | Octahedron |
| C. | Linear |
| D. | Plane triangle |
| Answer» B. Octahedron | |
| 5104. |
As the \[p-\]character increases, the bond angle in hybrid orbitals formed by \[s\] and atomic orbitals [MP PMT 1997] |
| A. | Decreases |
| B. | Increases |
| C. | Doubles |
| D. | Remains unchanged |
| Answer» B. Increases | |
| 5105. |
Out of the following hybrid orbitals, the one which forms the bond at angle\[{{120}^{o}}\], is [MP PMT 1997] |
| A. | \[{{d}^{2}}s{{p}^{3}}\] |
| B. | \[s{{p}^{3}}\] |
| C. | \[s{{p}^{2}}\] |
| D. | \[sp\] |
| Answer» D. \[sp\] | |
| 5106. |
In benzene molecule all \[C-C\] bond lengths are equal because |
| A. | All carbon atoms are equivalent |
| B. | All carbon atoms are \[s{{p}^{2}}\] hybridised |
| C. | All \[C-C\] bonds in benzene, have same order |
| D. | All \[C-C\] bonds are single covalent bond |
| Answer» D. All \[C-C\] bonds are single covalent bond | |
| 5107. |
The shapes of \[BC{{l}_{3}},\,\,PC{{l}_{3}}\]and \[IC{{l}_{3}}\]molecules are all |
| A. | Triangular |
| B. | Pyramidal |
| C. | \[T-\]shaped |
| D. | All above are incorrect |
| Answer» B. Pyramidal | |
| 5108. |
The geometry of sulphur trioxide molecule is |
| A. | Tetrahedral |
| B. | Trigonal planar |
| C. | Pyramidal |
| D. | Square planar |
| Answer» C. Pyramidal | |
| 5109. |
The \[PC{{l}_{5}}\] molecule is a result of the hybridisation of [MP PET 1995; DCE 2000; MP PMT 2002] |
| A. | \[s{{p}^{2}}{{d}^{2}}\] |
| B. | \[s{{p}^{3}}d\] |
| C. | \[sp{{d}^{3}}\] |
| D. | \[s{{p}^{2}}{{d}^{3}}\] |
| Answer» C. \[sp{{d}^{3}}\] | |
| 5110. |
Which of the following hybridisation has maximum s-characters [MP PET 1995] |
| A. | \[s{{p}^{3}}\] |
| B. | \[s{{p}^{2}}\] |
| C. | \[sp\] |
| D. | None of these |
| Answer» D. None of these | |
| 5111. |
The structure of \[P{{F}_{5}}\]molecule is [AFMC 1995; JIPMER 2001] |
| A. | Tetrahedral |
| B. | Trigonal bipyramidal |
| C. | Square planar |
| D. | Pentagonal bipyramidal |
| Answer» C. Square planar | |
| 5112. |
The correct order of the \[O-O\] bond length in \[{{O}_{2}},\,\,{{H}_{2}}{{O}_{2}}\] and \[{{O}_{3}}\] is [CBSE PMT 1995] |
| A. | \[{{O}_{2}}>{{O}_{3}}>{{H}_{2}}{{O}_{2}}\] |
| B. | \[{{O}_{3}}>{{H}_{2}}{{O}_{2}}>{{O}_{2}}\] |
| C. | \[{{H}_{2}}{{O}_{2}}>{{O}_{3}}>{{O}_{2}}\] |
| D. | \[{{O}_{2}}>{{H}_{2}}{{O}_{2}}>{{O}_{3}}\] |
| Answer» D. \[{{O}_{2}}>{{H}_{2}}{{O}_{2}}>{{O}_{3}}\] | |
| 5113. |
A \[s{{p}^{3}}\] hybridized orbital contains [DPMT 1984; BHU 1985; CPMT 1976] |
| A. | \[\frac{1}{4}s-\]character |
| B. | \[\frac{1}{2}s-\]character |
| C. | \[\frac{2}{3}s-\]character |
| D. | \[\frac{3}{4}s-\]character |
| Answer» B. \[\frac{1}{2}s-\]character | |
| 5114. |
In the compound \[C{{H}_{3}}OCl,\] which type of orbitals have been used by the circled carbon in bond formation [MP PET 1994] |
| A. | \[s{{p}^{3}}valuva\] |
| B. | \[s{{p}^{2}}\] |
| C. | \[sp\] |
| D. | p |
| Answer» C. \[sp\] | |
| 5115. |
The two types of bonds present in \[{{B}_{2}}{{H}_{6}}\] are covalent and [IIT 1994] |
| A. | Three centre bond |
| B. | Hydrogen bond |
| C. | Two centre bond |
| D. | None of the above |
| Answer» B. Hydrogen bond | |
| 5116. |
s-character in \[sp\]hybridised orbitals are |
| A. | \[\frac{1}{3}\] |
| B. | \[\frac{1}{2}\] |
| C. | \[\frac{1}{4}\] |
| D. | \[\frac{2}{3}\] |
| Answer» C. \[\frac{1}{4}\] | |
| 5117. |
The number of shared pairs of electrons in propane is [BHU 1981] |
| A. | 2 |
| B. | 4 |
| C. | 6 |
| D. | 10 |
| Answer» E. | |
| 5118. |
In diborane, the \[H-B-H\]bond angle is \[{{120}^{o}}\]. The hybridization of boron is likely to be [BHU 1981; CBSE PMT 1999] |
| A. | \[sp\] |
| B. | \[s{{p}^{2}}\] |
| C. | \[s{{p}^{3}}\] |
| D. | \[ds{{p}^{2}}\] |
| Answer» D. \[ds{{p}^{2}}\] | |
| 5119. |
The compound in which \[{{C}^{*}}\] uses \[s{{p}^{3}}\]hybrids for bond formation is [IIT 1989] |
| A. | \[H\overset{+}{\mathop{C}}\,OOH\] |
| B. | \[{{(N{{H}_{2}})}_{2}}\overset{+}{\mathop{C}}\,O\] |
| C. | \[{{(N{{H}_{3}})}_{3}}\overset{+}{\mathop{C}}\,OH\]\[HgC{{l}_{2}}\] |
| D. | \[C{{H}_{3}}\overset{+}{\mathop{C}}\,HO\] |
| Answer» D. \[C{{H}_{3}}\overset{+}{\mathop{C}}\,HO\] | |
| 5120. |
The hybridization of carbon atoms in \[C-C\] single bond of \[HC\equiv C-CH=C{{H}_{2}}\] is [IIT 1991; MP PET 1995] |
| A. | \[s{{p}^{3}}-s{{p}^{3}}\] |
| B. | \[s{{p}^{2}}-s{{p}^{3}}\] |
| C. | \[sp-s{{p}^{2}}\] |
| D. | \[s{{p}^{3}}-sp\] |
| Answer» D. \[s{{p}^{3}}-sp\] | |
| 5121. |
In \[\left[ Cu\,{{\left( N{{H}_{3}} \right)}_{4}} \right]\,S{{O}_{4}},\,\,;\,Cu\] has following hybridization [AIIMS 1988; UPSEAT 2001] |
| A. | \[ds{{p}^{2}}\] |
| B. | \[s{{p}^{3}}\] |
| C. | \[s{{p}^{2}}\] |
| D. | \[s{{p}^{3}}{{d}^{2}}\] |
| Answer» B. \[s{{p}^{3}}\] | |
| 5122. |
Carbon atoms in diamond are bonded to each other in a configuration [CPMT 1981] |
| A. | Tetrahedral |
| B. | Planar |
| C. | Linear |
| D. | Octahedral |
| Answer» B. Planar | |
| 5123. |
Which of the following molecules has trigonal planer geometry [CBSE PMT 2005] |
| A. | \[I{{F}_{3}}\] |
| B. | \[PC{{l}_{3}}\] |
| C. | \[N{{H}_{3}}\] |
| D. | \[B{{F}_{3}}\] |
| Answer» E. | |
| 5124. |
The species in which the central atom uses \[s{{p}^{2}}\]hybrid orbitals in its bonding is [IIT 1988] |
| A. | \[P{{H}_{3}}\] |
| B. | \[N{{H}_{3}}\] |
| C. | \[{{H}_{3}}{{C}^{+}}\] |
| D. | \[Sb{{H}_{3}}\] |
| Answer» D. \[Sb{{H}_{3}}\] | |
| 5125. |
In methane the bond angle is [AMU 1983] |
| A. | \[{{180}^{o}}\] |
| B. | \[{{90}^{o}}\] |
| C. | \[{{120}^{o}}\] |
| D. | \[{{109}^{o}}\] |
| Answer» E. | |
| 5126. |
Among the following compounds which is planar in shape [AMU 1992] |
| A. | Methane |
| B. | Acetylene |
| C. | Benzene |
| D. | Isobutene |
| Answer» D. Isobutene | |
| 5127. |
The two carbon atoms in acetylene are [AMU 1984; MADT Bihar 1982] |
| A. | \[s{{p}^{3}}\]hybridized |
| B. | \[s{{p}^{2}}\]hybridized |
| C. | \[sp\]hybridized |
| D. | Unhybridized |
| Answer» D. Unhybridized | |
| 5128. |
Acetate ion contains [AMU 1983] |
| A. | One \[C,\,\,O\]single bond and one \[C,\,\,O\] double bond |
| B. | Two \[C,\,\,O\] single bonds |
| C. | Two \[C,\,\,O\]double bonds |
| D. | None of the above |
| Answer» B. Two \[C,\,\,O\] single bonds | |
| 5129. |
The structural formula of a compound is \[C{{H}_{3}}-CH=C=C{{H}_{2}}.\] The type of hybridization at the four carbons from left to right are [CBSE PMT 1989] |
| A. | \[s{{p}^{2}},\,\,sp,\,\,s{{p}^{2}},\,\,s{{p}^{3}}\] |
| B. | \[s{{p}^{2}},\,\,s{{p}^{3}},\,\,s{{p}^{2}},\,\,sp\] |
| C. | \[s{{p}^{3}},\,\,s{{p}^{2}},\,\,sp,\,\,s{{p}^{2}}\] |
| D. | \[s{{p}^{3}},\,\,s{{p}^{2}},\,\,s{{p}^{2}},\,\,s{{p}^{2}}\] |
| Answer» D. \[s{{p}^{3}},\,\,s{{p}^{2}},\,\,s{{p}^{2}},\,\,s{{p}^{2}}\] | |
| 5130. |
Number of shared electrons in between carbon-carbon atoms in ethylene molecule is [MADT Bihar 1983] |
| A. | 2 |
| B. | 4 |
| C. | 6 |
| D. | 3 |
| Answer» C. 6 | |
| 5131. |
In ethene, the bond angle(s) is/are [CPMT 1976; AMU 1984; MP PMT 1985] |
| A. | \[{{109}^{o}}28'\] |
| B. | \[{{120}^{o}}\] |
| C. | \[{{180}^{o}}\] |
| D. | Different |
| Answer» C. \[{{180}^{o}}\] | |
| 5132. |
Which molecule is linear [MP PMT 1984; IIT 1982, 88; EAMCET 1993; CBSE PMT 1992; MP PET 1995; RPMT 1997] |
| A. | \[N{{O}_{2}}\] |
| B. | \[Cl{{O}_{2}}\] |
| C. | \[C{{O}_{2}}\] |
| D. | \[{{H}_{2}}S\] |
| Answer» D. \[{{H}_{2}}S\] | |
| 5133. |
Which one of the following compounds has bond angle as nearly \[{{90}^{o}}\] [MP PMT 1985] |
| A. | \[N{{H}_{3}}\] |
| B. | \[{{H}_{2}}S\] |
| C. | \[{{H}_{2}}O\] |
| D. | \[C{{H}_{4}}\] |
| Answer» C. \[{{H}_{2}}O\] | |
| 5134. |
The nature of hybridization in the \[BC{{l}_{3}}\] molecule is [EAMCET 1982] |
| A. | \[sp\] |
| B. | \[s{{p}^{2}}\] |
| C. | \[s{{p}^{3}}\] |
| D. | \[s{{p}^{3}}d\] |
| Answer» D. \[s{{p}^{3}}d\] | |
| 5135. |
When two pairs of electrons are shared, bond is [MNR 1979] |
| A. | Single covalent bond |
| B. | Double covalent bond |
| C. | Dative bond |
| D. | Triple bond |
| Answer» C. Dative bond | |
| 5136. |
The bond angle in carbon tetrachloride is approximately [MNR 1981; MP PMT 1987] |
| A. | \[{{90}^{o}}\] |
| B. | \[{{109}^{o}}\] |
| C. | \[{{120}^{o}}\] |
| D. | \[{{180}^{o}}\] |
| Answer» C. \[{{120}^{o}}\] | |
| 5137. |
In the following molecule, the two carbon atoms marked by asterisk (*) possess the following type of hybridized orbitals \[{{H}_{3}}C-{{C}^{*}}\equiv {{C}^{*}}-C{{H}_{3}}\] [NCERT 1984] |
| A. | \[s{{p}^{3}}\]orbital |
| B. | \[s{{p}^{2}}\]orbital |
| C. | \[sp\]orbital |
| D. | \[s\]orbital |
| Answer» D. \[s\]orbital | |
| 5138. |
The number of unpaired electrons in \[{{O}_{2}}\] molecule is [MNR 1983; Kerala PET 2002] |
| A. | 0 |
| B. | 1 |
| C. | 2 |
| D. | 3 |
| Answer» D. 3 | |
| 5139. |
The compound 1, 2-butadiene has [IIT 1983; MP PMT 1996] |
| A. | Only \[sp\]hybridized carbon atoms |
| B. | Only \[s{{p}^{2}}\]hybridized carbon atoms |
| C. | Both \[sp\]and \[s{{p}^{2}}\]hybridized carbon atoms |
| D. | \[sp,\,\,s{{p}^{2}}\] and \[s{{p}^{3}}\]hybridized carbon atoms |
| Answer» E. | |
| 5140. |
As compared to pure atomic orbitals, hybrid orbitals have |
| A. | Low energy |
| B. | Same energy |
| C. | High energy |
| D. | None of these |
| Answer» B. Same energy | |
| 5141. |
Which species do not have \[s{{p}^{3}}\]hybridization [DPMT 1985] |
| A. | Ammonia |
| B. | Methane |
| C. | Water |
| D. | Carbon dioxide |
| Answer» E. | |
| 5142. |
Experiment shows that \[{{H}_{2}}O\]has a dipole moment while \[C{{O}_{2}}\] has not. Point out the structures which best illustrate these facts [DPMT 1984; NCERT 1983; CPMT 1984] |
| A. | |
| B. | \[O=C=O\,;\,\,\,H-O-H\] |
| C. | |
| D. | \[\underset{\underset{C=O\,;}{\mathop{||\,\,\,\,\,\,\,\,\,\,}}\,}{\mathop{O\,\,\,\,\,\,\,}}\,\,\,\,\underset{\underset{O-H}{\mathop{|\,\,\,\,\,\,\,\,\,\,\,\,\,}}\,}{\mathop{H\,\,\,\,\,\,\,}}\,\] |
| Answer» B. \[O=C=O\,;\,\,\,H-O-H\] | |
| 5143. |
The central atom in a molecule is in \[s{{p}^{2}}\]hybrid state. The shape of molecule will be [MP PMT 1987; CBSE PMT 1989] |
| A. | Pyramidal |
| B. | Tetrahedral |
| C. | Octahedral |
| D. | Trigonal planar |
| Answer» E. | |
| 5144. |
The hybridization of \[Ag\] in the linear complex \[{{\left[ Ag\,{{\left( N{{H}_{3}} \right)}_{2}} \right]}^{+}}\] is [CPMT 1985; BHU 1981] |
| A. | \[ds{{p}^{2}}\] |
| B. | \[sp\] |
| C. | \[s{{p}^{2}}\] |
| D. | \[CC{{l}_{4}}\] |
| Answer» C. \[s{{p}^{2}}\] | |
| 5145. |
Which has the shortest \[C-C\] bond length [NCERT 1982; CPMT 1989] |
| A. | \[{{C}_{2}}{{H}_{5}}OH\] |
| B. | \[{{C}_{2}}{{H}_{6}}\] |
| C. | \[{{C}_{2}}{{H}_{2}}\] |
| D. | \[{{C}_{2}}{{H}_{4}}\] |
| Answer» D. \[{{C}_{2}}{{H}_{4}}\] | |
| 5146. |
In \[HCHO,\,\,'C'\] has hybridization [AIIMS 1987] |
| A. | \[sp\] |
| B. | \[s{{p}^{2}}\] |
| C. | \[s{{p}^{3}}\] |
| D. | All the above |
| Answer» C. \[s{{p}^{3}}\] | |
| 5147. |
Which of the following is the correct electronic formula of chlorine molecule [CPMT 1971] |
| A. | \[:\,\underset{.\,.}{\overset{\,\,\,.\,.}{\mathop{Cl}}}\,\,:\,\underset{.\,.}{\overset{\,\,\,.\,.}{\mathop{Cl}}}\,\,:\] |
| B. | \[:\,\underset{.\,.}{\overset{\,\,\,.\,.}{\mathop{C{{l}^{-}}}}}\,\,:\,\,:\,\,\underset{.\,.}{\overset{\,.\,.}{\mathop{C{{l}^{+}}}}}\,\,:\] |
| C. | \[:\,\underset{{}}{\overset{\,\,\,.\,.}{\mathop{Cl}}}\,\,:\,\underset{{}}{\overset{\,\,\,.\,.}{\mathop{Cl}}}\,\,:\] |
| D. | \[:\,\underset{{}}{\overset{\,\,\,.\,.}{\mathop{Cl}}}\,\,:\,\underset{{}}{\overset{\,\,\,.\,.}{\mathop{\,:\,Cl}}}\,\,:\] |
| Answer» B. \[:\,\underset{.\,.}{\overset{\,\,\,.\,.}{\mathop{C{{l}^{-}}}}}\,\,:\,\,:\,\,\underset{.\,.}{\overset{\,.\,.}{\mathop{C{{l}^{+}}}}}\,\,:\] | |
| 5148. |
Which one amongst the following possesses an \[sp\] hybridized carbon in its structure [CBSE PMT 1989] |
| A. | \[Ca{{I}_{2}}\] |
| B. | \[C.C{{l}_{2}}=C.C{{l}_{2}}\] |
| C. | \[C{{H}_{2}}=C=C{{H}_{2}}\] |
| D. | \[C{{H}_{2}}=CH-CH=C{{H}_{2}}\] |
| Answer» D. \[C{{H}_{2}}=CH-CH=C{{H}_{2}}\] | |
| 5149. |
Shape of methane molecule is [MNR 1983] |
| A. | Tetrahedral |
| B. | Pyramidal |
| C. | Octahedral |
| D. | Square planer |
| Answer» B. Pyramidal | |
| 5150. |
The \[C-H\]bond distance is the longest in [MNR 1990] |
| A. | \[{{C}_{2}}{{H}_{2}}\] |
| B. | \[{{C}_{2}}{{H}_{4}}\] |
| C. | \[{{C}_{2}}{{H}_{4}}B{{r}_{2}}\] |
| D. | \[{{C}_{6}}{{H}_{6}}\] |
| Answer» D. \[{{C}_{6}}{{H}_{6}}\] | |