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This section includes 15 Mcqs, each offering curated multiple-choice questions to sharpen your Organic Chemistry knowledge and support exam preparation. Choose a topic below to get started.
1. |
The reaction of HNO2 with ‘A’ gives quaternary ammonium salt. A is which of the following? |
A. | Methyl amine |
B. | Dimethyl amine |
C. | Trimethyl amine |
D. | Aniline |
Answer» D. Aniline | |
2. |
Primary amines react with nitrous acid to yield which of the following? |
A. | Insoluble nitrite salts |
B. | Yellow oily layer |
C. | Nitrogen gas |
D. | Azo dye |
Answer» D. Azo dye | |
3. |
When an organic compound was treated with sodium nitrite and hydrochloric acid in the ice cold, nitrogen gas was evolved copiously. What is the compound? |
A. | A nitrocompound |
B. | A primary amine |
C. | An aliphatic primary amine |
D. | An aromatic primary amine |
Answer» D. An aromatic primary amine | |
4. |
Aniline on treatment with excess of bromine water which of the following? |
A. | Aniline bromide |
B. | o-bromoaniline |
C. | p-bromoaniline |
D. | 2, 4, 6-tribromoaniline |
Answer» E. | |
5. |
The compound which on reaction with aqueous nitrous acid on HNO2 at low temperature produces an oily nitrosoamine is which of the following? |
A. | Diethylamine |
B. | Ethylamine |
C. | Aniline |
D. | Methylamine |
Answer» B. Ethylamine | |
6. |
When chloroform reacts with ethyl amine in presence of alcoholic KOH, the compound formed is which of the following? |
A. | Ethyl cyanide |
B. | Ethyl isocyanide |
C. | Formic acid |
D. | An amide |
Answer» C. Formic acid | |
7. |
Primary amines can be distinguished from secondary and tertiary amines by reacting with which of the following? |
A. | Chloroform and alcoholic KOH |
B. | Methyl iodide |
C. | Chloroform alone |
D. | Zinc dust |
Answer» B. Methyl iodide | |
8. |
When primary amines are treated with HCl, the product obtained is which of the following? |
A. | An alcohol |
B. | A cyanide |
C. | An amide |
D. | Ammonium salt |
Answer» E. | |
9. |
Reaction of primary amines with aldehyde yields which of the following compound? |
A. | Amides |
B. | Aldimines |
C. | Nitriles |
D. | Nitro compounds |
Answer» C. Nitriles | |
10. |
Ethyl amine undergoes oxidation in the presence of KMnO4 to form which compound? |
A. | An acid |
B. | An alcohol |
C. | An aldehyde |
D. | A nitrogen oxide |
Answer» D. A nitrogen oxide | |
11. |
Nitroso amines (R2N−N=O) are soluble in water. On heating them with concentrated H2SO4 they give secondary amines. What is this reaction called as? |
A. | Perkin’s reaction |
B. | Fittig’s reaction |
C. | Sandmeyer’s reaction |
D. | Liebermann’s nitroso reaction |
Answer» E. | |
12. |
p-chloroaniline and anilinium hydrochloride can be distinguished by which test? |
A. | Sandmeyer reaction |
B. | NaHCO3 |
C. | AgNO3 |
D. | Carbylamine test |
Answer» C. AgNO3 | |
13. |
Aniline reacts with acetaldehyde to form which of the following? |
A. | Schiff’s base |
B. | Carbylamine |
C. | Immine |
D. | Diazonium salt |
Answer» D. Diazonium salt | |
14. |
The action of nitrous acid on ethyl amine gives which of the following? |
A. | Ethane |
B. | Ammonia |
C. | Ethyl acohol |
D. | Nitroethane |
Answer» D. Nitroethane | |
15. |
Which of the following is converted into an alcohol on treatment with HNO2? |
A. | Methyl amine |
B. | Aniline |
C. | Dimethyl amine |
D. | Triethyl amine |
Answer» B. Aniline | |