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This section includes 14 Mcqs, each offering curated multiple-choice questions to sharpen your Chemistry knowledge and support exam preparation. Choose a topic below to get started.
1. |
A compound P on treating with concentrated H2SO4 forms R . The product R on heating at 460K forms a zwitter ionic compound. Identify P, R respectively. |
A. | Aniline; anilinium hydrogensulphate |
B. | Aniline; sulphanilic acid |
C. | Anilinium hydrogensulphate; sulphanilic acid |
D. | Sulphanilic acid; anilinium hydrogensulphate |
Answer» B. Aniline; sulphanilic acid | |
2. |
It is possible to obtain para isomers of anilines as the major product in electrophilic ring substitution of aniline. |
A. | True |
B. | False |
Answer» B. False | |
3. |
What is the order of quantities of all isomers of nitroaniline formed on the reaction of aniline with nitric acid and sulphuric acid at 288K? |
A. | ortho > meta > para |
B. | para > ortho > meta |
C. | para > meta > ortho |
D. | meta > para > ortho |
Answer» D. meta > para > ortho | |
4. |
What is the major product formed when aniline reacts with bromine water at room temperature? |
A. | 2-Bromoaniline |
B. | 4-Bromoanline |
C. | 2,6-Dibromoaniline |
D. | 2,4,6-Tribromoaniline |
Answer» E. | |
5. |
The activating effect of -NHCOCH3 group is ______ as compared to -NH2 group. |
A. | less |
B. | same |
C. | more |
D. | very high |
Answer» B. same | |
6. |
Aniline is a _______ directing compound. |
A. | ortho |
B. | meta |
C. | ortho and para |
D. | ortho, meta and para |
Answer» D. ortho, meta and para | |
7. |
Which of the following reactions/tests does not help in the distinction between ethylamine and diethylamine? |
A. | Carbylamine test |
B. | Hinsberg s test |
C. | Reaction with HNO<sub>2</sub> |
D. | Reaction with CH<sub>3</sub>CH<sub>2</sub>Br |
Answer» E. | |
8. |
Which of the following amines will form a product that is soluble in KOH, on reaction with Hinsberg s reagent? |
A. | Isopropylamine |
B. | Diethylamine |
C. | N,N-Dimethylpropylamine |
D. | N,N-Dimethylaniline |
Answer» B. Diethylamine | |
9. |
Which of the following amines, on reaction with benzenesulphonyl chloride, will give a sulphonamide that is insoluble in alkali? |
A. | Ethylamine |
B. | Ethylmethylamine |
C. | Trimethylamine |
D. | Aniline |
Answer» C. Trimethylamine | |
10. |
Hinsberg s reagent is _______ |
A. | benzenesulfonic acid |
B. | benzenesulphonyl chloride |
C. | p-toluenesulphonyl chloride |
D. | chlorosulphuric acid |
Answer» C. p-toluenesulphonyl chloride | |
11. |
Diethylamine reacts with nitrous acid in the cold to form _______ |
A. | diazonium salt |
B. | alcohol |
C. | imine |
D. | nitrosoamine |
Answer» E. | |
12. |
Which of the following is not a final product of the reaction between propylamine and nitrous acid? |
A. | CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>N<sub>2</sub>Cl |
B. | CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>OH |
C. | N<sub>2</sub> gas |
D. | H<sub>2</sub>O |
Answer» B. CH<sub>3</sub>CH<sub>2</sub>CH<sub>2</sub>OH | |
13. |
Tertiary amines dissolve in nitrous acid to form corresponding salts. |
A. | True |
B. | False |
Answer» B. False | |
14. |
Which gas is produced when ethanamine reacts with nitrous acid? |
A. | N<sub>2</sub> |
B. | H<sub>2</sub> |
C. | HCl |
D. | O<sub>2</sub> |
Answer» B. H<sub>2</sub> | |