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Anjana Gulzar Sarma
Anjana Gulzar Sarma
Asked: 3 years ago2022-11-08T17:37:34+05:30 2022-11-08T17:37:34+05:30In: General Awareness

Structure of a mixed oxide is cubic close packed the cubic unit cell of mixed oxide is composed of oxide ions. One fourth of the tetrahedral voids are occupied by divalent metal.A and the octahedral voids are occupied by a monvalent metal `B`. The formula of the oxide is :
A. `ABO_(2)`
B. `A_(2)BO_(2)`
C. `A_(2)B_(3)O_(4)`
D. `AB_(2)O_(2)`

Structure of a mixed oxide is cubic close packed the cubic unit cell of mixed oxide is composed of oxide ions. One fourth of the tetrahedral voids are occupied by divalent metal.A and the octahedral voids are occupied by a monvalent metal `B`. The formula of the oxide is :
A. `ABO_(2)`
B. `A_(2)BO_(2)`
C. `A_(2)B_(3)O_(4)`
D. `AB_(2)O_(2)`
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  1. ec8a4
    2022-10-31T21:33:45+05:30Added an answer about 3 years ago

    Correct Answer – D
    No. of atoms `(O^(2-))` in ccp `=4`
    No. of tetrahedral voids `=2xxN=8`
    No. of `A^(2+)` ions `=8xx1/4=2`
    No. of octahedral voids =No of `B^(+)` ions =4
    Ratio , `O^(2-),A^(2+):B^(+)=4:2:4=2:1:2`
    Formula of oxide `=AB_(2)O_(2)`

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Peter Bhatia
Peter Bhatia
Asked: 3 years ago2022-11-06T19:26:22+05:30 2022-11-06T19:26:22+05:30In: General Awareness

Structure of a mixed oxide is cubic close packed the cubic unit cell of mixed oxide is composed of oxide ions. One fourth of the tetrahedral voids are occupied by divalent metal.A and the octahedral voids are occupied by a monvalent metal `B`. The formula of the oxide is :
A. `AB_(2)O_(2)`
B. `ABO_(2)`
C. `A_(2)BO_(2)`
D. `A_(2)B_(3)O_(4)`

Structure of a mixed oxide is cubic close packed the cubic unit cell of mixed oxide is composed of oxide ions. One fourth of the tetrahedral voids are occupied by divalent metal.A and the octahedral voids are occupied by a monvalent metal `B`. The formula of the oxide is :
A. `AB_(2)O_(2)`
B. `ABO_(2)`
C. `A_(2)BO_(2)`
D. `A_(2)B_(3)O_(4)`
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  1. d385c
    2022-10-29T12:00:14+05:30Added an answer about 3 years ago

    Correct Answer – 1
    oxide ions`(O^(2-))` are arranged in fcc manner. Therefore number of oxide ions per unit cell is
    `8xx(1)/(8)+6xx(1)/(2)=4`
    Therfore the number of octahedral voids is `4` and number of tetrahedral voids is `8`.
    One fourth of the tetrahedral voids are occupied by divalent metal `A`. Therfore number of `A^(2+)` ions per unit cell is
    `(1)/(4)xx8=2`
    All the octahedral voids are occupied by a monovalent metal `B`.Therfore number of `B^(+)` ions per unit cell is `4`. Consequently the emipirical formula of mixed oxide is
    `A_(2)B_(4)O_(4)` or `AB_(2)O_(2)`

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