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1. |
The bond dissociation energy of \[B-F\] in\[~B{{F}_{3}}\] is \[646\text{ }kJ\text{ }mo{{l}^{-1}}\] whereas that of \[C-F\] in \[C{{F}_{4}}\] is\[515\text{ }kJ\text{ }mo{{l}^{-1}}\]. The correct reason for higher \[B-F\] bond dissociation energy as compared to that of \[C-F\] is |
A. | stronger \[\sigma \] bond between B and F in\[~B{{F}_{3}}\] as compared to that between C and F in \[C{{F}_{4}}\]. |
B. | significant \[p\pi -p\pi \] interaction between B and F in\[B{{F}_{3}}\] whereas there is no possibility of such interaction between C and F in\[C{{F}_{4}}\]. |
C. | lower degree of \[p\pi -p\pi \] interaction between B and F in \[~B{{F}_{3}}\] than that between C and F in \[C{{F}_{4}}\] |
D. | Smaller size of \[B-atom\] as compared to that of C-atom. |
Answer» C. lower degree of \[p\pi -p\pi \] interaction between B and F in \[~B{{F}_{3}}\] than that between C and F in \[C{{F}_{4}}\] | |