1.

From elementary molecular orbital theory we can give the electronic configuration of the singly positive nitrogen molecular ion \[N_{2}^{+}\] as                                        [UPSEAT 2003]

A.                 \[\sigma {{(1s)}^{2}}{{\sigma }^{*}}{{(1s)}^{2}}\sigma {{(2s)}^{2}}{{\sigma }^{*}}{{(2s)}^{2}}\pi {{(2p)}^{4}}\sigma {{(2p)}^{1}}\]
B.                         \[\sigma {{(1s)}^{2}}{{\sigma }^{*}}{{(1s)}^{2}}\sigma {{(2s)}^{2}}{{\sigma }^{*}}{{(2s)}^{2}}\sigma {{(2p)}^{1}}\pi {{(2p)}^{3}}\]
C.                 \[\sigma {{(1s)}^{2}}{{\sigma }^{*}}{{(1s)}^{2}}\sigma {{(2s)}^{2}}{{\sigma }^{*}}{{(2p)}^{2}}\pi {{(2p)}^{4}}\]
D.                 \[\sigma {{(1s)}^{2}}{{\sigma }^{*}}{{(1s)}^{2}}\sigma {{(2s)}^{2}}{{\sigma }^{*}}{{(2s)}^{2}}\sigma {{(2p)}^{2}}\pi {{(2p)}^{2}}\]
Answer» B.                         \[\sigma {{(1s)}^{2}}{{\sigma }^{*}}{{(1s)}^{2}}\sigma {{(2s)}^{2}}{{\sigma }^{*}}{{(2s)}^{2}}\sigma {{(2p)}^{1}}\pi {{(2p)}^{3}}\]


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