1.

Consider the reactions                 \[C(s)+2{{H}_{2}}(g)\to C{{H}_{4}}(g),\Delta H=-x\,kcal\]                 \[C(g)+4H(g)\to C{{H}_{4}}(g),\,\Delta H=-{{x}_{1}}\,kcal\]                 \[C{{H}_{4}}(g)\to C{{H}_{3}}(g)+H(g),\,\Delta H=+y\,kcal\]                 The bond energy of \[C-H\] bond is         [JIPMER 1997]

A.                 \[y\,kcal\,mo{{l}^{-1}}\]               
B.                 \[{{x}_{1}}\,kcal\,mo{{l}^{-1}}\]
C.                 \[x/4\,kcal\,mo{{l}^{-1}}\]          
D.                 \[{{x}_{1}}/4\,kcal\,mo{{l}^{-1}}\]
Answer» B.                 \[{{x}_{1}}\,kcal\,mo{{l}^{-1}}\]


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